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Journal of Coatings Technology and Research

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01-11-2013

Polydimethylsiloxane (PDMS)-based antibacterial organic–inorganic hybrid coatings

Authors: Burcu Oktay, Nilhan Kayaman-Apohan

Published in: Journal of Coatings Technology and Research | Issue 6/2013

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Abstract

UV-curable antibacterial organic–inorganic hybrid coatings were prepared by sol–gel method. Triethoxysilane-terminated poly(dimethylsiloxane) (TESi-PDMS) as a new coupling agent to improve the compatibility between organic and inorganic phases was synthesized. PDMS-based urethane methacrylate oligomer was obtained by reacting isophorone diisocyanate with hydroxyethyl methacrylate and hydroxyl-terminated PDMS. The formulations were applied onto polycarbonate panels and then cured by UV radiation. Physical properties of UV-cured free films such as gel content, stress–strain, and conversion of acrylate double bond were examined. In addition, the antibacterial effects of the coatings were investigated. Nanosilver-containing formulations exhibited high antibacterial effect against Escherichia coli and Staphylococcus aureus. Thermogravimetric analysis indicated that thermal stability of the hybrids was significantly higher than the organic polymer. Contact angle measurement showed that addition of silane precursor increased the contact angle from 95° to 110°.

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Talebian, N, Nilforoushan, MR, Zargar, EB, “Enhanced Antibacterial Performance of Hybrid Semiconductor Nanomaterials: ZnO/SnO₂ Nanocomposite Thin Films.” Appl. Surf. Sci., 258 (1) 547–555 (2011)CrossRef

Janardhanan, R, Karuppaiah, M, Hebalkar, N, Rao, TN, “Synthesis and Surface Chemistry of Nano Silver Particles.” Polyhedron, 28 (12) 2522–2530 (2009)CrossRef

Chen, X, Schluesener, HJ, “Nanosilver: A Nanoproduct in Medical Application.” Toxicol. Lett., 176 (1) 1–12 (2008)CrossRef

Lalueza, P, Monzón, M, Arruebo, M, Santamaria, J, “Antibacterial Action of Ag-Containing MFI Zeolite at Low Ag Loadings.” J. Chem. Commun., 47 (2) 680–682 (2011)CrossRef

Clement, JL, Jarrett, PS, “Antibacterial Silver. Met. Based.” Drugs, 1 (2) 467–482 (1994)

Yuranova, T, Rincon, AG, Bozzi, A, Parra, S, Pulgarin, C, Albers, P, Kiwi, J, “Antibacterial Textiles Prepared by RF-Plasma and Vacuum-UV Mediated Deposition of Silver.” Photochem. Photobiol.A: Chem., 161 (1) 27–34 (2003)CrossRef

Akhavan, O, Ghaderi, E, “Bactericidal Effects of Ag Nanoparticles İmmobilized on Surface of SiO₂ Thin Film with High Concentration.” Curr. Appl. Phys., 9 (6) 1381–1385 (2009)CrossRef

Percival, Sl, Bowler, PG, Russell, AD, “Bacterial Resistance to Silver in Wound Care.” J. Hosp. Inf., 60 (1) 1–7 (2005)CrossRef

Yilgor, I, McGrath, JE, “Polysiloxane Containing Copolymers: A Survey of Recent Developments.” Adv. Polym. Sci., 86 1–86 (1988)CrossRef

10.

Kraxner, P, Louis Boogh, L, Lejenue A, “The Role of Silanes in Filled and Crosslinked Polymers.” Organosilicon Chemistry Vol IV: From Molecules to Materials, pp. 562–572. Wiley-VCH, New York, 2000.

11.

Gates, DP, “Inorganic and Organometallic Polymers.” Annu. Rep. Prog. Chem. Sect. A: Inorg. Chem., 98 479–492 (2002)CrossRef

12.

Wang, LF, Ji, Q, Glass, TE, Ward, TC, McGrath, JE, Muggli, M, Burns, G, Sorathia, U, “Synthesis and Characterization of Organosiloxane Modified Segmented Polyether Polyurethanes.” Polymer, 41 (13) 5083–5093 (2000)CrossRef

13.

Roohpour, N, Wasikiewicz, JM, Paul, D, Vadgama, P, Rehman, IU, “Synthesis and Characterization of Enhanced Barrier Polyurethane for Encapsulation of İmplantable Medical Devices.” J. Mater. Sci. Mater. Med., 20 (9) 1803–1814 (2009)CrossRef

14.

