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Journal of Nanoparticle Research

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01-12-2015 | Research Paper

Preparation and capacitive properties of lithium manganese oxide intercalation compound

Authors: Fang Tian, Yibing Xie

Published in: Journal of Nanoparticle Research | Issue 12/2015

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Abstract

Lithium manganese oxide intercalation compound (Li_0.7MnO₂) supported on titanium nitride nanotube array (TiN NTA) was applied as cathode electrode material for lithium-ion supercapacitor application. Li_0.7MnO₂/TiN NTA was fabricated through electrochemical deposition and simultaneous intercalation process using TiN NTA as a substrate, Mn(CH₃COO)₂ as manganese source, and Li₂SO₄ as lithium source. The morphology and microstructure of the Li_0.7MnO₂/TiN NTA were characterized by scanning electron microscopy and X-ray diffraction analysis. The electrochemical performance of the Li_0.7MnO₂/TiN NTA was investigated by electrochemical impedance spectroscopy, cyclic voltammetry, and galvanostatic charge/discharge measurements. Li_0.7MnO₂/TiN NTA exhibited higher capacitive performance in Li₂SO₄ electrolyte solution rather than that in Na₂SO₄ electrolyte solution, which was due to the different intercalation effects of lithium-ion and sodium-ion. The specific capacitance was improved from 503.3 F g⁻¹ for MnO₂/TiN NTA to 595.0 F g⁻¹ for Li_0.7MnO₂/TiN NTA at a current density of 2 A g⁻¹ in 1.0 M Li₂SO₄ electrolyte solution, which was due to the intercalation of lithium-ion for Li_0.7MnO₂. Li_0.7MnO₂/TiN NTA also kept 90.4 % capacity retention after 1000 cycles, presenting a good cycling stability. An all-solid-state lithium-ion supercapacitor was fabricated and showed an energy density of 82.5 Wh kg⁻¹ and a power density of 10.0 kW kg⁻¹.

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Aravindan V, Mhamane D, Ling WC, Ogale S, Madhavi S (2013) Nonaqueous lithium-ion capacitors with high energy densities using trigol-reduced graphene oxide nanosheets as cathode-active material. Chemsuschem 6:2240–2244. doi:10.1002/cssc.201300465 CrossRef

Brandt A, Balducci A (2013) A study about the use of carbon coated iron oxide-based electrodes in lithium-ion capacitors. Electrochim Acta 108:219–225. doi:10.1016/j.electacta.2013.06.076 CrossRef

Choi D, Kumta PN (2006) Nanocrystalline TiN derived by a two-step halide approach for electrochemical capacitors. J Electrochem Soc 153:A2298–A2303. doi:10.1149/1.2359692 CrossRef

Dong SM et al (2011) Facile preparation of mesoporous titanium nitride microspheres for electrochemical energy storage. ACS Appl Mater Interface 3:93–98. doi:10.1021/am100951h CrossRef

Du H, Xie Y, Xia C, Wang W, Tian F (2014a) Electrochemical capacitance of polypyrrole-titanium nitride and polypyrrole-titania nanotube hybrids. New J Chem 38:1284–1293. doi:10.1039/c3nj01286g CrossRef

Du H, Xie Y, Xia C, Wang W, Tian F, Zhou Y (2014b) Preparation of a flexible polypyrrole nanoarray and its capacitive performance. Mater Lett 132:417–420. doi:10.1016/j.matlet.2014.06.140 CrossRef

Gong KP, Yu P, Su L, Xiong SX, Mao LQ (2007) Polymer-assisted synthesis of manganese dioxide/carbon nanotube nanocomposite with excellent electrocatalytic activity toward reduction of oxygen. J Phys Chem C 111:1882–1887. doi:10.1021/jp0628636 CrossRef

Grey CP, Dupre N (2004) NMR studies of cathode materials for lithium-ion rechargeable batteries. Chem Rev 104:4493–4512. doi:10.1021/cr020734p CrossRef

Huang B, Jang YI, Chiang YM, Sadoway DR (1998) Electrochemical evaluation of LiCoO₂ synthesized by decomposition and intercalation of hydroxides for lithium-ion battery applications. J Appl Electrochem 28:1365–1369. doi:10.1023/a:1003443108681 CrossRef

Huang ZF, Zhang HZ, Wang CZ, Wang DP, Meng X, Ming X, Chen G (2009) First-principles investigation on extraction of lithium ion from monoclinic LiMnO₂. Solid State Sci 11:271–274. doi:10.1016/j.solidstatesciences.2008.06.005 CrossRef

