Skip to main content
Disciplines
Automotive Business IT + Informatics Construction + Real Estate Electrical Engineering + Electronics Energy + Sustainability Insurance + Risk Finance + Banking Management + Leadership Marketing + Sales Mechanical Engineering + Materials
Events
DE
EN
Books
Journals
Topic Page
Marketing
Start single access now
Access for companies
EXTENDED SEARCH
Log in
Top
Journal of Materials Science
Published in: Journal of Materials Science 7/2018

26-12-2017 | Chemical routes to materials

Preparation and evaluation of superparamagnetic core–shell dummy molecularly imprinted polymer for recognition and extraction of organophosphorus pesticide

Authors: Mengxing Wei, Xiangyang Yan, Shaomin Liu, Yuxin Liu

Published in: Journal of Materials Science | Issue 7/2018

Log in

Activate our intelligent search to find suitable subject content or patents.

search-config
loading …

Abstract

In this paper, we reported a simple and effective strategy to synthesize core–shell dummy template magnetic molecularly imprinted polymers (Fe3O4@DMIPs) using ethyl paraoxon as a template for the recognition and selective extraction of organophosphorus pesticide. Initially, monodisperse Fe3O4 nanoparticles were synthesized directly through a facile one-pot hydrothermal method. Then, the imprinted layer was synthesized directly on the surface of the magnetic core by means of a one-pot sol–gel copolymerization which avoided further modification of the external part of the magnetic core. The structure and morphology of the materials (Fe3O4@DMIPs) were characterized by SEM, TEM, FTIR, XRD, and VSM. It was observed that Fe3O4@DMIPs showed regular morphology, good dispersibility, and superparamagnetism. The synthesis conditions for the formation of Fe3O4@DMIPs were systematically investigated. It was found that the morphology and monodispersity of Fe3O4@DMIPs were highly influenced by the ratio of the mixture solvent of methanol and water and the volume ratio of functional monomer (APTES) and cross-linker (TEOS). The binding performance of the imprinted polymers was investigated through a series of adsorption experiments, which indicated that the Fe3O4@DMIPs had a fast adsorption rate (15 min) and high adsorption capacity (195.7 mg g−1) to methyl parathion and phoxim. Meanwhile, real wine sample tests demonstrated a good extraction effect. This study provides a possibility for the selective extraction of organophosphorus pesticide residue in a complex matrix.
previous article Confined hexahedral nickel nanoparticle catalyst for catalytic hydrogenation reaction
next article MOF-derived various morphologies of N-doped carbon composites for acetylene hydrochlorination

Dont have a licence yet? Then find out more about our products and how to get one now:

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

  • über 102.000 Bücher
  • über 537 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Finance + Banking
  • Management + Führung
  • Marketing + Vertrieb
  • Maschinenbau + Werkstoffe
  • Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

inform now

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

  • über 67.000 Bücher
  • über 390 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Maschinenbau + Werkstoffe




 

Jetzt Wissensvorsprung sichern!

