Skip to main content
Disciplines
Automotive Business IT + Informatics Construction + Real Estate Electrical Engineering + Electronics Energy + Sustainability Insurance + Risk Finance + Banking Management + Leadership Marketing + Sales Mechanical Engineering + Materials
Events
DE
EN
Books
Journals
Topic Page
Marketing
Start single access now
Access for companies
EXTENDED SEARCH
Log in
Top
Journal of Sol-Gel Science and Technology
Published in: Journal of Sol-Gel Science and Technology 3/2023

03-07-2023 | Original Paper: Functional coatings, thin films and membranes (including deposition techniques)

MWCNTs and Al2O3 nanoparticles assembled into silane sol-gel ceramic multi-layer coating to improve surface performance of the magnesium alloy

Authors: Maede Sadat Koozegari, Mohammad Reza Tohidifar

Published in: Journal of Sol-Gel Science and Technology | Issue 3/2023

Log in

Activate our intelligent search to find suitable subject content or patents.

search-config
loading …

Abstract

This paper reports the successful deposition of mono- and double-layer coatings of silane-Al2O3/multi-walled carbon nanotube (MWCNT) nanocomposites on magnesium alloy (AZ91) by sol-gel dip coating technique to improve the corrosion behavior. Scanning electron microscopy, atomic force microscopy, electrochemical impedance spectroscopy, and potentiodynamic polarization techniques were utilized to assess the protective performance of the coatings with various MWCNT contents (0.02, 0.05, 0.1, and 0.15 wt.%) and constant Al2O3 concentration (2 wt.%). The incorporation of an optimal amount of MWCNTs (0.1 wt.%) into the mono-layer coating led to corrosion resistance with polarization resistance and roughness of 183.4 kΩcm2 and 23.97 nm, respectively. In the case of the double-layer coatings, 0.15 wt.% MWCNT was the optimal value as it significantly increased the polarization resistance (349.6 kΩcm2) and reduced the roughness (5.58 nm), and cracking. The mentioned coating system can be a promising candidate to protect AZ91 magnesium alloy against corrosion.

Graphical Abstract

previous article Optimization of energy-storage performance of Mn-doped BaZr0.2Ti0.8O3 lead-free ferroelectric thin films by the sol–gel method
next article Epoxide synthesis of binary rare earth oxide aerogels with high molar ratios (1:1) of Eu, Gd, and Yb

Dont have a licence yet? Then find out more about our products and how to get one now:

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

  • über 67.000 Bücher
  • über 390 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Maschinenbau + Werkstoffe




 

Jetzt Wissensvorsprung sichern!

inform now

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

  • über 102.000 Bücher
  • über 537 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Finance + Banking
  • Management + Führung
  • Marketing + Vertrieb
  • Maschinenbau + Werkstoffe
  • Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