Kweon HJ, Kim SS, Kim GB, Park DG (1998) Syntheses of LiMn₂O₄, LiCoO₂ and LiNi0.8Co0.2O₂ by the PVA-precursor method and their use as a cathode in the lithium-ion rechargeable battery. J Mater Sci Lett 17:1697–1701. doi:10.1023/a:1006610831799 CrossRef

Liu ZH, Kang LP, Zhao MZ, Ooi K (2007) Preparation, ion-exchange, and electrochemical behavior of Cs-type manganese oxides with a novel hexagonal-like morphology. J Mater Res 22:2437–2447. doi:10.1557/jmr.2007.0302 CrossRef

Lu XH et al (2012) Stabilized TiN nanowire arrays for high-performance and flexible supercapacitors. Nano Lett 12:5376–5381. doi:10.1021/nl302761z CrossRef

Luo JY, Cheng L, Xia YY (2007) LiMn₂O₄ hollow nanosphere electrode material with excellent cycling reversibility and rate capability. Electrochem Commun 9:1404–1409. doi:10.1016/j.elecom.2007.01.058 CrossRef

Mai LQ et al (2013) Fast ionic diffusion-enabled nanoflake electrode by spontaneous electrochemical pre-intercalation for high-performance supercapacitor. Sci Rep 3:1718. doi:10.1038/srep01718 CrossRef

Najafpour MM, Pashaei B, Nayeri S (2012) Calcium manganese(IV) oxides: biomimetic and efficient catalysts for water oxidation. Dalton Trans 41:4799–4805. doi:10.1039/c2dt12189a CrossRef

Park MS, Lim YG, Kim JH, Kim YJ, Cho J, Kim JS (2011) A novel lithium-doping approach for an advanced lithium ion capacitor. Adv Energy Mater 1:1002–1006. doi:10.1002/aenm.201100270 CrossRef

Qu QT, Zhang P, Wang B, Chen YH, Tian S, Wu YP, Holze R (2009) Electrochemical performance of MnO₂ nanorods in neutral aqueous electrolytes as a cathode for asymmetric supercapacitors. J Phys Chem C 113:14020–14027. doi:10.1021/jp8113094 CrossRef

Ramadoss A, Kim SJ (2014) Hierarchically structured TiO₂@MnO₂ nanowall arrays as potential electrode material for high-performance supercapacitors. Int J Hydrog Energy 39:12201–12212. doi:10.1016/j.ijhydene.2014.05.118 CrossRef

Rettew RE, Sauerbrey M, Cheng S, Alamgir F (2011) Surface-architecture-determined electrochemistry of Pt on Au, TiO₂, CeO₂, and MnO₂ surfaces. In: Abstracts of papers of the American chemical society, vol 242

Sherrill SA, Duay J, Gui Z, Banerjee P, Rubloff GW, Lee SB (2011) MnO₂/TiN heterogeneous nanostructure design for electrochemical energy storage. Phys Chem Chem Phys 13:15221–15226. doi:10.1039/c1cp21815h CrossRef

Sivakkumar SR, Pandolfo AG (2012) Evaluation of lithium-ion capacitors assembled with pre-lithiated graphite anode and activated carbon cathode. Electrochim Acta 65:280–287. doi:10.1016/j.electacta.2012.01.076 CrossRef

Smith PH, Tran TN, Jiang TL, Chung J (2013) Lithium-ion capacitors: electrochemical performance and thermal behavior. J Power Sources 243:982–992. doi:10.1016/j.jpowsour.2013.06.012 CrossRef

Tian F, Xie YB, Du HX, Zhou YZ, Xia C, Wang W (2014) Preparation and electrochemical capacitance of graphene/titanium nitride nanotube array. RSC Adv 4:41856–41863. doi:10.1039/c4ra05020g CrossRef

Tiano AL et al (2015) Correlating size and composition-dependent effects with magnetic, Mossbauer, and pair distribution function measurements in a family of catalytically active ferrite nanoparticles. Chem Mater 27:3572–3592. doi:10.1021/acs.chemmater.5b00767 CrossRef

Van der Ven A, Ceder G (2001) Lithium diffusion mechanisms in layered intercalation compounds. J Power Sources 97–8:529–531. doi:10.1016/s0378-7753(01)00638-3

Van der Ven A, Bhattacharya J, Belak AA (2013) Understanding Li diffusion in Li-intercalation compounds. Acc Chem Res 46:1216–1225. doi:10.1021/ar200329r CrossRef

Xia C, Xie Y, Wang Y, Wang W, Du H, Tian F (2013) Preparation and capacitance performance of polyaniline/titanium nitride nanotube hybrid. J Appl Electrochem 43:1225–1233. doi:10.1007/s10800-013-0610-x CrossRef

