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Rheologica Acta

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18-04-2020 | Original Contribution

Phase state and rheology of polyisobutylene blends with silicone resin

Authors: Sergey O. Ilyin, Veronika V. Makarova, Mariya Y. Polyakova, Valery G. Kulichikhin

Published in: Rheologica Acta | Issue 6/2020

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Abstract

Silicone resins are hyperbranched macromolecules, which are nearly spherical in shape, nanometer in size, and covered with numerous terminal organic groups. For this reason, they can play a role of functionalized silica nanoparticles that are miscible with a polymer medium. In this paper, mixtures of linear polyisobutylene (PIB) with methyl-terminated silicone MT resin are considered. The phase states of mixtures were studied by laser interferometry method accompanied with rheological tests. It turned out that the solubility of the silicone resin in PIB matrix does not exceed a few percent even at high temperatures. Nevertheless, the addition of the resin significantly reduces the effective viscosity of PIB due to the shear-induced interlayer slip. To describe the concentration dependence of the blend viscosity, various empirical equations were considered, and their combination to describe the viscosity of blends in different phase states by one equation was proposed.

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Amirova AI, Golub OV, Meshkov IB, Migulin DA, Muzafarov AM, Filippov AP (2015) Solution behavior of hyperbranched polymethylsilsesquioxane with intramolecular cycles. Int J Polym Anal Charact 20(3):268–276CrossRef

Anokhina TS, Ilyin SO, Ignatenko VY, Bakhtin DS, Kostyuk AV, Antonov SV, Volkov AV (2019) Formation of porous films with hydrophobic surface from a blend of polymers. Polym Sci Ser A 61(5):619–626CrossRef

Antonow GN (1907) Sur la tension superficielle a la limite de deux couches. J Chim Phys 5:372–385CrossRef

Arrhenius S (1887) Über die innere Reibung verdünnter wässeriger Lösungen. Z Physik Chem 1:285–298

Baumann TF, Jones TV, Wilson T, Saab AP, Maxwell RS (2009) Synthesis and characterization of novel PDMS nanocomposites using POSS derivatives as cross-linking filler. J Polym Sci Part A 47(10):2589–2596CrossRef

Carr PL, Davies GR, Feast WJ, Stainton NM, Ward IM (1996) Dielectric and mechanical characterization of aryl ester dendrimer/PET blends. Polymer 37(12):2395–2401CrossRef

Chacko RT, Ventura J, Zhuang J, Thayumanavan S (2012) Polymer nanogels: a versatile nanoscopic drug delivery platform. Adv Drug Deliv Rev 64(9):836–851CrossRef

Chalykh AE, Gerasimov VK (2004) Phase equilibria and phase structures of polymer blends. Russ Chem Rev 73(1):59–74CrossRef

Chen D, Chen F, Hu X, Zhang H, Yin X, Zhou Y (2015) Thermal stability, mechanical and optical properties of novel addition cured PDMS composites with nano-silica sol and MQ silicone resin. Compos Sci Technol 117:307–314CrossRef

Chen W, Lupton KE, Romenesko DJ, Schmidt RG, Zhang H (1999) Organic polymers modified with thermoplastic silicone blends. US Patent:5861450

Chuang HK, Han CD (1984) Rheological behavior of polymer blends. J Appl Polym Sci 29:2205–2229CrossRef

Clarson SJ, Semlyen JA (1993) Siloxane polymers. Prentice Hall, New Jersey

Cox WP, Merz EH (1958) Correlation of dynamic and steady flow viscosities. J Polym Sci 28(118):619–622CrossRef

Deng F, Wang X, He D, Hu J, Gong C, Ye YS, Xie X, Xue Z (2015) Microporous polymer electrolyte based on PVDF/PEO star polymer blends for lithium ion batteries. J Membr Sci 491:82–89CrossRef

Derkach SR (2009) Rheology of emulsions. Adv Colloid Interf Sci 151(1–2):1–23CrossRef

