Skip to main content
Top
Published in: Tribology Letters 3/2010

01-06-2010 | Original Paper

Nanocomposite UHMWPE–CNT Polymer Coatings for Boundary Lubrication on Aluminium Substrates

Authors: M. Abdul Samad, Sujeet K. Sinha

Published in: Tribology Letters | Issue 3/2010

Log in

Activate our intelligent search to find suitable subject content or patents.

search-config
loading …

Abstract

The boundary lubrication regime plays a very important role in determining the life span of any of the two mating parts under liquid-lubricated conditions. It is during the start\stop cycles when insufficient fluid is available to fully separate the surfaces in relative motion and thus unusual wear takes place; a case of boundary lubrication. The aim of this work is to study the feasibility of using polymer coatings as boundary lubricants. This study investigates the friction and wear properties of ultra-high molecular weight polyethylene (UHMWPE) films coated on aluminium substrates under dry and base oil (without any additives)-lubricated conditions. In order to increase the load bearing capacity of the UHMWPE coatings, 0.1 wt% of single-walled carbon nanotubes are added. Experiments are carried out on a custom-built tribometer simulating a line contact between a polymer-coated cylindrical Al surface (shaft) and a flat uncoated Al plate as the counterface. The experimental parameters such as the normal load and the sliding speed are selected to simulate the boundary and mixed lubrication regimes for comparison purposes. Specific wear rates of the polymer films and bare Al surface under lubricated conditions are also calculated. Stribeck curves have been generated to evaluate the effectiveness of the pristine UHMWPE and the nanocomposite coatings in the various regimes of lubrication, especially the boundary lubrication regime. It is observed that the selected polymer coatings are effective in protecting the metallic surfaces without causing any observable oil contamination with wear debris.

Dont have a licence yet? Then find out more about our products and how to get one now:

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

  • über 102.000 Bücher
  • über 537 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Finance + Banking
  • Management + Führung
  • Marketing + Vertrieb
  • Maschinenbau + Werkstoffe
  • Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

  • über 67.000 Bücher
  • über 390 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Maschinenbau + Werkstoffe




 

Jetzt Wissensvorsprung sichern!