inform now
Appendix
Available only for authorised users
Literature
1.
Rajabalizadeh Z, Seifzadeh D, Habibi-Yangjeh A, Mesri Gundoshmian T, Nezamdoust S (2018) Electrochemical noise analysis to examine the corrosion behavior of Ni−P deposit on AM60B alloy plated by Zr pretreatment. Surf. Coat. Tech. 346:29–39CrossRef
2.
Xian W, Linxin L, Xie Z-H, Yu G (2018) Duplex coating combining layered double hydroxide and 8-quinolinol layers on Mg Alloy for corrosion protection. Electrochim. Acta 283:1845–1857CrossRef
3.
Ai-hui LIU, Ji-lin XU (2018) Preparation and corrosion resistance of superhydrophobic coatings on AZ31 magnesium alloy. T. Nonferr. Metal. Soc. 28:2287–2293CrossRef
4.
Ashraf MA, Liu ZH, Peng WX, Yoysefi N (2019) Amino acid and TiO2 nanoparticles mixture inserted into sol-gel coatings: an efficient corrosion protection system for AZ91 magnesium alloy. Prog. Org. Coat. 136:105296CrossRef
5.
Ashassi-Sorkhabi H, Moradi-Alavian S, Esrafili MD, Kazempour A (2019) Hybrid sol- gel coatings based on silanes-amino acids for corrosion protection of AZ91 magnesium alloy: electrochemical and DFT insights. Prog. Org. Coat. 131:191–202CrossRef
6.
Nezamdoust S, Seifzadeh D, Habibi-Yangjeh A (2020) Nanodiamond incorporated sol- gel coating for corrosion protection of magnesium alloy. T. Nonferr. Metal. Soc. 30:1535–1549CrossRef
7.
Talha M, Wang Q, Ma Y, Lin Y (2023) Self-assembled hybrid silane/ZnO coatings for corrosion protection of resorbable magnesium alloy. Int. J. Adhes. Adhes. 120:103281CrossRef
8.
Pereira GS, Ramirez OMP, Avila PRT, Avila JA, Pinto HC, Miyazaki MH, de Melo HG, Filho WWB (2022) Cerium conversion coating and sol-gel coating for corrosion protection of the WE43 Mg alloy. Corr. Sci. 206:110527CrossRef
9.
Khosravi H S, Veerapandiyan VK, Vallant R, Reichmann K (2020) Effect of processing conditions on the structural properties and corrosion behavior of TiO2- SiO2 multilayer coatings derived via the sol-gel method. Ceram. Int. 46:17741–17751CrossRef
10.
Mohammadi I, Shahrabi T, Mahdavian M, Izadi M (2022) A novel corrosion inhibitive system comprising Zn-Al LDH and hybrid sol-gel silane nanocomposite coating for AA2024-T3. J. Alloy Compd. 909:164755CrossRef
11.
Balaji J, Roh SH, Edison TNJI, Jung HY, Sethuraman MG (2020) Sol-gel based hybrid silane coating for enhanced corrosion protection of copper in aqueous sodium chloride. J. Mol. Liq. 302:112551CrossRef
12.
Liang Y, Liu B, Zhang B, Liu ZH, Liu W (2021) Effects and mechanism of filler surface coating strategy on thermal conductivity of composites: A case study on epoxy/SiO2-coated BN composites. Int. J. Heat Mass Tran. 164:120533CrossRef
13.
Poelman M, Fedel M, Motte C, Lahema D, Th. Urios, Paint Y, Deflorian F, Olivier MG (2015) Influence of formulation and application parameters on the performances of a sol-gel/clay nanocomposite on the corrosion resistance of hot- dip galvanized steel. Part I. Study of the sol preparation parameters. Surf. Coat. Tech. 274:1–8CrossRef
14.
Ansari F, Naderi R, Dehghanian C (2015) Study on the protective function of cloisite incorporated silane sol-gel coatings cured at different conditions. Appl. Clay Sci. 114:93–102CrossRef
15.
Both J, Szabo G, Katona G, Muresan LM (2022) Tannic acid reinforced sol-gel silica coatings for corrosion protection of zinc substrates. Mat. Chem. Phys. 282:125912CrossRef
16.
Shi Y, Yuan SH, Ter-Ovanessian B, Hermange K, Huo Y, Normand B (2021) Enhancing the barrier effect of sol-gel derived inorganic coating by doping h-BN nanosheet. Appl. Surf. Sci. 544:148849CrossRef
