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16-08-2018

Precursor synthesis of maghemite and its adsorption properties with respect to bivalent copper ions

Authors: О. D. Linnikov, V. N. Krasil’nikov, О. I. Gyrdasova, I. V. Rodina, I. V. Baklanova, А. P. Tyutyunnik, Т. V. Dyachkova, A. Yu. Suntsov, F. Sauerzopf, V. V. Marchenkov

Published in: Adsorption | Issue 7/2018

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Abstract

The low-dimensional maghemite γ-Fe₂O₃ has been synthesized by the precursor method. The basic formate of the composition Fe(OH)(HCOO)₂ produced by an original technique was used as a precursor. A study of the magnetic and adsorption properties of the synthesized maghemite showed that it is ferrimagnetic in a wide temperature interval and an effective sorbent for removal of bivalent copper ions from aqueous solutions. The process of adsorption of Cu²⁺ ions by γ-Fe₂O₃ powder is described by the Langmuir equation. A comparison of the obtained parameters of the Langmuir equation with available literature data reveals that, allow for the specific surface area, the maghemite powder synthesized in this work surpasses the maghemite samples produced by other methods in the adsorption capacity with respect to copper ions.

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Title: Precursor synthesis of maghemite and its adsorption properties with respect to bivalent copper ions
Authors: О. D. Linnikov
V. N. Krasil’nikov
О. I. Gyrdasova
I. V. Rodina
I. V. Baklanova
А. P. Tyutyunnik
Т. V. Dyachkova
A. Yu. Suntsov
F. Sauerzopf
V. V. Marchenkov
Publication date: 16-08-2018
Publisher: Springer US
Published in: Adsorption / Issue 7/2018
Print ISSN: 0929-5607
Electronic ISSN: 1572-8757
DOI: https://doi.org/10.1007/s10450-018-9967-9

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