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Journal of Polymer Research
Published in: Journal of Polymer Research 6/2020

01-06-2020 | ORIGINAL PAPER

Novel poly(3-hydroxy butyrate) macro RAFT agent. Synthesis and characterization of thermoresponsive block copolymers

Authors: Baki Hazer, Melike Eren, Yetkin Senemoğlu, Tina Modjinou, Estelle Renard, Valérie Langlois

Published in: Journal of Polymer Research | Issue 6/2020

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Abstract

A novel reversible addition fragmentation transfer (RAFT) agent based on the poly-3-hydroxy butyrate (PHB) with three hydroxyl groups (PHB-R2) and thermoresponsive amphiphilic block copolymers derived from N-isopropyl acryl amide (NIPAM) are described. Hydroxylated PHB is obtained by the reaction between PHB and diethanol amine (DEA) to prepare hydroxylated PHB (PHB-DEA). It is then reacted with a RAFT agent, 2-(dodecylthiocarbonothioylthio)-2-methylpropionic acid (DDMAT). Hydroxyl ends of the hydroxylated PHB are capped with carboxylic acid end of the trithiocarbonate. The block copolymers obtained by the polymerization of NIPAM initiated by PHB-R2 were characterized by 1H NMR and physicochemical techniques. PHB content in the obtained block copolymers is varying between 14 and 45 wt%. The thermo-responsive PHB-PNIPAM block copolymers show the lower critical solution temperature (LCST) 28 and 30 °C while LCST of the pure PNIPAM is 32 °C.
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Metadata
Title
Novel poly(3-hydroxy butyrate) macro RAFT agent. Synthesis and characterization of thermoresponsive block copolymers
Authors
Baki Hazer
Melike Eren
Yetkin Senemoğlu
Tina Modjinou
Estelle Renard
Valérie Langlois
Publication date
01-06-2020
Publisher
Springer Netherlands
Published in
Journal of Polymer Research / Issue 6/2020
Print ISSN: 1022-9760
Electronic ISSN: 1572-8935
DOI
https://doi.org/10.1007/s10965-020-02133-1

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