17.
Yang M, Wang T, Wu M (2021) Ablation behavior of SiC whisker and ZrB2 particle- filled ZrO2 sol-gel composite coating under high-intensity continuous laser irradiation. Ceram. Int. 47:26327–26334CrossRef
18.
Fernandez-Hernan JP, Torres B, Lopez AJ, Martinez-Campos E, Rams J (2021) Sol- gel coatings doped with graphene nanoplatelets for improving the degradation rate and the cytocompatibility of AZ31 alloy for biomedical applications. Surf. Coat. Tech. 426:127745CrossRef
19.
Seifzadeh D, Golmoghani-Ebrahimi E (2012) Formation of novel and crack free nanocomposites based on sol gel process for corrosion protection of copper. Surf. Coat. Tech. 210:103–112CrossRef
20.
Suleiman RK, Kumar AM, Rahman MM, Al-Badour FA, Meliani MH, Saleh TA (2020) Effect of metal oxide additives on the structural and barrier properties of a hybrid organosilicon sol-gel coating in 3.5% NaCl medium. Prog. Org. Coat. 148:105825CrossRef
21.
Liu Y, Lin Q, Chen J, Shao Y, Wang Y, Wang J (2022) PDMS-OH and nano- SiO2 Modified KH570-TEOS silica-sol coating and protective effect on concrete. Colloid Surface A 648:129279CrossRef
22.
Parhizkar N, Ramezanzadeh B, Shahrabi T (2018) Corrosion protection and adhesion properties of the epoxy coating applied on the steel substrate pre-treated by a sol- gel based silane coating filled with amino and isocyanate silane functionalized graphene oxide nanosheets. Appl. Surf. Sci. 439:45–59CrossRef
23.
Liu Y, Cao H, Yu Y, Chen SH (2015) Corrosion protection of silane coatings modified by carbon nanotubes on stainless steel. Int. J. Electrochem. Sci. 10:3497–3509CrossRef
24.
Karbasi M, Yazdian N, Vahidian A (2012) Development of electro-co-deposited Ni- TiC nano-particle reinforced nanocomposite coatings. Surf. Coat. Tech. 207:587–593CrossRef
25.
Jiang L, Han M, Sun J, Gong M, Lin Y, Xiao T, Xiang P, Chen W, Tan X (2023) Strong mechanical and durable superhydrophobic photothermal MWCNTs/SiO2/PDMS/PVDF composite coating for anti-icing and de-icing. Prog. Org. Coat. 174:107282CrossRef
26.
Song R, Zhang SH, He Y, Li H, Fan Y, He T, Zhang Y, Xiang Y, Zhang H (2021) Effect of H-MWCNTs addition on anti-corrosion performance and mechanical character of Ni-Cu/H-MWCNTs composite coatings prepared by pulse electrodeposition technique. Colloid Surface A 630:127519CrossRef
27.
Wei J, Sun L, Han J, Huang W (2022) MWCNTs/CB waterborne conductive smart coating for damage monitoring of composites: Design, fabrication, characterization, and verification. Prog. Org. Coat. 172:107136CrossRef
28.
Nezamdoust S, Seifzadeh D, Rajabalizadeh Z (2018) PTMS/OH-MWCNT sol-gel nanocomposite for corrosion protection of magnesium alloy. Surf. Coat. Tech. 335:228–240CrossRef
29.
Lopez AJ, Urena A, Rams J (2010) Fabrication of novel sol-gel silica coatings reinforced with multi-walled carbon nanotubes. Mater. Lett. 64:924–927CrossRef
30.
Fernandez-Hernan JP, Lopez AJ, Torres B, Rams J (2020) Silicon oxide multilayer coatings doped with carbon nanotubes and graphene nanoplatelets for corrosion protection of AZ31B magnesium alloy. Prog. Org. Coat. 148:105836CrossRef
31.
Daavari M, Atapour M, Mohedano M, Sanchez HM, Rodriguez-Hernandez J, Matykina E, Arrabal R, Taherizadeh A (2022) Quasi-in vivo corrosion behavior of AZ31B Mg alloy with hybrid MWCNTs-PEO/PCL based coatings. J. Magnes. Alloy 10:3217–3233CrossRef
32.