Edmondson S, Osborne VL, Huck WTS (2004) Polymer brushes via surface-initiated polymerizations. Chem Soc Rev 33:14–22CrossRef

Flagg DH, McCarthy TJ (2016) Rediscovering silicones: MQ copolymers. Macromolecules 49(22):8581–8592CrossRef

Grace HP (1982) Dispersion phenomena in high viscosity immiscible fluid systems and application of static mixers as dispersion devices in such systems. Chem Eng Commun 14(3–6):225–277CrossRef

Guido S, Simeone M, Villone M (1999) Diffusion effects on the interfacial tension of immiscible polymer blends. Rheol Acta 38:287–296CrossRef

Han CD, Kim J, Kim JK (1989) Determination of the order-disorder transition temperature of block copolymers. Macromolecules 22(1):383–394CrossRef

Hashimoto T, Takebe T, Asakawa K (1993) Phase transition of polymer mixtures under simple shear flow. Physica Part A 194(1–4):338–351CrossRef

Hayashi H, Flory PJ, Wignall GD (1983) Configuration of the polyisobutylene chain according to neutron and X-ray scattering. Macromolecules 16(8):1328–1335CrossRef

Heitmiller RF, Naar RZ, Zabusky HH (1964) Effect of homogeneity on viscosity in capillary extrusion of polyethylene. J Appl Polym Sci 8(2):873–880CrossRef

Hennequin Y, Evens M, Angulo CMQ, van Duijneveldt JS (2005) Miscibility of small colloidal spheres with large polymers in good solvent. J Chem Phys 123(054906):1–8

Holtel D, Burgath A, Frey H (1997) Degree of branching in hyperbranched polymers. Acta Polymer 48:30–35CrossRef

Huang J, Turner SR (2018) Hypercrosslinked polymers: a review. Polym Rev 58:1–41CrossRef

Hurd CB (1946) Studies on siloxanes. I. The specific volume and viscosity in relation to temperature and constitution. J Am Chem Soc 68:364–370CrossRef

Ignatenko VY, Anokhina TS, Ilyin SO, Kostyuk AV, Bakhtin DS, Antonov SV, Volkov AV (2020) Fabrication of microfiltration membranes from polyisobutylene/polymethylpentene blends. Polym Int 69(2):165–172CrossRef

Ilyin SO, Kulichikhin VG, Malkin AY (2016a) The rheological characterisation of typical injection implants based on hyaluronic acid for contour correction. Rheol Acta 55(3):223–233CrossRef

Ilyin SO, Makarova VV, Anokhina TS, Ignatenko VY, Brantseva TV, Volkov AV, Antonov SV (2018) Diffusion and phase separation at the morphology formation of cellulose membranes by regeneration from N-methylmorpholine N-oxide solutions. Cellulose 25(4):2515–2530CrossRef

Ilyin SO, Polyakova MY, Makarova VV, Meshkov IB, Kulichikhin VG (2016b) Phase state and rheology of organosilicon nanocomposites with functionalized hyperbranched nanoparticles. Polym Sci Ser A 58(6):985–993CrossRef

Iza M, Bousmina M (2000) Nonlinear rheology of immiscible polymer blends: step strain experiments. J Rheol 44:1363–1384CrossRef

Jackson NE, Tucker CL III (2003) A model for large deformation of an ellipsoidal droplet with interfacial tension. J Rheol 47:659–682CrossRef

Jia P, Liu H, Liu Q, Cai X (2016) Thermal degradation mechanism and flame retardancy of MQ silicone/epoxy resin composites. Polym Degrad Stab 134:144–150CrossRef

Kakkar A (2017) Miktoarm star polymers: from basics of branched architecture to synthesis, self-assembly and applications. Royal Society of Chemistry, LondonCrossRef

Kammer HW, Kummerloewe C, Kressler J, Melior JP (1991) Shear-induced phase changes in polymer blends. Polymer 32(8):1488–1492CrossRef

