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03-10-2020 | Original Research

NaOH(KOH)-catalyzed vinylation of cellulose with acetylene gas in water

Authors: Lidiya N. Parshina, Ludmila A. Oparina, Anatolii P. Tantsyrev, Nina K. Gusarova, Boris A. Trofimov

Published in: Cellulose | Issue 16/2020

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Abstract

Diverse mercerized celluloses (powder cellulose and kraft pulp) have been successfully vinylated with acetylene in an aqueous solution of alkali metal hydroxides (KOH or NaOH) at 125–140 °C. Depending on the reaction conditions, degree of substitution (DS) of the hydroxyl groups by highly reactive polymerazable vinyloxy groups ranges 0.08–0.73, the yields of vinyl celluloses being 24–75%. The process is accompanied by alkaline degradation of the cellulose macromolecule.

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Title: NaOH(KOH)-catalyzed vinylation of cellulose with acetylene gas in water
Authors: Lidiya N. Parshina
Ludmila A. Oparina
Anatolii P. Tantsyrev
Nina K. Gusarova
Boris A. Trofimov
Publication date: 03-10-2020
Publisher: Springer Netherlands
Published in: Cellulose / Issue 16/2020
Print ISSN: 0969-0239
Electronic ISSN: 1572-882X
DOI: https://doi.org/10.1007/s10570-020-03435-9

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