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Polymer Bulletin

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02-03-2017 | Original Paper

Poly(1,4-butadiene)-graft-poly(L-lactide) via the grafting-from strategy

Authors: Flavien Leroux, Véronique Montembault, Sandie Piogé, Sagrario Pascual, Laurent Fontaine

Published in: Polymer Bulletin | Issue 11/2017

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Abstract

Poly(1,4-butadiene)-graft-poly(L-lactide) copolymers were efficiently prepared via the grafting-from strategy using a combination of ring-opening metathesis polymerization (ROMP) of a hydroxyl-functionalized cyclobutene monomer and organocatalyzed ring-opening polymerization (ROP) of L-lactide. The copolymers were characterized by NMR, MALDI-TOF, SEC, TGA, and DSC demonstrating that well-defined polyester-grafted poly(1,4-butadiene) were obtained through the reported methodology.

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Title: Poly(1,4-butadiene)-graft-poly(L-lactide) via the grafting-from strategy
Authors: Flavien Leroux
Véronique Montembault
Sandie Piogé
Sagrario Pascual
Laurent Fontaine
Publication date: 02-03-2017
Publisher: Springer Berlin Heidelberg
Published in: Polymer Bulletin / Issue 11/2017
Print ISSN: 0170-0839
Electronic ISSN: 1436-2449
DOI: https://doi.org/10.1007/s00289-017-1961-y

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