Kango S, Kalia S, Celli A, Njuguna J, Habibi Y, Kumar R (2013) Surface modification of inorganic nanoparticles for development of organic–inorganic nanocomposites—a review. Prog Polym Sci 38(8):1232–1261CrossRef

Karpukhina EA, Ilyin SO, Makarova VV, Meshkov IB, Kulichikhin VG (2014) Phase state and rheology of polyisobutylene mixtures with decyl surface modified silica nanoparticles. Polym Sci Ser A 56(6):798–811CrossRef

Kazakova VV, Rebrov EA, Myakushev VB, Strelkova TV, Ozerin AN, Ozerina LA, Chenskaya TB, Sheiko SS, Sharipov EY, Muzafarov AM (2000) From a hyperbranched polyethoxysiloxane toward molecular forms of silica: a polymer-based approach to the monitoring of silica properties. ACS Symp Ser 729:503–515CrossRef

Kopesky ET, Haddad TS, McKinley GH, Cohen RE (2005) Miscibility and viscoelastic properties of acrylic polyhedral oligomeric silsesquioxane–poly (methyl methacrylate) blends. Polymer 46(13):4743–4752CrossRef

Kumar SK, Jouault N, Benicewicz B, Neely T (2013) Nanocomposites with polymer grafted nanoparticles. Macromolecules 46(9):3199–3214CrossRef

Lederer A, Burchard W (2015) Hyperbranched polymers: macromolecules in between deterministic linear chains and dendrimer structures. Royal Society of Chemistry, London

Lee JH, Archer LA (2002) Stress relaxation of star/linear polymer blends. Macromolecules 35(17):6687–6696CrossRef

Li S, Lin Q, Cui C (2016) The effect of core–shell particles on the mechanical performance of epoxy resins modified with hyperbranched polymers. J Mater Res 31(10):1393–1402CrossRef

Liao YT, Lin YC, Kuo SW (2017) Highly thermally stable, transparent, and flexible polybenzoxazine nanocomposites by combination of double-decker-shaped polyhedral silsesquioxanes and polydimethylsiloxane. Macromolecules 50(15):5739–5747CrossRef

Lin CC (1979) A mathematical model for viscosity in capillary extrusion of two-component polyblends. Polym J 11(3):185–192CrossRef

Liu Q, Bao X, Deng S, Cai X (2014) The investigation of methyl phenyl silicone resin/epoxy resin using epoxy-polysiloxane as compatibilizer. J Therm Anal Calorim 118(1):247–254CrossRef

Lucas P, Robin JJ (2007) Silicone-based polymer blends: an overview of the materials and processes. Adv Polym Sci 209:111–147

Lucassen-Reynders EH (1993) Interfacial viscoelasticity in emulsions and foams. Food Struct 12(1):1–12

Ma PC, Siddiqui NA, Marom G, Kim JK (2010) Dispersion and functionalization of carbon nanotubes for polymer-based nanocomposites: a review. Compos Part A 41(10):1345–1367CrossRef

Maffettone PL, Greco F (2004) Ellipsoidal drop model for single drop dynamics with non-Newtonian fluids. J Rheol 48(1):83–100CrossRef

Maffettone PL, Minale M (1998) Equation of change for ellipsoidal drops in viscous flow. J Non-Newtonian Fluid Mech 78(2–3):227–241CrossRef

Malkin AY, Semakov AV, Kulichikhin VG (2010) Self-organization in the flow of complex fluids (colloid and polymer systems): Part 1: experimental evidence. Adv Colloid Interf Sci 157(1–2):75–90CrossRef

Makarova V, Kulichikhin V (2012) Application of interferometry to analysis of polymer-polymer and polymer-solvent interactions. In: Padron I (ed) Interferometry. Research and Applications in Science and Technology. InTech, Rijeka, pp 395–436

Marom G, Wagner HD (2017) Should polymer nanocomposites be regarded as molecular composites? J Mater Sci 52:8357–8361CrossRef

