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01-04-2019 | Original Research

One-pot catalytic hydrogenolysis of rice straw into biogasoline

Authors: Yang Peng, Teng Li, Xianghua Li, Tian Gao, Weiran Yang

Published in: Cellulose | Issue 15/2019

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Abstract

The waste rice straw is a sustainable bioresource with large reserves and low-cost, thus can be used to produce fuels and chemicals to enhance its value. In this paper, we have developed a new method to convert rice straw into biogasoline with high yield in one step by using multifunctional catalyst of RhCl₃/NaI/HCl/H₂ in a biphasic reaction system. Lipid and lignin in the rice straw hindered its conversion and need to be removed by pretreatment. The major products are C5 and C6 furan, furfural, and cyclic ketones, which are low in oxygen content and can be used as biogasoline. Under the optimal reaction conditions (140 °C, 4 h, 300 psi H₂, toluene to water volume ration 1:1), C5 from hemicellulose with 77.2% yield and C6 from cellulose with 71.7% yield can be obtained. The total biogasoline yield based on dry rice straw is 23.5 wt%, which is quite significant. The mechanism of the conversion process was also well studied.

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Title: One-pot catalytic hydrogenolysis of rice straw into biogasoline
Authors: Yang Peng
Teng Li
Xianghua Li
Tian Gao
Weiran Yang
Publication date: 01-04-2019
Publisher: Springer Netherlands
Published in: Cellulose / Issue 15/2019
Print ISSN: 0969-0239
Electronic ISSN: 1572-882X
DOI: https://doi.org/10.1007/s10570-019-02403-2

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