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Published in:
Basic Elements for Energy Storage and Conversion Read chapter Read first chapter

2016 | OriginalPaper | Chapter

7. Polyanionic Compounds as Cathode Materials

Authors : Christian Julien, Alain Mauger, Ashok Vijh, Karim Zaghib

Published in: Lithium Batteries

Publisher: Springer International Publishing

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Abstract

Polyanionic compounds have emerged as novel lithium insertion compounds and considered as the most advanced positive electrodes for the next generation of Li-ion batteries owing to their advantages with regard to low cost, non-toxicity, environmental friendliness, and high safety. From the safety view point, compared to metal-oxide cathodes, these materials rank number one, with a remarkable thermal stability and tolerance to overcharge and over-discharge. This chapter outlines the structural, physical, and electrochemical properties of lithium-phosphate compounds. Several aspects that are important for applications are discussed such as morphology upon synthesis, residual impurities and surface state of particles. These impurities are identified and a quantitative estimate of their concentrations is deduced from the combination of analytical methods. LiFePO4 has won the challenge to be the active element for the positive electrode of Li-ion batteries for electro-mobility. An optimized preparation provides materials with carbon-coated particles free of any impurity phase, insuring structural stability and electrochemical performance that justify the use of this material as a cathode element in new generation of lithium secondary batteries operating for powering hybrid electric vehicles and full electric vehicles.

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previous chapter Cathode Materials with Monoatomic Ions in a Three-Dimensional Framework
next chapter Fluoro-polyanionic Compounds
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Metadata
Title
Polyanionic Compounds as Cathode Materials
Authors
Christian Julien
Alain Mauger
Ashok Vijh
Karim Zaghib
Copyright Year
2016
Book
Lithium Batteries

Print ISBN: 978-3-319-19107-2

Electronic ISBN: 978-3-319-19108-9

Copyright Year: 2016

DOI
https://doi.org/10.1007/978-3-319-19108-9_7