Skip to main content
Top
Published in: Journal of Materials Science: Materials in Electronics 16/2020

07-07-2020

Nanosized-MnCo2O4-embedded 1D carbon nanofibres for supercapacitor with promising electrochemical properties

Authors: Hongquan Yu, Hengyan Zhao, Yanbo Wu, Baojiu Chen, Jiashi Sun, Lihong Cheng, Xiangping Li, Jinsu Zhang, Sai Xu

Published in: Journal of Materials Science: Materials in Electronics | Issue 16/2020

Log in

Activate our intelligent search to find suitable subject content or patents.

search-config
loading …

Abstract

In this work, nanosized-MnCo2O4-embedded one-dimensional (1-d) carbon (MnCo2O4/C) nanofibres were prepared using a simple electrospinning/calcination method and their electrochemical performance was investigated. Transmission electron microscopy, energy-dispersive spectroscopy, and selected area electron diffraction were used to show that copious quantities of MnCo2O4 nanoparticles (10–20 nm in diameter) are homogeneously dispersed and embedded in the 1-d carbon matrix thus produced. The MnCo2O4/C composite nanofibres exhibit high-specific capacitance 125.0 F/g (1.0 A/g) and good cycle stability (119% capacitance retention after 1000 cycles). The superior electrochemical performance of the composite is due to its unique embedded structure which provides a favourable electron carrier and buffering matrix for the effective release of mechanical stress caused by changes in volume. It also prevents the aggregation of MnCo2O4 nanoparticles during charge–discharge cycling.

Dont have a licence yet? Then find out more about our products and how to get one now:

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

  • über 102.000 Bücher
  • über 537 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Finance + Banking
  • Management + Führung
  • Marketing + Vertrieb
  • Maschinenbau + Werkstoffe
  • Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

  • über 67.000 Bücher
  • über 390 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Maschinenbau + Werkstoffe




 

Jetzt Wissensvorsprung sichern!

Springer Professional "Wirtschaft"

Online-Abonnement

Mit Springer Professional "Wirtschaft" erhalten Sie Zugriff auf:

  • über 67.000 Bücher
  • über 340 Zeitschriften

aus folgenden Fachgebieten:

  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Finance + Banking
  • Management + Führung
  • Marketing + Vertrieb
  • Versicherung + Risiko




Jetzt Wissensvorsprung sichern!