Literature
1.
go back to reference Vizintin, J., Kalin, M., Dohda, K., Jahanmir, S. (eds.): Tribology of Mechanical Systems: A Guide to Present and Future Technologies. American Society of Mechanical Engineers, USA (2004) Vizintin, J., Kalin, M., Dohda, K., Jahanmir, S. (eds.): Tribology of Mechanical Systems: A Guide to Present and Future Technologies. American Society of Mechanical Engineers, USA (2004)
2.
go back to reference Gold, P.W., Loos, J.: Wear resistance of PVD coatings in roller bearings. Wear 253, 465–472 (2002)CrossRef Gold, P.W., Loos, J.: Wear resistance of PVD coatings in roller bearings. Wear 253, 465–472 (2002)CrossRef
3.
go back to reference Erdemir, A., Nichols, F.A., Pan, X.Z.: Friction and wear performance of ion-beam-deposited diamond-like carbon films on steel substrates. Diam. Relat. Mater. 3, 119–125 (1994)CrossRef Erdemir, A., Nichols, F.A., Pan, X.Z.: Friction and wear performance of ion-beam-deposited diamond-like carbon films on steel substrates. Diam. Relat. Mater. 3, 119–125 (1994)CrossRef
4.
go back to reference Grill, A.: Tribology of diamondlike carbon and related materials: an updated review. Surf. Coat. Technol. 94–95, 507–513 (1997) Grill, A.: Tribology of diamondlike carbon and related materials: an updated review. Surf. Coat. Technol. 94–95, 507–513 (1997)
5.
go back to reference Gahlin, R., Larsson, M., Hedenqvist, P.: ME-C:H coatings in roller bearings. Wear, 249, 302–309 (2001) Gahlin, R., Larsson, M., Hedenqvist, P.: ME-C:H coatings in roller bearings. Wear, 249, 302–309 (2001)
6.
go back to reference Siu, J.H.W., Li, L.K.Y.: An investigation of the effect of surface roughness and coating thickness on the friction and wear behaviour of a commercial MoS2-metal coating on AISI 400C steel. Wear 237, 283–287 (2000)CrossRef Siu, J.H.W., Li, L.K.Y.: An investigation of the effect of surface roughness and coating thickness on the friction and wear behaviour of a commercial MoS2-metal coating on AISI 400C steel. Wear 237, 283–287 (2000)CrossRef
7.
go back to reference Neville, A., Morina, A., Haque, T., Voong, M.: Compatibility between tribological surfaces and lubricant additives: how friction and wear reduction can be controlled by surface/lube synergies. Tribol. Int. 40, 1680–1695 (2007)CrossRef Neville, A., Morina, A., Haque, T., Voong, M.: Compatibility between tribological surfaces and lubricant additives: how friction and wear reduction can be controlled by surface/lube synergies. Tribol. Int. 40, 1680–1695 (2007)CrossRef
8.
go back to reference Li, J., Ren, T., Liu, H., Wang, D., Liu, W.: The tribological study of a tetrazole derivative as additive in liquid paraffin. Wear 246, 130–133 (2000)CrossRef Li, J., Ren, T., Liu, H., Wang, D., Liu, W.: The tribological study of a tetrazole derivative as additive in liquid paraffin. Wear 246, 130–133 (2000)CrossRef
9.
go back to reference Varlot, K., Kasrai, M., Bancroft, G.M., Yamaguchi, E.S., Ryason, P.R., Igarashi, J.: X-ray absorption study of antiwear films generated from ZDDP and borate micelles. Wear 249, 1029–1035 (2001)CrossRef Varlot, K., Kasrai, M., Bancroft, G.M., Yamaguchi, E.S., Ryason, P.R., Igarashi, J.: X-ray absorption study of antiwear films generated from ZDDP and borate micelles. Wear 249, 1029–1035 (2001)CrossRef
10.
go back to reference Jimenez, E., Bermudez, M.D., Carrion, F.J., Martinez-Nicolas, G.: Room temperature ionic liquids as lubricant additives in steel-aluminium contacts: influence of sliding velocity, normal load and temperature. Wear 261, 347–359 (2006)CrossRef Jimenez, E., Bermudez, M.D., Carrion, F.J., Martinez-Nicolas, G.: Room temperature ionic liquids as lubricant additives in steel-aluminium contacts: influence of sliding velocity, normal load and temperature. Wear 261, 347–359 (2006)CrossRef
11.
go back to reference Glovnea, R.P., Olver, A.V., Spikes, H.: Lubrication of rough surfaces by a boundary film-forming viscosity modifier additive. J. Tribol. 127, 223–312 (2005)CrossRef Glovnea, R.P., Olver, A.V., Spikes, H.: Lubrication of rough surfaces by a boundary film-forming viscosity modifier additive. J. Tribol. 127, 223–312 (2005)CrossRef
12.
go back to reference Klein, L.C.: Sol-gel technology for thin films, fibres, performs, electronics and speciality shapes. Noyes Publications, Park Ridge, NJ (1988) Klein, L.C.: Sol-gel technology for thin films, fibres, performs, electronics and speciality shapes. Noyes Publications, Park Ridge, NJ (1988)
13.