Marteaux L, Liles DT (2016) Silicone Dispersions. CRC Press, Boca Raton

McLeish TCB, O'Connor KP (1993) Rheology of star-linear polymer blends: molecular tube models. Polymer 34(14):2998–3003CrossRef

Marzi D, Capone B, Marakis J, Merola MC, Truzzolillo D, Cipelletti L, Moingeon F, Gauthier M, Vlassopoulos D, Likos CN, Camargo M (2015) Depletion, melting and reentrant solidification in mixtures of soft and hard colloids. Soft Matter 11(42):8296–8312CrossRef

Metelkin VI, Blekht VS (1984) Formation of a continuous phase in heterogeneous polymer mixtures. Colloid J 46(3):425–429

Mezzenga R, Boogh L, Månson JAE (2001) A review of dendritic hyperbranched polymer as modifiers in epoxy composites. Compos Sci Technol 61(5):787–795CrossRef

Migulin D, Tatarinova E, Meshkov I, Cherkaev G, Vasilenko N, Buzin M, Muzafarov A (2016) Synthesis of the first hyperbranched polyorganoethoxysilsesquioxanes and their chemical transformations to functional core–shell nanogel systems. Polym Int 65:72–83CrossRef

Minale M (2004) Deformation of a non-Newtonian ellipsoidal drop in a non-Newtonian matrix: extension of Maffettone–Minale model. J Non-Newton Fluid Mech 123(2–3):151–160CrossRef

Minale M (2010) Models for the deformation of a single ellipsoidal drop: a review. Rheol Acta 49(8):789–806CrossRef

Minale M, Moldenaers P, Mewis J (1997) Effect of shear history on the morphology of immiscible polymer blends. Macromolecules 30(18):5470–5475CrossRef

Nunez CM, Andrady AL, Guo RK, Baskir JN, Morgan DR (1998) Mechanical properties of blends of PAMAM dendrimers with poly(vinyl chloride) and poly(vinyl acetate). J Polym Sci Part A 36:2111–2117CrossRef

Nunez CM, Chiou BS, Andrady AL, Khan SA (2000) Solution rheology of hyperbranched polyesters and their blends with linear polymers. Macromolecules 33(5):1720–1726CrossRef

Ohno K, Morinaga T, Takeno S, Tsujii Y, Fukuda T (2007) Suspensions of silica particles grafted with concentrated polymer brush: effects of graft chain length on brush layer thickness and colloidal crystallization. Macromolecules 40(25):9143–9150CrossRef

Olabisi O, Robeson LM, Shaw MT (1979) Polymer-polymer miscibility. Academic Press, New York

Paul DR, Barlow JW (1980) Polymer blends. J Macromol Sci Rev Macromol Chem 18(1):109–168CrossRef

Peng X, Huang Y, Xia T, Kong M, Li G (2011) Shapes of dispersed phase in confined PIB/PDMS blends with different compositions during shear flow. Eur Polym J 47(10):1956–1963

Rahman IA, Padavettan V (2012) Synthesis of silica nanoparticles by sol-gel: size-dependent properties, surface modification, and applications in silica-polymer nanocomposites—a review. J Nanomater 2012:1687–4110CrossRef

Ratna D, Varley R, Raman RS, Simon GP (2003) Studies on blends of epoxy-functionalized hyperbranched polymer and epoxy resin. J Mater Sci 38(1):147–154CrossRef

Ristić S, Mijović J (2008) Dynamics in complex systems: Dendrimer–polymer blends in electric and mechanical fields. Polymer 49(21):4695–4702CrossRef

Robins MM (2000) Emulsions—creaming phenomena. Curr Opin Colloid Interface Sci 5:265–272CrossRef

Roldugin VI, Serenko OA, Getmanova EV, Novozhilova NA, Nikifirova GG, Buzin MI, Chvalun SN, Ozerin AN, Muzafarov AM (2016) Effect of hybrid nanoparticles on glass transition temperature of polymer nanocomposites. Polym Compos 37(7):1978–1990CrossRef

