Skip to main content
Disciplines
Automotive Business IT + Informatics Construction + Real Estate Electrical Engineering + Electronics Energy + Sustainability Insurance + Risk Finance + Banking Management + Leadership Marketing + Sales Mechanical Engineering + Materials
Events
DE
EN
Books
Journals
Topic Page
Marketing
Start single access now
Access for companies
EXTENDED SEARCH
Log in
Top
Polymer Bulletin
Published in: Polymer Bulletin 5/2020

01-07-2019 | Original Paper

Preparation and characterization of maleic anhydride grafted SEBS/silica composites through modification by ethanolamine

Authors: Pao-Lin Chuang, Yu-Hsun Nien

Published in: Polymer Bulletin | Issue 5/2020

Log in

Activate our intelligent search to find suitable subject content or patents.

search-config
loading …

Abstract

In our previous study, SEBS was first grafted by using maleic anhydride (MA) to form SEBS-g-MA, and it was then modified by ethanolamine (EA), which was noted as EA modified SEBS-g-MA. In this study, the EA modified SEBS-g-MA was compounded with tetraethyl orthosilicate (TEOS) using the sol–gel method to form EA modified SEBS-g-MA/silica composites. The chemical structures, mechanical properties and thermal stability of the EA modified SEBS-g-MA/silica composites were characterized. SEBS-g-MA modified with EA formed imide structures with hydroxyl group. After EA modified SEBS-g-MA reacted with TEOS, the absorption peak of Si–O–Si structure was observed in the EA modified SEBS-g-MA modified SEBS/silica composites. From solid-state NMR, the structures of silica in the EA modified SEBS-g-MA/silica composites were mainly in the forms of networks made of Si bonding with three or four –O–Si groups. In TGA, the thermal stability of the EA modified SEBS-g-MA/silica was better than that of SEBS. The storage modulus and Tg of the EA modified SEBS-g-MA/silica composites were enhanced. The tensile strength and Young’s modulus of EA modified SEBS-g-MA/silica was improved.
previous article Environmentally sustainable rice husk ash reinforced cardanol based polybenzoxazine bio-composites for insulation applications
next article Synthesis, characterization and rheological properties of multiblock associative copolymers by RAFT technique

Dont have a licence yet? Then find out more about our products and how to get one now:

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

  • über 102.000 Bücher
  • über 537 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Finance + Banking
  • Management + Führung
  • Marketing + Vertrieb
  • Maschinenbau + Werkstoffe
  • Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

inform now

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

  • über 67.000 Bücher
  • über 390 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Maschinenbau + Werkstoffe




 

Jetzt Wissensvorsprung sichern!

