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2020 | OriginalPaper | Chapter

7. Phosphorus Sorption Characteristics of the Surface Sediments from Industrially Polluted GBPS Reservoir, India

Authors : Bijendra Kumar, Anshumali

Published in: Contemporary Environmental Issues and Challenges in Era of Climate Change

Publisher: Springer Singapore

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Abstract

Various kinetic models and isotherm have been used for deciphering mechanism of phosphorus (P) sorption on surface sediments of polluted freshwater bodies. The P sorption kinetics and equilibrium isotherm and the relationship between phosphorus sorption parameters were studied in 24 industrially contaminated surface sediments of Govind Ballabh Pant Sagar (GBPS) reservoir, India. The results showed that P adsorption on the sediments mainly occurred within 10 h and then reached equilibrium in 48 h; phosphate sorption rates of 0–0.25 h were the highest over 48 h and suggested quick sorption process; and the pseudo-second-order rate model showed the kinetics of P adsorption with high correlation coefficients. Native adsorbed phosphorus (W_NAP) and adsorption equilibrium concentration (C_EPC) were found to be high in surface sediments of the most polluted upstream region. The surface sediments showed maximum adsorption (Q_max, mg kg⁻¹) with 0.80 mg L⁻¹ phosphorus concentration. The equilibrium concentration of phosphorus (C_eq) was more than the C_EPC, while the W_NAP values were less than Q_max. The positive regression between W_NAP and C_EPC and K_p (partition coefficient) and Q_max indicated that surface sediments would act as a sink and adsorb phosphorus from overlying water in the GBPS reservoir.

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Title: Phosphorus Sorption Characteristics of the Surface Sediments from Industrially Polluted GBPS Reservoir, India
Authors: Bijendra Kumar
Anshumali
Publisher: Springer Singapore
Book: Contemporary Environmental Issues and Challenges in Era of Climate Change
Print ISBN: 978-981-329-594-0

Electronic ISBN: 978-981-329-595-7

Copyright Year: 2020
DOI: https://doi.org/10.1007/978-981-32-9595-7_7