Xia C, Xie Y, Wang W, Du H (2014) Fabrication and electrochemical capacitance of polyaniline/titanium nitride core-shell nanowire arrays. Synth Met 192:93–100. doi:10.1016/j.synthmet.2014.03.018 CrossRef

Xia C, Xie Y, Du H, Wang W (2015) Ternary nanocomposite of polyaniline/manganese dioxide/titanium nitride nanowire array for supercapacitor electrode. J Nanopart Res 17:30. doi:10.1007/s11051-014-2855-7

Xiao XL, Wang L, Wang DS, He XM, Peng Q, Li YD (2009) Hydrothermal synthesis of orthorhombic LiMnO₂ nano-particles and LiMnO₂ nanorods and comparison of their electrochemical performances. Nano Res 2:923–930. doi:10.1007/s12274-009-9094-8 CrossRef

Xie Y, Du H (2015) Electrochemical capacitance of carbon quantum dots-polypyrrole titania nanotube hybrid. RSC Adv 5:89689–89697. doi:10.1039/C5RA16538E CrossRef

Xie Y, Fang X (2014) Electrochemical flexible supercapacitor based on manganese dioxide-titanium nitride nanotube hybrid. Electrochim Acta 120:273–283. doi:10.1016/j.electacta.2013.12.103 CrossRef

Xie Y, Zhan Y (2015) Electrochemical capacitance of porous reduced graphene oxide/nickel foam. J Porous Mater 22:403–412. doi:10.1007/s10934-015-9909-9 CrossRef

Xie Y, Wang Y, Du H (2013) Electrochemical capacitance performance of titanium nitride nanoarray. Mater Sci Eng B 178:1443–1451. doi:10.1016/j.mseb.2013.09.005 CrossRef

Xie Y, Wang D, Zhou Y, Du H, Xia C (2014) Supercapacitance of polypyrrole/titania/polyaniline coaxial nanotube hybrid. Synth Met 198:59–66. doi:10.1016/j.synthmet.2014.09.029 CrossRef

Xie Y, Du H, Xia C (2015a) Porous poly(3,4-ethylenedioxythiophene) nanoarray used for flexible supercapacitor. Microporous Mesoporous Mater 204:163–172. doi:10.1016/j.micromeso.2014.11.021 CrossRef

Xie Y, Song F, Du H, Xia C (2015b) Preparation of carbon-coated lithium iron phosphate/titanium nitride for a lithium-ion supercapacitor. New J Chem 39:604–613. doi:10.1039/c4nj01169d CrossRef

Xie Y, Xia C, Du H, Wang W (2015c) Enhanced electrochemical performance of polyaniline/carbon/titanium nitride nanowire array for flexible supercapacitor. J Power Sources 286:561–570. doi:10.1016/j.jpowsour.2015.04.025 CrossRef

Yan J et al (2010) Electrochemical properties of graphene nanosheet/carbon black composites as electrodes for supercapacitors. Carbon 48:1731–1737. doi:10.1016/j.carbon.2010.01.014 CrossRef

Yu HY, Wu JH, Fan LQ, Xu KQ, Zhong X, Lin YZ, Lin JM (2011) Improvement of the performance for quasi-solid-state supercapacitor by using PVA-KOH-KI polymer gel electrolyte. Electrochim Acta 56:6881–6886. doi:10.1016/j.electacta.2011.06.039 CrossRef

Yu Y, Zhang B, He YB, Huang ZD, Oh SW, Kim JK (2013) Mechanisms of capacity degradation in reduced graphene oxide/alpha-MnO₂ nanorod composite cathodes of Li-air batteries. J Mater Chem A 1:1163–1170. doi:10.1039/c2ta00426g CrossRef

Yu MH et al (2015) Holey tungsten oxynitride nanowires: novel anodes efficiently integrate microbial chemical energy conversion and electrochemical energy storage. Adv Mater 27:3085–3091. doi:10.1002/adma.201500493 CrossRef

Yuan AB, Zhang QL (2006) A novel hybrid manganese dioxide/activated carbon supercapacitor using lithium hydroxide electrolyte. Electrochem Commun 8:1173–1178. doi:10.1016/j.elecom.2006.05.018 CrossRef

Zhuang QC, Xu SD, Qiu XY, Cui YL, Fang LA, Sun SG (2010) Diagnosis of electrochemical impedance spectroscopy in lithium ion batteries. Prog Chem 22:1044–1057

Title: Preparation and capacitive properties of lithium manganese oxide intercalation compound
Authors: Fang Tian
Yibing Xie
Publication date: 01-12-2015
Publisher: Springer Netherlands
Published in: Journal of Nanoparticle Research / Issue 12/2015
Print ISSN: 1388-0764
Electronic ISSN: 1572-896X
DOI: https://doi.org/10.1007/s11051-015-3284-y

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