Literature
1.
go back to reference J. Nai, W. Xiong, L. David, Hollow structures based on prussian blue and its analogs for electrochemical energy storage and conversion. Adv. Mater. 38, 1706825 (2019)CrossRef J. Nai, W. Xiong, L. David, Hollow structures based on prussian blue and its analogs for electrochemical energy storage and conversion. Adv. Mater. 38, 1706825 (2019)CrossRef
2.
go back to reference Y. Wang, Y. Song, Y. Xia, Electrochemical capacitors: mechanism, materials, systems, characterization and applications. Chem. Soc. Rev. 45, 5925–5950 (2016)CrossRef Y. Wang, Y. Song, Y. Xia, Electrochemical capacitors: mechanism, materials, systems, characterization and applications. Chem. Soc. Rev. 45, 5925–5950 (2016)CrossRef
3.
go back to reference C. Costentin, R.P. Thomas, S. Jean-Michel, How do pseudocapacitors store energy? Theoretical analysis and experimental illustration. ACS Appl. Mater. Interface 9, 8649–8658 (2017)CrossRef C. Costentin, R.P. Thomas, S. Jean-Michel, How do pseudocapacitors store energy? Theoretical analysis and experimental illustration. ACS Appl. Mater. Interface 9, 8649–8658 (2017)CrossRef
4.
go back to reference C. Liu, J. Wang, J. Li, M. Zeng, R. Luo, Synthesisof N-doped hollow-structured mesoporous carbon nanospheres for high-perfor-mance supercapacitors. ACS Appl. Mater. Interface 8, 7194–7204 (2016)CrossRef C. Liu, J. Wang, J. Li, M. Zeng, R. Luo, Synthesisof N-doped hollow-structured mesoporous carbon nanospheres for high-perfor-mance supercapacitors. ACS Appl. Mater. Interface 8, 7194–7204 (2016)CrossRef
5.
go back to reference X. Meng, L. Lu, C. Sun, Green synthesis of three-dimensional MnO2/graphene hydrogel composites as a high-performance electrode material for supercapacitors. ACS Appl. Mater. Interface 10, 16474–16481 (2018)CrossRef X. Meng, L. Lu, C. Sun, Green synthesis of three-dimensional MnO2/graphene hydrogel composites as a high-performance electrode material for supercapacitors. ACS Appl. Mater. Interface 10, 16474–16481 (2018)CrossRef
6.
go back to reference M.F. El-Kady, Y. Shao, R.B. Kaner, Graphene for batteries, supercapacitors and beyond. Nat. Rev. Mater. 1, 16033 (2016)CrossRef M.F. El-Kady, Y. Shao, R.B. Kaner, Graphene for batteries, supercapacitors and beyond. Nat. Rev. Mater. 1, 16033 (2016)CrossRef
7.
go back to reference Z. Pan, Y. Jiang, P. Yang, Z. Wu, W. Tian, In situ growth of layered bimetallic ZnCo hydroxide nanosheets for high-performance all-solid-state pseudocapacitor. ACS Nano 12, 2968–2979 (2018)CrossRef Z. Pan, Y. Jiang, P. Yang, Z. Wu, W. Tian, In situ growth of layered bimetallic ZnCo hydroxide nanosheets for high-performance all-solid-state pseudocapacitor. ACS Nano 12, 2968–2979 (2018)CrossRef
8.
go back to reference W. Li, M. Wu, P. Shi, T. Li, H. Yue, Enhanced energy storage performance of advanced hybrid supercapacitors derived from ultrafine Ni–P@Ni nanotubes with novel three-dimensional porous network synthesized via reaction temperatures regulation. Electrochim. Acta 331, 135440 (2020)CrossRef W. Li, M. Wu, P. Shi, T. Li, H. Yue, Enhanced energy storage performance of advanced hybrid supercapacitors derived from ultrafine Ni–P@Ni nanotubes with novel three-dimensional porous network synthesized via reaction temperatures regulation. Electrochim. Acta 331, 135440 (2020)CrossRef
9.
go back to reference T. Ling, P. Da, X. Zheng, B. Ge, Atomic-level structure engineering of metal oxides for high-rate oxygen intercalation pseudocapacitance. Sci. Adv. 4, eaau6261 (2018)CrossRef T. Ling, P. Da, X. Zheng, B. Ge, Atomic-level structure engineering of metal oxides for high-rate oxygen intercalation pseudocapacitance. Sci. Adv. 4, eaau6261 (2018)CrossRef
