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Colloid and Polymer Science
Published in: Colloid and Polymer Science 10/2017

16-07-2017 | Original Contribution

Novel preparation of Fe3O4/styrene-co-butyl acrylate composite microspheres via a phase inversion emulsion process

Author: Yufeng Duan

Published in: Colloid and Polymer Science | Issue 10/2017

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Abstract

A new approach to prepare the magnetic composite microspheres of Fe3O4 and copolymer of styrene-co-butyl acrylate was reported by a phase inversion emulsion technique. During the phase inversion process, the system converts from a continuous bulk organic phase to a continuous aqueous phase dispersed with organic drops composed of monomers, polymers, and Fe3O4 particles. The obtained Fe3O4/styrene-co-butyl acrylate composite microspheres were mostly spherical with a diameter in the range of a few micrometers to dozens of micrometers. Also, large amounts of Fe3O4 particles present in the interior of the microspheres and some were embedded in the surface. The results from X-ray powder diffraction indicated the crystal structure of Fe3O4 was not changed during the preparation of microspheres. According to TGA curve, the content of Fe3O4 particles in microspheres reached approximately 48%. The microspheres exhibited superparamagnetism. High-magnetic-content microspheres can be easily obtained by this method.
previous article Micromorphology, phase behavior, and properties of environmental, multi-cross-linked polyurethane/polyacrylate microemulsions based on in situ surfactant-free polymerization
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Metadata
Title
Novel preparation of Fe3O4/styrene-co-butyl acrylate composite microspheres via a phase inversion emulsion process
Author
Yufeng Duan
Publication date
16-07-2017
Publisher
Springer Berlin Heidelberg
Published in
Colloid and Polymer Science / Issue 10/2017
Print ISSN: 0303-402X
Electronic ISSN: 1435-1536
DOI
https://doi.org/10.1007/s00396-017-4154-1

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