go back to reference Suh, N.P.: Tribophysics. Prentice-Hall, Englewood Cliffs, NJ (1986) Suh, N.P.: Tribophysics. Prentice-Hall, Englewood Cliffs, NJ (1986)
14.
go back to reference Abdul Samad, M., Satyanarayana, N., Sinha, S.K.: Tribology of UHMWPE film on air-plasma treated tool steel and effect of PFPE overcoat. Surf. Coat. Technol. 204, 1330–1338 (2010)CrossRef Abdul Samad, M., Satyanarayana, N., Sinha, S.K.: Tribology of UHMWPE film on air-plasma treated tool steel and effect of PFPE overcoat. Surf. Coat. Technol. 204, 1330–1338 (2010)CrossRef
15.
go back to reference Fusaro, R.L.: Tribological properties of polymer films and solid bodies in a vacuum environment. Prepared for the 1987 Annual Meeting of the American Society of Lubrication Engineers. NASA Report Fusaro, R.L.: Tribological properties of polymer films and solid bodies in a vacuum environment. Prepared for the 1987 Annual Meeting of the American Society of Lubrication Engineers. NASA Report
16.
go back to reference Bello, J.O., Wood, R.J.K.: Micro-abrasion of filled and unfilled polyamide 11 coatings. Wear 258, 294–302 (2005)CrossRef Bello, J.O., Wood, R.J.K.: Micro-abrasion of filled and unfilled polyamide 11 coatings. Wear 258, 294–302 (2005)CrossRef
17.
go back to reference Gadow, R., Scherer, D.: Composite coatings with dry lubrication ability on light metal substrates. Surf. Coat. Technol. 151–152, 471–477 (2002)CrossRef Gadow, R., Scherer, D.: Composite coatings with dry lubrication ability on light metal substrates. Surf. Coat. Technol. 151–152, 471–477 (2002)CrossRef
18.
go back to reference Sinha, S.K., Lee, C.B., Lim, S.C.: Tribological performance of UHMWPE and PFPE coated films on aluminium surface. Tribol. Lett. 29, 193–199 (2008)CrossRef Sinha, S.K., Lee, C.B., Lim, S.C.: Tribological performance of UHMWPE and PFPE coated films on aluminium surface. Tribol. Lett. 29, 193–199 (2008)CrossRef
19.
go back to reference Harvey, P.E., Stein, L.: Ultra High Molecular Weight Polyethylene (UHMWPE). Ticona LLC, ASM International (1999) Harvey, P.E., Stein, L.: Ultra High Molecular Weight Polyethylene (UHMWPE). Ticona LLC, ASM International (1999)
20.
go back to reference Sinha, S.K.: Wear Failures of Plastics, in ASM International Handbook, vol. 11, pp. 1019–1027. ASM International, Materials Park, OH (2002) Sinha, S.K.: Wear Failures of Plastics, in ASM International Handbook, vol. 11, pp. 1019–1027. ASM International, Materials Park, OH (2002)
21.
go back to reference Satyanarayana, N., Sinha, S.K., Ong, B.H.: Tribology of a novel UHMWPE/PFPE dual film coated onto Si surface. Sensor. Actuator. Phys. 128, 98–108 (2006)CrossRef Satyanarayana, N., Sinha, S.K., Ong, B.H.: Tribology of a novel UHMWPE/PFPE dual film coated onto Si surface. Sensor. Actuator. Phys. 128, 98–108 (2006)CrossRef
22.
go back to reference Myo, M., Sinha, S.K.: DLC and UHMWPE as hard/soft composite film on Si for improved tribological performance. Surf. Coat. Technol. 202, 3698–3708 (2008) Myo, M., Sinha, S.K.: DLC and UHMWPE as hard/soft composite film on Si for improved tribological performance. Surf. Coat. Technol. 202, 3698–3708 (2008)
23.
go back to reference M. Abdul Samad, Sinha, S.K.: Mechanical, thermal and tribological characterization of a UHMWPE film reinforced with carbon nanotubes coated on steel. Tribol. Lett. (2010) (submitted). Manuscript number TRIL1268 M. Abdul Samad, Sinha, S.K.: Mechanical, thermal and tribological characterization of a UHMWPE film reinforced with carbon nanotubes coated on steel. Tribol. Lett. (2010) (submitted). Manuscript number TRIL1268
24.
go back to reference Bal, S., Samal, S.S.: Carbon nanotube reinforced polymer composites—a state of the art. Bull. Mater. Sci. 30, 379–386 (2007)CrossRef Bal, S., Samal, S.S.: Carbon nanotube reinforced polymer composites—a state of the art. Bull. Mater. Sci. 30, 379–386 (2007)CrossRef
25.
go back to reference Giraldo, L.F., Brostow, W., Devaux, E., Lopez, B.L., Perez, L.D.: Scratch and wear resistance of polyamide 6 reinforced with multiwall carbon nanotubes. Nanosci. Nanotechnol. 8, 1–8 (2008)CrossRef Giraldo, L.F., Brostow, W., Devaux, E., Lopez, B.L., Perez, L.D.: Scratch and wear resistance of polyamide 6 reinforced with multiwall carbon nanotubes. Nanosci. Nanotechnol. 8, 1–8 (2008)CrossRef
26.
go back to reference Satyanarayana, N., Rajan, K.S.S., Sinha, S.K., Shen, L.: Carbon nanotube reinforced polyimide thin film for high wear durability. Tribol. Lett. 27, 181–188 (2007)CrossRef Satyanarayana, N., Rajan, K.S.S., Sinha, S.K., Shen, L.: Carbon nanotube reinforced polyimide thin film for high wear durability. Tribol. Lett. 27, 181–188 (2007)CrossRef