Karatas, S, Kayaman-Apohan, N, Turunc, O, Güngör, A, “Synthesis and Characterization of UV-Curable Phosphorus Containing Hybrid Materials Prepared by Sol–Gel Technique.” Polym. Adv. Technol., 22 (5) 567–576 (2011)CrossRef

15.

Goto, Y, Otsuka, O, Sawada, H, “Preparation and Applications of Novel Fluoroalkyl End-Capped Oligomers/Polyimide/Silica Nanocomposites.” Polym. Adv. Technol., 23 (3) 290–298 (2012)CrossRef

16.

Duhua Wang, D, Bierwagen, PB, “Sol–Gel Coatings on Metals for Corrosion Protection.” Prog. Org. Coat., 64 (4) 327–338 (2009)CrossRef

17.

Xiao, X, Hao, C, “Preparation of Waterborne Epoxy Acrylate/Silica Sol Hybrid Materials and Study of Their UV Curing Behavior.” Colloid Surf. A: Physicochem. Eng. Asp., 359 (1–3) 82–87 (2010)CrossRef

18.

Soppera, O, Croutxe-Barghorn, C, Carre, C, Blanc, D, “Design of Photoinduced Relief Optical Devices with Hybrid Sol–Gel Materials.” Appl. Surf. Sci., 186 (1–4) 91–94 (2002)CrossRef

19.

Chibac, A, Melinte, V, Buruiana, T, Balan, L, Buruiana, EC, “One-Pot Synthesis of Photocrosslinked Sol–Gel Hybrid Composites Containing Silver Nanoparticles in Urethane–Acrylic Matrixes.” Chem. Eng. J., 200–202 577–588 (2012)CrossRef

20.

Marini, M, Niederhausern, SD, Iseppi, R, Bondi, M, Sabia, C, Toselli, M, Pilati, F, “Antibacterial Activity of Plastics Coated with Silver-Doped Organic-Inorganic Hybrid Coatings Prepared by Sol-Gel Processes.” Biomacromolecules, 8 1246–1254 (2007)CrossRef

21.

An, J, Zhang, M, Wang, S, Tang, J, “Physical, Chemical and Microbiological Changes in Stored Green Asparagus Spears as Affected by Coating of Silver Nanoparticles-PVP.” LWT - Food Sci. Technol., 41 (6) 1100–1107 (2008)CrossRef

22.

Stobie, N, Duffy, B, Colreavy, J, McHale, P, Hinder, SJ, McCormack, DE, “Dual-Action Hygienic Coatings: Benefits of Hydrophobicity and Silver Ion Release for Protection of Environmental and Clinical Surfaces.” J. Colloid Interface Sci., 345 (2) 286–292 (2010)CrossRef

23.

Nimittrakoolchai, O, Supothina, S, “Deposition of Transparent, Hydrophobic Olydimethylsiloxane—Nanocrystalline TiO₂ Hybrid Films on Glass Substrate.” Songklanakarin J. Sci. Technol., 32 (2) 157–162 (2010)

24.

Yang, CY, Huang, LY, Shen, TL, Yeh, JA, “Cell Adhesion, Morphology and Biochemistry on Nanotopographic Oxidized Silicon Surfaces.” Eur. Cell Mater., 20 415–430 (2010)

25.

Villeneuve, S, Lavıolette, M, Auger, M, De Sılets, S, “¹³C-NMR Spectroscopy Study of Polyurethane Obtained from Azide Hydroxyl-Terminated Polymer Cured with Isophorone Diisocyanate (IPDI). J. Polym. Sci.” Part C: Polym. Lett., 35 2991–2998 (1997)CrossRef

26.

Ono, HK, Jones, FN, Pappas, SP, “Relative Reactivity of İsocyanate Groups of İsophorone Diisocyanate. Unexpected High Reactivity of the Secondary İsocyanate Group.” J. Polym. Sci., Part C: Polym. Lett., 23 509–515 (1985)CrossRef

27.

Shen, XS, Wang, GZ, Hong, X, Zhu, W, “Nanospheres of Silver Nanoparticles: Agglomeration, Surface Morphology Control and Application as SERS Substrates.” Phys. Chem. Chem. Phys., 11 7450–7454 (2009)CrossRef

28.