10.
go back to reference A. Belhboub, S. Patrice, M. Céline, On the development of an original mesoscopic model to predict the capacitive properties of carbon-carbon supercapacitors. Electrochim. Acta 327, 135022 (2019)CrossRef A. Belhboub, S. Patrice, M. Céline, On the development of an original mesoscopic model to predict the capacitive properties of carbon-carbon supercapacitors. Electrochim. Acta 327, 135022 (2019)CrossRef
11.
go back to reference J. Wang, C. Cui, W. Qian, Highly electroconductive mesoporous activated carbon fibers and their performance of the ionic liquid-based electrical double-layer capacitors. Carbon 154, 1–6 (2019)CrossRef J. Wang, C. Cui, W. Qian, Highly electroconductive mesoporous activated carbon fibers and their performance of the ionic liquid-based electrical double-layer capacitors. Carbon 154, 1–6 (2019)CrossRef
12.
go back to reference L. Kou, Z. Liu, T. Huang, B. Zheng, Wet-spun, porous, orientational graphene hydrogel films for high-performance supercapacitor electrodes. Nanoscale 7, 4080–4087 (2015)CrossRef L. Kou, Z. Liu, T. Huang, B. Zheng, Wet-spun, porous, orientational graphene hydrogel films for high-performance supercapacitor electrodes. Nanoscale 7, 4080–4087 (2015)CrossRef
13.
go back to reference L. Song, X. Cao, L. Li, Q. Wang, General method for large-area Films of carbon nanomaterials and application of a self-assembled carbon nanotube film as a high-performance electrode material for an all-solid-state supercapacitor. Adv. Funct. Mater. 27, 1700474 (2017)CrossRef L. Song, X. Cao, L. Li, Q. Wang, General method for large-area Films of carbon nanomaterials and application of a self-assembled carbon nanotube film as a high-performance electrode material for an all-solid-state supercapacitor. Adv. Funct. Mater. 27, 1700474 (2017)CrossRef
14.
go back to reference A.T. Aqueel Ahmed, B. Hou, H.S. Chavan, Y. Jo, S. Cho, J. Kim, S.M. Pawar, S. Cha, A.I. Inamdar, H. Kim, Im H Self-assembled nanostructured CuCo2O4 for electrochemical energy storage and the oxygen evolution reaction via morphology engineering. Small 14, 1800742 (2018)CrossRef A.T. Aqueel Ahmed, B. Hou, H.S. Chavan, Y. Jo, S. Cho, J. Kim, S.M. Pawar, S. Cha, A.I. Inamdar, H. Kim, Im H Self-assembled nanostructured CuCo2O4 for electrochemical energy storage and the oxygen evolution reaction via morphology engineering. Small 14, 1800742 (2018)CrossRef
15.
go back to reference J. Bao, Z. Wang, W. Liu, L. Xu, F. Lei, J. Xie, ZnCo2O4 ultrathin nanosheets towards the high performance of flexible supercapacitors and bifunctional electrocatalysis. J. Alloys Compd. 764, 565–573 (2018)CrossRef J. Bao, Z. Wang, W. Liu, L. Xu, F. Lei, J. Xie, ZnCo2O4 ultrathin nanosheets towards the high performance of flexible supercapacitors and bifunctional electrocatalysis. J. Alloys Compd. 764, 565–573 (2018)CrossRef
16.
go back to reference H. Yang, F. Hu, Y. Zhang, L. Shi, Q. Wang, Controlled synthesis of porous spinel cobalt manganese oxides as efficient oxygen reduction reaction electrocatalysts. Nano Res. 9, 207–213 (2016)CrossRef H. Yang, F. Hu, Y. Zhang, L. Shi, Q. Wang, Controlled synthesis of porous spinel cobalt manganese oxides as efficient oxygen reduction reaction electrocatalysts. Nano Res. 9, 207–213 (2016)CrossRef
17.
go back to reference T. Zhang, C. He, F. Sun, Y. Ding, M. Wang, L. Peng, J. Wang, Y. Lin, Co3O4 nanoparticles anchored on nitrogen-doped reduced graphene oxide as a multifunctional catalyst for H2O2 reduction, oxygen reduction and evolution reaction. Sci. Rep. 7, 43638 (2017)CrossRef T. Zhang, C. He, F. Sun, Y. Ding, M. Wang, L. Peng, J. Wang, Y. Lin, Co3O4 nanoparticles anchored on nitrogen-doped reduced graphene oxide as a multifunctional catalyst for H2O2 reduction, oxygen reduction and evolution reaction. Sci. Rep. 7, 43638 (2017)CrossRef
