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Published in: Journal of Sol-Gel Science and Technology 3/2011

01-09-2011 | Original Paper

Preparation and characterization of La0.6Sr0.4Co0.2Fe0.8O3-δ thin-film membrane on porous support by dip-coating method

Authors: Salwa Meredith Hashim, Abdul Rahman Mohamed, Subhash Bhatia

Published in: Journal of Sol-Gel Science and Technology | Issue 3/2011

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Abstract

Perovskite-type La0.6Sr0.4Co0.2Fe0.8O3-δ (LSCF6428) thin-film membrane prepared by modified Pechini sol–gel process, was successfully deposited on porous support of similar composition using dip-coating method. Fine grain and crack-free film with perovskite structure was obtained at sintering temperature of 800 °C and dwelling time of 60 min. The cross-sectional image indicated that LSCF6428 thin-film membrane coated on the porous support showed excellent adhesion to the support with uniform thickness. The minimum dense layer thickness obtained by dip-coating method was around 0.5 μm. It was found that the oxygen permeability of the supported thin film was lower than that of the perovskite support, which indicated that the pores of the support were reduced by thin-film deposition on the support surface. The reduction in the pore size led to the more selective permeation mechanism contributes to the overall permeation. Successful deposition of LSCF6428 thin-film membrane on porous support can be considered as a promising technique for the preparation of oxygen separation membrane.

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Metadata
Title
Preparation and characterization of La0.6Sr0.4Co0.2Fe0.8O3-δ thin-film membrane on porous support by dip-coating method
Authors
Salwa Meredith Hashim
Abdul Rahman Mohamed
Subhash Bhatia
Publication date
01-09-2011
Publisher
Springer US
Published in
Journal of Sol-Gel Science and Technology / Issue 3/2011
Print ISSN: 0928-0707
Electronic ISSN: 1573-4846
DOI
https://doi.org/10.1007/s10971-011-2519-3

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