Tsuji, T, Thang, DH, Okazaki, Y, Nakanishi, M, Tsuboi, Y, Tsuji, M, “Preparation of Silver Nanoparticles by Laser Ablation in Polyvinylpyrrolidone Solutions.” Appl. Surf. Sci., 254 (16) 5224–5230 (2008)CrossRef

29.

Sun, Y, Xia, Y, “Shape-Controlled Synthesis of Gold and Silver Nanoparticles.” Science, 298 2176–2179 (2002)CrossRef

30.

Lim, B, Jiang, M, Tao, J, Camargo, PHC, Zhu, Y, Xia, Y, “Shape-Controlled Synthesis of Pd Nanocrystals in Aqueous Solutions.” Adv. Funct. Mater., 19 (2) 189–200 (2009)CrossRef

31.

Gorup, LF, Longo, E, Leite, ER, Camargo, ER, “Moderating Effect of Ammonia on Particle Growth and Stability of Quasi-Monodisperse Silver Nanoparticles Synthesized by the Turkevich Method.” J. Colloid Interface Sci., 360 (2) 355–358 (2011)CrossRef

32.

Mülazim, Y, Kahraman, MV, Kayaman-Apohan, N, Kızıltaş, S, Güngör, A, “Preparation and Characterization of UV-Curable, Boron-Containing, Transparent Hybrid Coatings.” J. Appl. Polym. Sci., 120 (4) 2112 (2011)CrossRef

33.

Joki-Korpela, F, Pakkanen, TT, “Incorporation of Polydimethylsiloxane into Polyurethanes and Characterization of Copolymers.” Eur. Polym. J., 47 (8) 1694–1708 (2011)CrossRef

34.

Fenouillot, FF, Méchin, F, Boisson, F, Alcouffe, P, Pokropski, P, Kallel, T, Mnif, M, “Coarsening of Nanodomains by Reorganization of Polysiloxane Segments at High Temperature in Polyurethane/α, ω-Aminopropyl Polydimethylsiloxane Blends.” Eur. Polym. J., 48 (2) 284–295 (2012)CrossRef

35.

Mukai, U, Gleason, KK, Argon, AS, Cohen, RE, “Polydimethylsiloxane/Nylon-6 Block Copolymers: Molecular Mobility at the Interface.” Macromolecules, 28 (14) 4899–4903 (1995)CrossRef

36.

Kahraman, MV, Kuğu, M, Menceloğlu, Y, Kayaman-Apohan, N, Güngör, A, “The Novel Use of Organo Alkoxy Silane for the Synthesis of Organic–İnorganic Hybrid Coatings.” J. Non-Cryst. Solids, 352 (21–22) 2143–2151 (2006)CrossRef

37.

Karataş, S, Kayaman-Apohan, N, Demirer, H, Güngör, A, “Polyimide–Silica Hybrid Coatings: Morphological, Mechanical, and Thermal İnvestigations.” Polym. Adv. Technol., 18 (6) 490–496 (2007)CrossRef

38.

Kozakiewicz, J, “Polysiloxaneurethanes: New Polymers for Potential Coating Applications.” Prog. Org. Coat., 27 123–131 (1996)CrossRef

39.

Chen, RS, Chang, CJ, Chang, YR, “Study on Siloxane-Modified Polyurethane Dispersions form Various Polydimethylsiloxane.” J. Polym. Sci. Part A: Polym. Chem., 43 (16) 3482–3490 (2005)CrossRef

40.

Sondi, I, Salopek-Sondi, BJ, “Silver Nanoparticles as Antimicrobial Agent: A Case Study on E. coli as a Model for Gram-Negative Bacteria.” J. Colloid Interface Sci., 275 177–182 (2004)CrossRef

41.

Feng, QL, Wu, J, Chen, GQ, Cui, FZ, Kim, TN, Kim, JO, “A Mechanistic Study of the Antibacterial Effect of Silver İons on Escherichia coli and Staphylococcus aureus.” J. Biomed. Mater. Res., 52 (4) 662–668 (2000)CrossRef

Title: Polydimethylsiloxane (PDMS)-based antibacterial organic–inorganic hybrid coatings
Authors: Burcu Oktay
Nilhan Kayaman-Apohan
Publication date: 01-11-2013
Publisher: Springer US
Published in: Journal of Coatings Technology and Research / Issue 6/2013
Print ISSN: 1547-0091
Electronic ISSN: 1935-3804
DOI: https://doi.org/10.1007/s11998-013-9505-3

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