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Polymer Bulletin

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27-04-2017 | Original Paper

Preparation and characterization of ABS and copper (II) sulfate coordination composites by planetary ball mill

Authors: Zhiwei Fu, Yapeng Mao, Shourui Li, Shouchao Liu, Chengli Shao, Peng Shang, Qiuying Li, Chifei Wu

Published in: Polymer Bulletin | Issue 2/2018

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Abstract

Acrylonitrile–butadiene–styrene (ABS) composites filled with anhydrous copper sulfate (CuSO₄) particles were prepared by planetary ball mill. The ball milling process can provide CuSO₄ particles of small sizes for homogeneous particle distribution in a matrix. To directly enhance the interaction between the two ingredients, a coordination reaction was generated by heat press at 180 °C. Fourier transform infrared, electron spin resonance, Ultraviolet–visible, and X-ray photoelectron spectroscopy were employed to investigate the coordination reaction. The results showed that a coordination reaction happened between nitrile groups (–CN) of ABS and copper ions (Cu²⁺) of CuSO₄. The loss factor of dynamic mechanical analysis indicated the decrease of intermolecular friction due to a strong interaction between the matrix and the particles. The homogeneously dispersed, micro-sized CuSO₄ particles were observed by scanning electron microscope. The interface was indistinguishable under the microscope indicating a well-bonded surface and good compatibility. In addition, dissolution behavior showed that the solvent resistance of the composites was significantly improved.

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Title: Preparation and characterization of ABS and copper (II) sulfate coordination composites by planetary ball mill
Authors: Zhiwei Fu
Yapeng Mao
Shourui Li
Shouchao Liu
Chengli Shao
Peng Shang
Qiuying Li
Chifei Wu
Publication date: 27-04-2017
Publisher: Springer Berlin Heidelberg
Published in: Polymer Bulletin / Issue 2/2018
Print ISSN: 0170-0839
Electronic ISSN: 1436-2449
DOI: https://doi.org/10.1007/s00289-017-2042-y

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