27.
go back to reference Zoo, Y.S., An, J.W., Lim, D.P., Lim, D.S.: Effect of carbon nanotube on tribological behaviour of UHMWPE. Tribol. Lett. 16, 305–309 (2004)CrossRef Zoo, Y.S., An, J.W., Lim, D.P., Lim, D.S.: Effect of carbon nanotube on tribological behaviour of UHMWPE. Tribol. Lett. 16, 305–309 (2004)CrossRef
28.
go back to reference Xue, Y., Wu, W., Jacobs, O., Schadel, B.: Tribological behaviour of UHMWPE/HDPE blends reinforced with multi-wall carbon nanotubes. Polym. Test. 25, 221–229 (2006)CrossRef Xue, Y., Wu, W., Jacobs, O., Schadel, B.: Tribological behaviour of UHMWPE/HDPE blends reinforced with multi-wall carbon nanotubes. Polym. Test. 25, 221–229 (2006)CrossRef
29.
go back to reference Ruan, S., Gao, P., Yu, T.X.: Ultro-strong gel spun UHMWPE fibers reinforced using multiwalled carbon nanotubes. Polymer 47, 1604–1611 (2006)CrossRef Ruan, S., Gao, P., Yu, T.X.: Ultro-strong gel spun UHMWPE fibers reinforced using multiwalled carbon nanotubes. Polymer 47, 1604–1611 (2006)CrossRef
30.
go back to reference Wei, Z., Zhao, Y.P., Ruan, S.L., Gao, P., Yu, T.X.: A study of the tribological behaviour of carbon-nanotube-reinforced ultrahigh molecular weight polyethylene composites. Surf. Interface Anal. 38, 883–886 (2006)CrossRef Wei, Z., Zhao, Y.P., Ruan, S.L., Gao, P., Yu, T.X.: A study of the tribological behaviour of carbon-nanotube-reinforced ultrahigh molecular weight polyethylene composites. Surf. Interface Anal. 38, 883–886 (2006)CrossRef
31.
go back to reference Utegulov, Z.N., Mast, D.B.: Functionalization of single-walled carbon nanotubes using isotropic plasma treatment: resonant Raman spectroscopy study. J. Appl. Phys. 97, 104324-1–104324-4 (2005) Utegulov, Z.N., Mast, D.B.: Functionalization of single-walled carbon nanotubes using isotropic plasma treatment: resonant Raman spectroscopy study. J. Appl. Phys. 97, 104324-1–104324-4 (2005)
32.
go back to reference Chen, Q., Dai, L., Gao, M., Huag, S., Mau, J.: Plasma activation of carbon nanotubes for chemical modification. J. Phys. Chem. B 105, 618–622 (2001)CrossRef Chen, Q., Dai, L., Gao, M., Huag, S., Mau, J.: Plasma activation of carbon nanotubes for chemical modification. J. Phys. Chem. B 105, 618–622 (2001)CrossRef
33.
go back to reference Plank, N.O.V., Jiang, L., Cheung, R.: Fluorination of carbon nanotubes in CF4 plasma. Appl. Phys. Lett. 83, 2426–2428 (2003)CrossRefADS Plank, N.O.V., Jiang, L., Cheung, R.: Fluorination of carbon nanotubes in CF4 plasma. Appl. Phys. Lett. 83, 2426–2428 (2003)CrossRefADS
34.
go back to reference Khare, B.N., Meyyappan, M., Cassel, A.M., Nguen, C.V., Han, J.: Functionalization of carbon nanotubes using atomic hydrogen from a glow discharge. Nano Lett. 2, 73–77 (2002)CrossRefADS Khare, B.N., Meyyappan, M., Cassel, A.M., Nguen, C.V., Han, J.: Functionalization of carbon nanotubes using atomic hydrogen from a glow discharge. Nano Lett. 2, 73–77 (2002)CrossRefADS
35.
go back to reference Hilding, J., Grulke, E.A., Zhang, Z.G., Lockwood, F.: Dispersion of carbon nanotubes in liquids. J. Dispersion Sci. Technol. 24, 1–41 (2003)CrossRef Hilding, J., Grulke, E.A., Zhang, Z.G., Lockwood, F.: Dispersion of carbon nanotubes in liquids. J. Dispersion Sci. Technol. 24, 1–41 (2003)CrossRef
36.
go back to reference Miyoshi, K.: Solid Lubrication Fundamentals and Applications, p. 266. Marcel Dekker, Inc., New York (2001)CrossRef Miyoshi, K.: Solid Lubrication Fundamentals and Applications, p. 266. Marcel Dekker, Inc., New York (2001)CrossRef
37.
go back to reference Bhushan, B.: Principles and Applications of Tribology, p. 687. Wiley, New York (1999) Bhushan, B.: Principles and Applications of Tribology, p. 687. Wiley, New York (1999)
38.
go back to reference Guanteng, G., Cann, P.M., Olver, A.V., Spikes, H.A.: Lubricant film thickness in rough surface, mixed elastohydrodynamic contact. J. Tribol. 122, 65–76 (2000)CrossRef Guanteng, G., Cann, P.M., Olver, A.V., Spikes, H.A.: Lubricant film thickness in rough surface, mixed elastohydrodynamic contact. J. Tribol. 122, 65–76 (2000)CrossRef
Metadata
Title
Nanocomposite UHMWPE–CNT Polymer Coatings for Boundary Lubrication on Aluminium Substrates
Authors
M. Abdul Samad
Sujeet K. Sinha
Publication date
01-06-2010
Publisher
Springer US
Published in
Tribology Letters / Issue 3/2010
Print ISSN: 1023-8883
Electronic ISSN: 1573-2711
DOI
https://doi.org/10.1007/s11249-010-9610-8

Other articles of this Issue 3/2010

Tribology Letters 3/2010 Go to the issue

Premium Partners