18.
go back to reference S. Cui, L. Sun, F. Kong, L. Huo, H. Zhao, Carbon-coated MnCo2O4 nanowire as bifunctional oxygen catalysts for rechargeable Zn-air batteries. J. Power Sources 430, 25–31 (2019)CrossRef S. Cui, L. Sun, F. Kong, L. Huo, H. Zhao, Carbon-coated MnCo2O4 nanowire as bifunctional oxygen catalysts for rechargeable Zn-air batteries. J. Power Sources 430, 25–31 (2019)CrossRef
19.
go back to reference H.B. Wu, J.S. Chen, H.H. Hong, X.W. Lou, Nanostructured metal oxide-based materials as advanced anodes for lithium-ion batteries. Nanoscale 4, 2526–2542 (2012)CrossRef H.B. Wu, J.S. Chen, H.H. Hong, X.W. Lou, Nanostructured metal oxide-based materials as advanced anodes for lithium-ion batteries. Nanoscale 4, 2526–2542 (2012)CrossRef
20.
go back to reference M.V. Reddy, G.V.S. Rao, B.V.R. Chowdari, Metal oxides and oxysalts as anode materials for Li ion batteries. Chem. Rev. 113, 5364–5457 (2013)CrossRef M.V. Reddy, G.V.S. Rao, B.V.R. Chowdari, Metal oxides and oxysalts as anode materials for Li ion batteries. Chem. Rev. 113, 5364–5457 (2013)CrossRef
21.
go back to reference G.T. Fu, Z. Liu, J. Zhang, J. Wu, L. Xu, D. Sun, J. Zhang, Y. Tang, P. Chen, Spinel MnCo2O4 nanoparticles cross-linked with two-dimensional porous carbon nanosheets as a high-efficiency oxygen reduction electrocatalyst. Nano Res. 9, 2110–2122 (2016)CrossRef G.T. Fu, Z. Liu, J. Zhang, J. Wu, L. Xu, D. Sun, J. Zhang, Y. Tang, P. Chen, Spinel MnCo2O4 nanoparticles cross-linked with two-dimensional porous carbon nanosheets as a high-efficiency oxygen reduction electrocatalyst. Nano Res. 9, 2110–2122 (2016)CrossRef
22.
go back to reference Y.G. Liang, H. Wang, J. Zhou, Y. Li, J. Wang, T. Regier, H. Dai, Covalent hybrid of spinel manganese-cobalt oxide and graphene as advanced oxygen reduction electrocatalysts. J. Am. Chem. Soc. 134, 3517–3523 (2012)CrossRef Y.G. Liang, H. Wang, J. Zhou, Y. Li, J. Wang, T. Regier, H. Dai, Covalent hybrid of spinel manganese-cobalt oxide and graphene as advanced oxygen reduction electrocatalysts. J. Am. Chem. Soc. 134, 3517–3523 (2012)CrossRef
23.
go back to reference J. Xu, Y. Sun, M. Lu, L. Wang, J. Zhang, Fabrication of the porous MnCo2O4 nanorod arrays on Ni foam as an advanced electrode for asymmetric supercapacitors. Acta Mater. 152, 162–174 (2018)CrossRef J. Xu, Y. Sun, M. Lu, L. Wang, J. Zhang, Fabrication of the porous MnCo2O4 nanorod arrays on Ni foam as an advanced electrode for asymmetric supercapacitors. Acta Mater. 152, 162–174 (2018)CrossRef
24.
go back to reference L.B. Kong, C. Lu, M.C. Liu, Y.C. Luo, L. Kang, X. Li, F.C. Walsh, The specific capacitance of sol-gel synthesised spinel MnCo2O4 in an alkaline electrolyte. Electrochim. Acta. 115, 22–27 (2014)CrossRef L.B. Kong, C. Lu, M.C. Liu, Y.C. Luo, L. Kang, X. Li, F.C. Walsh, The specific capacitance of sol-gel synthesised spinel MnCo2O4 in an alkaline electrolyte. Electrochim. Acta. 115, 22–27 (2014)CrossRef
25.
go back to reference V. Venkatachalam, A. Alsalme, A. Alghamdi, R. Jeyavel, High-performance electrochemical capacitor based on MnCo2O4 nanostructured electrode. J. Electroanal. Chem. 756, 94–100 (2015)CrossRef V. Venkatachalam, A. Alsalme, A. Alghamdi, R. Jeyavel, High-performance electrochemical capacitor based on MnCo2O4 nanostructured electrode. J. Electroanal. Chem. 756, 94–100 (2015)CrossRef
26.