inform now
Literature
1.
Brinker CJ, Scherer GW (1990) Sol–gel science. The physics and chemistry of sol–gel processing. Academic Press, San Diego
2.
Wen J, Wilkes GL (1996) Organic/inorganic hybrid network materials by the sol–gel approach. Chem Mater 8:1667–1681
3.
Morikawa A, Iyoku Y, Kakimoto M-A, Imai Y (1992) Feature article. Preparation of new polyimide–silica hybrid materials via the sol–gel process. J Mater Chem 2:679–689
4.
Klein LC (1988) Sol–gel technology for thin films, performs, electronics and specialty shapes, 1st edn. William andrew, Norwich
5.
Schmidt H (1994) Inorganic–organic composites by sol–gel techniques. J Sol-Gel Sci Technol 1:217–231
6.
Mark JE, Wang S, Ahmad Z (1995) Inorganic–organic composites, including some examples involving polyamides and polyimides. Macromol Symp 98:731–751
7.
Brinker CJ (1994) Sol–gel processing of silica. Adv Chem 234:361–401
8.
Coltrain BK, Kelts W (1994) The chemistry of hydrolysis and condensation of silica sol–gel precursors. Adv Chem 234:403–418
9.
Kozuka H, Sakka S (1994) Formation of silica gels composed of micrometer-sized particles by the sol–gel method. Adv Chem 234:129–141
10.
Schmidt H, Krug H (1994) Sol–gel-based inorganic–organic composite materials. ACS Symp Ser 572:183–194
11.
Brinker CJ, Raman NK, Logan MN, Sehgal R, Assink RA, Hua D-W, Ward TL (1994) Structure–property relationships in sol–gel-derived thin films. ACS Symp Ser 572:104–121
12.
Yoldas BE (1979) Monolithic glass formation by chemical polymerization. J Mater Sci 14:1843–1849
13.
Nogami M, Moriya Y (1980) Glass formation through hydrolysis of Si(OC2H5)4 with NH4OH and HCl solution. J Non-Cryst Solids 37:191–201
14.
Chumha N, Kittiwachana S, Thongtem T, Thongtem S, Kaowphong S (2014) Synthesis and characterization of GdVO4 nanoparticles by a malic acid-assisted sol–gel method. Mater Lett 136:18–21
15.
More PM, Umbarkar SB, Dongare MK (2016) Template-free sol–gel synthesis of high surface area mesoporous silica based catalysts for esterification of di-carboxylic acids. C R Chimie 19:1247–1253
16.
Habibi N, Wang Y, Arandiyan H, Rezaei M (2017) Low-temperature synthesis of mesoporous nanocrystalline magnesium aluminate (MgAl2O4) spinel with high surface area using a novel modified sol–gel method. Adv Powder Technol 28:1249–1257
17.
Zhuang L, Ma B, Chen S, Hou Z, Chen S (2015) Fast synthesis of mesoporous silica materials via simple organic compounds templated sol–gel route in the absence of hydrogen bond. Microporous Mesoporous Mater 213:22–29
18.
Hesaraki S (2016) Photocurable bioactive bone cement based on hydroxyethyl methacrylate-poly(acrylic/maleic) acid resin and mesoporous sol gel-derived bioactive glass. Mater Sci Eng C 63:535–545
19.
Song E-H, Jeong S-H, Park J-U, Kim S, Kim H-E, Song J (2017) Polyurethane-silica hybrid foams from a one-step foaming reaction, coupled with a sol–gel process, for enhanced wound healing. Mater Sci Eng C 79:866–874
20.
Li Y, Shimizu H (2009) Toward a stretchable, elastic, and electrically conductive nanocomposite: morphology and properties of poly[styrene-b-(ethylene-co-butylene)-b-styrene]/multiwalled carbon nanotube composites fabricated by high-shear processing. Macromolecules 42:2587–2593
21.
Ganguly A, Maiti M, Bhowmick AK (2008) Structure–property relationship of specialty elastomer-clay nanocomposites. Bull Mater Sci 31:455–459
22.
Ganguly A, Bhowmick AK (2009) Effect of polar modification on morphology and properties of styrene-(ethylene-co-butylene)-styrene triblock copolymer and its montmorillonite clay-based nanocomposites. J Mater Sci 44:903–918
23.
Kausar A, Zulfiqar S, Shabbir S, Ishaq M, Sarwar MI (2007) Mechanical properties of functionalized SEBS based inorganic hybrid materials. Polym Bull 59:457–468
24.
Chuang P-L, Nien Y-H (2019) Synthesis and characterization of maleic anhydride grafted SEBS modified with ethanolamine, 2-amino-2-methyl-1-propanol or glycerine. J Polym Res 26:66
25.
Murilloa EA, López BL (2015) Effect of the maleic anhydride content on the structural, thermal, rheological and film properties of the n-butyl methacrylate–maleic anhydride copolymers. Prog Org Coat 78:96–102
26.
Yao H, Zhang N, Shen K, Song N, Shi K, Zhu S, Zhang Y, Guan S (2017) From a flexible hyperbranched polyimide to a microporous polyimide network: microporous architecture and carbon dioxide adsorption. Polymer 115:176–183
27.
Arat R, Uyanik N (2017) Study of the morphological and thermal properties of polystyrene nanocomposites based on modified halloysite nanotubes with styrene-maleic anhydride copolymers. Mater Today Commun 13:255–262
28.
Dellacasa E, Forouharshad M, Rolandi R, Pastorino L, Monticelli O (2018) Poly(styrene-co-maleic anhydride) nanoparticles as protein carriers. Mater Lett 220:241–244
29.
Wróblewska AA, Lingier S, Noordijk J, Du Prez FE, De Wildeman SMA, Bernaerts KV (2017) Polyamides based on a partially bio-based spirodiamine. Eur Polym J 96:221–231
30.
Yao J, Pantano MF, Pugno NM, Bastiaansen CWM, Peijs T (2015) High-performance electrospun co-polyimide nanofibers. Polymer 76:105–112
31.
