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01-06-2010 | Research Paper

Optical properties of transparent barium titanate nanoparticle/polymer hybrid synthesized from metal alkoxides

Authors: Ken-ichi Mimura, Kosuke Hiramatsu, Makoto Moriya, Wataru Sakamoto, Satoshi Kawado, Yoshiaki Uesu, Toshinobu Yogo

Published in: Journal of Nanoparticle Research | Issue 5/2010

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Abstract

A transparent BaTiO₃ particle/polymer hybrid was synthesized from a Ba–Ti double alkoxide modified with an organic ligand and its refractive index and second harmonic generation were studied. BaTiO₃ particles modified with 2-vinyloxyethanol (ethylene glycol monovinyl ether, EGMVE) were polymerized with methyl methacrylate (MMA) yielding the transparent BaTiO₃ particle/poly MMA hybrid. X-ray photoelectron spectra indicated that the formation of chemical bonds between BaTiO₃ nanoparticles and the organic matrix. The refractive indexes of the hybrid films depended on the crystallite size of BaTiO₃ nanoparticles and the volume fractions of BaTiO₃ and polymer phases. The hybrid film synthesized at BaTiO₃/8EGMVE/30H₂O/PMMA revealed a refractive index of 1.65 at 589 nm with an Abbe number of 54. The hybrid film exhibited a second harmonic wave of 532 nm on irradiation with a fundamental wave of 1,064 nm.

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Title: Optical properties of transparent barium titanate nanoparticle/polymer hybrid synthesized from metal alkoxides
Authors: Ken-ichi Mimura
Kosuke Hiramatsu
Makoto Moriya
Wataru Sakamoto
Satoshi Kawado
Yoshiaki Uesu
Toshinobu Yogo
Publication date: 01-06-2010
Publisher: Springer Netherlands
Published in: Journal of Nanoparticle Research / Issue 5/2010
Print ISSN: 1388-0764
Electronic ISSN: 1572-896X
DOI: https://doi.org/10.1007/s11051-009-9758-z

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