Jia J, Zhang B, Liu D, Liu SH, Ji G, Ji R (2020) Effects of Al2O3 coating induced structural and mechanical changes of C/C composites. J. Alloy compd. 818:152847CrossRef
33.
Mohammadi I, Shahrabi T, Mahdavian M, Izadi M (2021) Zn-Al layered double hydroxide as an inhibitive conversion coating developed on AA2024-T3 by one- step hydrothermal crystallization: Crystal structure evolution and corrosion protection performance. Surf. Coat. Tech. 409:126882CrossRef
34.
Nallamuthu N, Prakash I, Venkateswarlu M, Balasubramanyam S, Satyanarayana N (2008) Sol-gel synthesis and characterization of Li2O-As2O5-SiO2 glassy System, Mat. Chem. Phys. 111:24–28
35.
Tran ThN, Pham ThVA, Le MLPh, Nguyen ThPhTh, Tran VM (2013) Synthesis of amorphous silica and sulfonic acid functionalized silica used as reinforced phase for polymer electrolyte memberane. Adv. Nat. Sci.: Nanosci. Nanotechnol 4:045007
36.
Boulesbaa M (2021) Spectroscopic ellipsometry and FTIR characterization of annealed SiOxNy:H films prepared by PECVD. Opt. Mater. 122:111693CrossRef
37.
Kazancioglu M, Tsilomelekis G, Lehman R, Hara M (2021) FTIR studies on plasticization of silicate glass with ionic liquids (conversion to silicate polymers). J. Non-Cryst. Solids 561:120757CrossRef
38.
Djebaili K, Mekhalif Z, Boumaza A, Djelloul A (2015) XPS, FTIR, EDX, and XRD analysis of Al2O3 scales grown on PM2000 alloy. J. Spectrosc. 2015:868109
39.
Li Y, Xu C, Wei B, Zhang X, Zheng M, Wu D, Ajayan PM (2002) Self-organized ribbons of aligned carbon nanotubes. Chem. Mater. 14:483–485CrossRef
40.
Afghahi SSS, Peymanfar R, Javanshir SH, Atassi Y, Jafarian M (2017) Synthesis, characterization and microwave characteristics of ternary nanocomposite of MWCNTs/doped Sr-hexaferrite/PANI. J. Magn. Magn. Mater. 423:152–157CrossRef
Metadata
Title
MWCNTs and Al2O3 nanoparticles assembled into silane sol-gel ceramic multi-layer coating to improve surface performance of the magnesium alloy
Authors
Maede Sadat Koozegari
Mohammad Reza Tohidifar
Publication date
03-07-2023
Publisher
Springer US
Published in
Journal of Sol-Gel Science and Technology / Issue 3/2023
Print ISSN: 0928-0707
Electronic ISSN: 1573-4846
DOI
https://doi.org/10.1007/s10971-023-06181-z

Other articles of this Issue 3/2023

Journal of Sol-Gel Science and Technology 3/2023 Go to the issue

Original Paper: Functional coatings, thin films and membranes (including deposition techniques)

Optimization of energy-storage performance of Mn-doped BaZr0.2Ti0.8O3 lead-free ferroelectric thin films by the sol–gel method

Original Paper: Sol-gel and hybrid materials for biological and health (medical) applications

Antimicrobial properties of polysiloxane/polyoxometallates

Original Paper: Sol-gel and hybrid materials for catalytic, photoelectrochemical and sensor applications

Influence of defect density states on NO2 gas sensing performance of Na: ZnO thin films

Original Paper: Nano-structured materials (particles, fibers, colloids, composites, etc.)

Novel fibrous/nano-Al2O3 insulation composites produced using sol-gel impregnation for energy-saving

Original Paper: Characterization methods of sol-gel and hybrid materials

3rd order optical nonlinearity enhancement of halochromic phenol red dye immobilized in PVA/silica hybrid host matrix

Original Paper: Sol-gel, hybrids and solution chemistries

Investigating the growth, thermal expansion and dispersion of iron oxide in presence of nanostructured siloxane containing hydrophobic PDMS-like segments

Premium Partners

    Image Credits