Hsiao S-H, Chen Y-Z (2017) Electroactive and ambipolar electrochromic polyimides from arylene diimides with triphenylamine N-substituents. Dyes Pigm 144:173–183
32.
Xu S, Wang Y (2015) Novel thermally cross-linked polyimide membranes for ethanol dehydration via pervaporation. J Membr Sci 496:142–155
33.
Rwei S-P, Chen Y-M, Lin W-Y, Chiang W-Y (2014) Synthesis and rheological characterization of water-soluble glycidyltrimethylammonium-chitosan. Mar Drugs 12:5547–5562PubMedPubMedCentral
34.
Wang C-S, Leu T-S (2000) Synthesis and characterization of polyimides containing naphthalene pendant group and flexible ether linkages. Polymer 41:3581–3591
35.
Zhang C, Li P, Cao B (2017) Decarboxylation crosslinking of polyimides with high CO2/CH4 separation performance and plasticization resistance. J Membr Sci 528:206–216
36.
Xie Z, Hoang M, Duong T, Ng D, Dao B, Gray S (2011) Sol–gel derived poly(vinyl alcohol)/maleic acid/silica hybrid membrane for desalination by pervaporation. J Membr Sci 383:96–103
37.
Catauro M, Bollino F, Papale F, Ferrara C, Mustarelli P (2015) Silica–polyethylene glycol hybrids synthesized by sol–gel: biocompatibility improvement of titanium implants by coating. Mater Sci Eng C 55:118–125
38.
Huang X, Liao W, Ye L, Zhang N, Lan S, Fan H, Qu J (2017) Fabrication of hydrophobic composite films by sol–gel process between POSS-containing fluorinated polyacrylate latexes and colloidal silica particle. Microporous Mesoporous Mater 243:311–318
39.
Catauro M, Bollino F, Papale F (2018) Surface modifications of titanium implants by coating with bioactive and biocompatible poly (ε-caprolactone)/SiO2 hybrids synthesized via sol–gel. Arab J Chem 11:1126–1133
40.
Ravera E, Martelli T, Geiger Y, Fragai M, Goobes G, Luchinat C (2016) Biosilica and bioinspired silica studied by solid-state NMR. Coord Chem Rev 327–328:110–122
41.
Luhmer M, d’Espinose JB, Hommel H, Legrand AP (1996) High-resolution 29Si solid-state NMR study of silicon functionality distribution on the surface of silicas. Magn Reson Imaging 14:911–913PubMed
42.
Zhao H, Chen Q, Zhang S (2012) A novel scheme for quantitative characterization of the structures of mesoporous silica by solid-state 29Si NMR. Microporous Mesoporous Mater 155:240–244
43.
Murray DK (2010) Differentiating and characterizing geminal silanols in silicas by 29Si NMR spectroscopy. J Colloid Interface Sci 352:163–170PubMed
44.
Kim HN, Lee SK (2013) Atomic structure and dehydration mechanism of amorphous silica: insights from 29Si and 1H solid-state MAS NMR study of SiO2 nanoparticles. Geochim Cosmochim Acta 120:39–64
45.
Zulfiqar S, Ahmad Z, Ishaq M, Saeed S, Sarwar MI (2007) 2007, Thermal and mechanical properties of SEBS-g-MA based inorganic composite materials. J Mater Sci 42:93–100
46.
Ganguly A, Bhowmick AK (2008) Sulfonated Styrene-(ethylene-co-butylene)-styrene/Montmorillonite Clay Nanocomposites: synthesis, Morphology, and Properties. Nanoscale Res Lett 3:36–44
47.
Mader D, Bruch M, Maier R-D, Stricker F, Mulhaupt R (1999) Glass transition temperature depression of elastomers blended with poly(propene)s of different stereoregularities. Macromolecules 32:1252–1259
48.
Wang L, Hong S, Hu H, Zhao J, Han CC (2007) The surface morphology evolution of an ultrathin film of poly[styrene-b-(ethylene-co-butylene)-b-styrene] during its dewetting process. Langmuir 23:2304–2307PubMed
49.
Bar G, Thomann Y, Wangbo M-H (1998) Characterization of the morphologies and nanostructures of blends of poly(styrene)-block-poly(ethene-co-but-1-ene)-block-poly(styrene) with Isotactic and atactic polypropylenes by tapping-mode atomic force microscopy. Langmuir 14:1219–1226
50.
Yadav SK, Mahapatra SS, Cho JW, Lee JY (2010) Functionalization of multiwalled carbon nanotubes with poly(styrene-b-(ethylene-co-butylene)-b-styrene) by click coupling. J Phys Chem C 114:11395–11400
Metadata
Title
Preparation and characterization of maleic anhydride grafted SEBS/silica composites through modification by ethanolamine
Authors
Pao-Lin Chuang
Yu-Hsun Nien
Publication date
01-07-2019
Publisher
Springer Berlin Heidelberg
Published in
Polymer Bulletin / Issue 5/2020
Print ISSN: 0170-0839
Electronic ISSN: 1436-2449
DOI
https://doi.org/10.1007/s00289-019-02868-y

Other articles of this Issue 5/2020

Polymer Bulletin 5/2020 Go to the issue

Original Paper

Poly(amino acid)/ZnO nanoparticles nanocomposites with enhanced thermal, mechanical, and antibacterial properties

Original Paper

Crystallization behavior of plasticized poly(lactide) film by poly(l-lactic acid)-poly(ethylene glycol)-poly(l-lactic acid) triblock copolymer

Original Paper

Microstructure characterization of low molecular weight polybutadiene using the chain end groups by nuclear magnetic resonance spectroscopy

Original Paper

Electrical, thermal behaviors and synthesis of intramolecular cobalt phthalocyanine with single-chain polymer structure

Original Paper

Synthesis, characterization and applications of nano-Ag-tagged poly(ε-caprolactone-block-tetrahydrofuran)

Original Paper

The synthesis of rGO/RuO2, rGO/PANI, RuO2/PANI and rGO/RuO2/PANI nanocomposites and their supercapacitors

Premium Partners

    Image Credits