Rothon R (2017) Fillers for polymer applications. Springer, ChamCrossRef

van Ruymbeke E, Coppola S, Balacca L, Righi S, Vlassopoulos D (2010) Decoding the viscoelastic response of polydisperse star/linear polymer blends. J Rheol 54(3):507–538CrossRef

Schmaljohann D, Pötschke P, Hässler R, Voit BI, Froehling PE, Mostert B, Loontjens JA (1999) Blends of amphiphilic, hyperbranched polyesters and different polyolefins. Macromolecules 32(19):6333–6339CrossRef

Serenko OA, Roldugin VI, Novozhilova NA, Soldatov MA, Nikiforova GG, Mironova MV, Ilyin SO, Kulichikhin VG, Muzafarov AM (2015) Phase structure and properties of blends based on polystyrene and carbosilane dendrimers. Polym Sci Ser A 57(5):586–595CrossRef

Shi X, Chen Z, Yang Y (2014) Toughening of poly (l-lactide) with methyl MQ silicone resin. Eur Polym J 50:243–248CrossRef

Sperling RA, Parak WJ (2010) Surface modification, functionalization and bioconjugation of colloidal inorganic nanoparticles. Phil Trans R Soc Part A 368:1333–1383CrossRef

Thomas S, Grohens Y, Jyotishkumar P (2015) Characterization of polymer blends. Wiley, Weinheim

Thomas S, Muller R, Abraham J (2016) Rheology and processing of polymer nanocomposites. Wiley, HobokenCrossRef

Utracki LA (1991) On the viscosity-concentration dependence of immiscible polymer blends. J Rheol 35(8):1615–1637CrossRef

Utracki LA, Wilkie CA (2014) Polymer blends handbook, 2nd edn. Springer, Dordrecht

Vögtle F, Richardt G, Werner N (2009) Dendrimer chemistry. Wiley, WeinheimCrossRef

Vshivkov SA, Kulichikhin SG, Rusinova EV (1998) Phase transitions in polymer solutions induced by mechanical fields. Russ Chem Rev 67(3):233–243CrossRef

Xanthos M (2010) Functional fillers for plastics, 2nd edn. Wiley, WeinheimCrossRef

Yu W, Bousmina M (2003) Ellipsoidal model for droplet deformation in emulsions. J Rheol 47:1011–1039CrossRef

Zhang JF, Sun X (2004) Mechanical properties and crystallization behavior of poly (lactic acid) blended with dendritic hyperbranched polymer. Polym Int 53(6):716–722CrossRef

Zhang W, Camino G, Yang R (2017) Polymer/polyhedral oligomeric silsesquioxane (POSS) nanocomposites: an overview of fire retardance. Prog Polym Sci 67:77–125CrossRef

Zhang Y, Yang X, Zhao X, Huang W (2012) Synthesis and properties of optically clear silicone resin/epoxy resin hybrids. Polym Int 61:294–300CrossRef

Zhao J, Fu Y, Liu S (2008) Polyhedral oligomeric silsesquioxane (POSS)-modified thermoplastic and thermosetting nanocomposites: a review. Polym Polym Compos 16(8):483–500

Zhiltsov A, Gritsenko O, Kazakova V, Gorbatsevitch O, Bessonova N, Askadskii A, Serenko O, Muzafarov A (2015) Polylactide and hybrid silicasol nanoparticle-based composites. J Appl Polym Sci 132(17):41894–41903CrossRef

Title: Phase state and rheology of polyisobutylene blends with silicone resin
Authors: Sergey O. Ilyin
Veronika V. Makarova
Mariya Y. Polyakova
Valery G. Kulichikhin
Publication date: 18-04-2020
Publisher: Springer Berlin Heidelberg
Published in: Rheologica Acta / Issue 6/2020
Print ISSN: 0035-4511
Electronic ISSN: 1435-1528
DOI: https://doi.org/10.1007/s00397-020-01208-6

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