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Challenges in Polymerization in Dispersed Media Read chapter Read first chapter

2018 | OriginalPaper | Chapter

Stimuli-Responsive Latexes Stabilized by Carbon Dioxide Switchable Groups

Authors : Michael F. Cunningham, Philip G. Jessop, Ali Darabi

Published in: Polymer Reaction Engineering of Dispersed Systems

Publisher: Springer International Publishing

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Abstract

Preparation of stimuli-responsive latexes whose colloidal stability can be reversibly switched using only CO2 as a trigger is reviewed. By incorporating CO2-responsive moieties into the formulation of an emulsion polymerization, polymer particles can be made for which stabilization originates from functional groups that are readily switched “on” (charged) and “off” (neutral) simply by adding or removing CO2 at atmospheric pressure. The functional groups that provide colloidal stability, typically amidines or tertiary amines, can be added in various forms such as premanufactured surfactants, functional monomers, or functional, commercially available initiators. This review focuses on the preparation, behavior, and properties of these CO2-switchable emulsion polymers. Detailed discussion is provided on how the switching behavior and latex properties are influenced by the choice of CO2-switchable moieties and the method of their incorporation into latex particles.

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previous chapter Morphology of Composite Polymer Latexes: An Update on Synthesis and Applications, Modeling, and Characterization
next chapter Probing Coagulation and Fouling in Colloidal Dispersions with Viscosity Measurements: In Silico Proof of Concept
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Metadata
Title
Stimuli-Responsive Latexes Stabilized by Carbon Dioxide Switchable Groups
Authors
Michael F. Cunningham
Philip G. Jessop
Ali Darabi
Copyright Year
2018
Book
Polymer Reaction Engineering of Dispersed Systems

Print ISBN: 978-3-319-96435-5

Electronic ISBN: 978-3-319-96436-2

Copyright Year: 2018

DOI
https://doi.org/10.1007/12_2017_6

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