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Published in: Cellulose 6/2020

24-01-2020 | Original Research

One-pot synthesis of HMF from carbohydrates over acid-base bi-functional carbonaceous catalyst supported on halloysite nanotubes

Authors: Yunlei Zhang, Bing Li, Wen Guan, Yanan Wei, Changhao Yan, Minjia Meng, Jianming Pan, Yongsheng Yan

Published in: Cellulose | Issue 6/2020

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Abstract

Nitrogen-doped carbon materials have attracted enormous interest in catalysis owing to their outstanding catalytic performance. In this work, nitrogen-doped carbonaceous catalysts (NCC) supported on inexpensive and naturally abundant halloysite nanotubes were successfully synthesized via precipitation polymerization, calcination, and sulfonation processes. The physical and chemical properties of the obtained catalysts were systematically characterized by different methods. The results indicated that NCC catalysts had mesoporous structures, excellent thermostability and acid-base bi-functional active sites. One-pot synthesis of 5-hydroxymethylfurfural (HMF) from glucose was performed to investigate the synthesized NCC catalysts. Benefiting from the synergistic effects of the acid-base bi-functional active sites, the highest HMF yield (62.8%) was achieved in an isopropanol-mediated DMSO system under optimal conditions. Moderate to excellent yields of HMF were also obtained from one-pot conversions of other carbohydrates, including inulin, sucrose, cellobiose, maltose and starch, with our developed catalytic system. The one-pot production of HMF from cellulose was also smoothly processed by the NCC bi-functional catalyst in an IL-based system. This work has developed a versatile strategy for designing nitrogen-doped carbonaceous catalysts that can be employed for the direct transformation of renewable carbohydrates to platform chemicals.

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Appendix
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Metadata
Title
One-pot synthesis of HMF from carbohydrates over acid-base bi-functional carbonaceous catalyst supported on halloysite nanotubes
Authors
Yunlei Zhang
Bing Li
Wen Guan
Yanan Wei
Changhao Yan
Minjia Meng
Jianming Pan
Yongsheng Yan
Publication date
24-01-2020
Publisher
Springer Netherlands
Published in
Cellulose / Issue 6/2020
Print ISSN: 0969-0239
Electronic ISSN: 1572-882X
DOI
https://doi.org/10.1007/s10570-020-02994-1

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