go back to reference H. Che, A. Liu, J. Mu, C. Wu, X. Zhang, Template-free synthesis of novel flower-like MnCo2O4 hollow microspheres for application in supercapacitors. Ceram. Int. 42, 2416–2424 (2016)CrossRef H. Che, A. Liu, J. Mu, C. Wu, X. Zhang, Template-free synthesis of novel flower-like MnCo2O4 hollow microspheres for application in supercapacitors. Ceram. Int. 42, 2416–2424 (2016)CrossRef
27.
go back to reference A.K. Mondal, D. Su, S. Chen, A. Ung, H.S. Kim, G. Wang, Mesoporous MnCo2O4 with a flake-like structure as advanced materials for lithium-ion batteries and supercapacitors. Chem. A 21, 1526–1532 (2015) A.K. Mondal, D. Su, S. Chen, A. Ung, H.S. Kim, G. Wang, Mesoporous MnCo2O4 with a flake-like structure as advanced materials for lithium-ion batteries and supercapacitors. Chem. A 21, 1526–1532 (2015)
28.
go back to reference R. Ding, Z. Li, C. Wang, M. Chen, Porous MnCo2O4-TiO2 microspheres with a yolk-shell structure for lithium-ion battery applications. J. Alloys Compd. 726, 445–452 (2017)CrossRef R. Ding, Z. Li, C. Wang, M. Chen, Porous MnCo2O4-TiO2 microspheres with a yolk-shell structure for lithium-ion battery applications. J. Alloys Compd. 726, 445–452 (2017)CrossRef
29.
go back to reference C. Chen, B. Liu, Q. Ru, S. Ma, B. An, X. Hou, S. Hu, Fabrication of cubic spinel MnCo2O4 nanoparticles embedded in graphene sheets with their improved lithium-ion and sodium-ion storage properties. J. Power. Sources. 326, 252–263 (2016)CrossRef C. Chen, B. Liu, Q. Ru, S. Ma, B. An, X. Hou, S. Hu, Fabrication of cubic spinel MnCo2O4 nanoparticles embedded in graphene sheets with their improved lithium-ion and sodium-ion storage properties. J. Power. Sources. 326, 252–263 (2016)CrossRef
30.
go back to reference L. Li, Y.Q. Zhang, X.Y. Liu, S.J. Shi, X.Y. Zhao, H. Zhang, X. Ge, G.F. Cai, C.D. Gu, X.L. Wang, J.P. Tu, One-dimension MnCo2O4 nanowire arrays for electrochemical energy storage. Electrochim. Acta 116, 467–474 (2014)CrossRef L. Li, Y.Q. Zhang, X.Y. Liu, S.J. Shi, X.Y. Zhao, H. Zhang, X. Ge, G.F. Cai, C.D. Gu, X.L. Wang, J.P. Tu, One-dimension MnCo2O4 nanowire arrays for electrochemical energy storage. Electrochim. Acta 116, 467–474 (2014)CrossRef
31.
go back to reference W. Liu, H. Niu, J. Yang, K. Cheng, K. Ye, Ternary transition metal sulfides embedded in graphene nanosheets as both the anode and cathode for high- performance asymmetric supercapacitors. Chem. Mater. 30, 1055–1068 (2018)CrossRef W. Liu, H. Niu, J. Yang, K. Cheng, K. Ye, Ternary transition metal sulfides embedded in graphene nanosheets as both the anode and cathode for high- performance asymmetric supercapacitors. Chem. Mater. 30, 1055–1068 (2018)CrossRef
32.
go back to reference T. Pettong, P. Iamprasertkun, A. Krittayavathananon, P. Sukha, High-performance asymmetric supercapacitors of MnCo2O4 nanofibers and N-doped reduced graphene oxide aerogel. ACS Appl. Mater. Interfaces 8, 34045–34053 (2016)CrossRef T. Pettong, P. Iamprasertkun, A. Krittayavathananon, P. Sukha, High-performance asymmetric supercapacitors of MnCo2O4 nanofibers and N-doped reduced graphene oxide aerogel. ACS Appl. Mater. Interfaces 8, 34045–34053 (2016)CrossRef
Metadata
Title
Nanosized-MnCo2O4-embedded 1D carbon nanofibres for supercapacitor with promising electrochemical properties
Authors
Hongquan Yu
Hengyan Zhao
Yanbo Wu
Baojiu Chen
Jiashi Sun
Lihong Cheng
Xiangping Li
Jinsu Zhang
Sai Xu
Publication date
07-07-2020
Publisher
Springer US
Published in
Journal of Materials Science: Materials in Electronics / Issue 16/2020
Print ISSN: 0957-4522
Electronic ISSN: 1573-482X
DOI
https://doi.org/10.1007/s10854-020-03915-5

Other articles of this Issue 16/2020

Journal of Materials Science: Materials in Electronics 16/2020 Go to the issue