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27-07-2022

Na₂O–CaO–SO₃ Ceramics as Promising Inorganic Porogens

Authors: T. V. Safronova, T. B. Shatalova, Ya. Yu. Filippov, O. U. Toshev, A. V. Knot’ko, L. A. Vaimugin, D. V. Savchenkova

Published in: Glass and Ceramics | Issue 3-4/2022

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Abstract

Ceramics with post-firing (600 – 900°C) phase composition represented by calcium sulfate anhydrite CaSO₄ and sodium calcium sulfates (Na_0.8Ca_0.1)₂SO₄ and Na₆Ca(SO₄)₄ was obtained from a powder mixture of sodium sulfate Na₂SO₄ and calcium sulfate dihydrate CaSO₄ ∙ 2H₂O with molar ratio CaSO₄ ∙ 2H₂O/Na₂SO₄ = 1. The phase composition of the powder mixture after homogenization (in acetone) in a planetary mill included, in addition to the initial salts, hydrated sodium calcium sulfate Na₄Ca(SO₄)₃ ∙ 2H₂O. On soaking in water for 5 and 60 min the weight loss of the ceramic sample fired at 700°C was equal to 15 and 75%, respectively. Na₂O–CaO–SO₃ ceramics in the form of granules or complex structures obtained by means of 3D printing can be used as a removable (soluble or leachable) porogen and (or) a prototype of a porous space with specified architecture to obtain porous polymeric or inorganic materials.

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Title: Na2O–CaO–SO3 Ceramics as Promising Inorganic Porogens
Authors: T. V. Safronova
T. B. Shatalova
Ya. Yu. Filippov
O. U. Toshev
A. V. Knot’ko
L. A. Vaimugin
D. V. Savchenkova
Publication date: 27-07-2022
Publisher: Springer US
Published in: Glass and Ceramics / Issue 3-4/2022
Print ISSN: 0361-7610
Electronic ISSN: 1573-8515
DOI: https://doi.org/10.1007/s10717-022-00461-w

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