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Journal of Nanoparticle Research
Published in: Journal of Nanoparticle Research 9/2019

01-09-2019 | Research Paper

Pd-P nanoparticles as active catalyst for the hydrogenation of acetylenic compounds

Authors: Lyudmila B. Belykh, Nikita I. Skripov, Tatyana P. Sterenchuk, Kseniya L. Gvozdovskaya, Seseg B. Sanzhieva, Fedor K. Schmidt

Published in: Journal of Nanoparticle Research | Issue 9/2019

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Abstract

Pd-P nanoparticles were obtained by low-temperature reduction of Pd(acac)2 with hydrogen in the presence of elemental phosphorus. Using the EDX analysis, XRD, and HRTEM, the composition, size, and morphology of the particles were determined for different P:Pd ratios. The results of testing Pd-P nanoparticles showed that they are 8–9 times higher in activity in the hydrogenation of mono- and di-substituted acetylenic compounds than Pd-black and phase-pure Pd3P phosphide, while maintaining high selectivity to alkenes at 95–98% conversion of alkynes. Colloidal solutions of Pd-P nanoparticles can act as long-lived supported catalysts (TON = 27,444 mol PA·(mol Pd total)−1). The effect of the P:Pd ratio on the change in the rates of hydrogenation of alkyne (r1) and the resulting alkene (r2) under the action of Pd-P nanoparticles has been found and experimentally substantiated. Electron-deficient small clusters of palladium contained along with palladium phosphides in the Pd-P nanoparticles are responsible for the decrease in the ratio r1:r2 in the ratio range P:Pd = 1–1.5.
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Appendix
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Metadata
Title
Pd-P nanoparticles as active catalyst for the hydrogenation of acetylenic compounds
Authors
Lyudmila B. Belykh
Nikita I. Skripov
Tatyana P. Sterenchuk
Kseniya L. Gvozdovskaya
Seseg B. Sanzhieva
Fedor K. Schmidt
Publication date
01-09-2019
Publisher
Springer Netherlands
Published in
Journal of Nanoparticle Research / Issue 9/2019
Print ISSN: 1388-0764
Electronic ISSN: 1572-896X
DOI
https://doi.org/10.1007/s11051-019-4641-z

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