inform now
Literature
1.
Yang YQ, Tu HY, Zhang AD, Du D, Lin YH (2012) Preparation and characterization of Au–ZrO2–SiO2 nanocomposite spheres and their application in enrichment and detection of organophosphorus agents. J Mater Chem 22:4977–4981CrossRef
2.
Haginaka J, Tabo H, Matsunaga H (2012) Preparation of molecularly imprinted polymers for organophosphates and their application to the recognition of organophosphorus compounds and phosphopeptides. Anal Chim Acta 748:1–8CrossRef
3.
4.
Zhou MC, Hu F, He H, Shu SH, Wang M (2015) Determination of phosphorothioate pesticides in environmental water by molecularly imprinted matrix solid-phase dispersion coupled with gas chromatography and a nitrogen phosphorus detector. Instrum Sci Technol 43:669–680CrossRef
5.
Zheng ZZ, Li XY, Dai ZF, Liu SQ, Tang ZY (2011) Detection of mixed organophosphorus pesticides in real samples using quantum dots/bi-enzyme assembly multilayers. J Mater Chem 21:16955–16962CrossRef
6.
Xin JH, Qiao XG, Ma Y, Xu ZX (2012) Simultaneous separation and determination of eight organophosphorous pesticide residues in vegetables through molecularly imprinted solid-phase extraction coupled to gas chromatography. J Sep Sci 35:3501–3508CrossRef
7.
Ohno K, Minami T, Matsui Y, Magara Y (2008) Effects of chlorine on organophosphorus pesticides adsorbed on activated carbon: desorption and oxon formation. Water Res 42:1753–1759CrossRef
8.
Lebel GL, Williams DT, Griffith G, Benoit FM (1979) Isolation and concentration of organophosphorus pesticides from drinking water at the ng/L level, using macroreticular resin. J Assoc Off Anal Chem 62:241–249
9.
Moral A, Sicilia MD, Rubio S, Perez-Bendito D (2008) Multifunctional sorbents for the extraction of pesticide multiresidues from natural waters. Anal Chim Acta 608:61–72CrossRef
10.
Liu XT, Zhang HY, Ma YQ, Wu XL, Meng LX, Guo YL, Yu G, Liu YQ (2013) Graphene-coated silica as a highly efficient sorbent for residual organophosphorus pesticides in water. J Mater Chem A 1:1875–1884CrossRef
11.
12.
Xin JH, Qiao XG, Xu ZX, Zhou J (2013) Molecularly imprinted polymer as sorbent for solid-phase extraction coupling to gas chromatography for the simultaneous determination of trichlorfon and monocrotophos residues in vegetables. Food Anal Methods 6:274–281CrossRef
13.
14.
Xu LH, Fang GZ, Pan MF, Wang XF, Wang S (2016) One-pot synthesis of carbon dots-embedded molecularly imprinted polymer for specific recognition of sterigmatocystin in grains. Biosens Bioelectron 77:950–956CrossRef
15.
16.
17.
Bui BTS, Haupt K (2010) Molecularly imprinted polymers: synthetic receptors in bioanalysis. Anal Bioanal Chem 398:2481–2492CrossRef
18.
Maryam A, Mehrorang G, Abbas O (2017) Water compatible molecularly imprinted nanoparticles as a restricted access material for extraction of hippuric acid, a biological indicator of toluene exposure, from human urine. Microchim Acta 184:879–887CrossRef
19.
Matsui J, Sodeyama T, Saiki Y, Miyazawa T, Yamada T, Tamaki K, Murashima T (2009) Face-to-face porphyrin moieties assembled with spacing for pyrazine recognition in molecularly imprinted polymers. Biosens Bioelectron 25:635–639CrossRef
20.
Basabe-Desmonts L, Reinhoudt DN, Crego-Calama M (2007) Design of fluorescent materials for chemical sensing. Chem Soc Rev 36:993–1017CrossRef
21.
Xu ZX, Fang GZ, Wang S (2010) Molecularly imprinted solid phase extraction coupled to high-performance liquid chromatography for determination of trace dichlorvos residues in vegetables. Food Chem 119:845–850CrossRef
22.
Zhu XL, Yang J, Su QD, Cai JB, Gao Y (2005) Selective solid-phase extraction using molecularly imprinted polymer for the analysis of polar organophosphorus pesticides in water and soil samples. J Chromatogr A 1092:161–169CrossRef
23.
Meng L, Qiao XG, Song JM, Xu ZX, Xin JH, Zhang YS (2011) Study of an online molecularly imprinted solid phase extraction coupled to chemiluminescence sensor for the determination of trichlorfon in vegetables. J Agric Food Chem 59:12745–12751CrossRef
24.
Li DQ, Qiao XG, Lu JX, Xu ZX (2016) Synthesis and evaluation of a magnetic molecularly imprinted polymer sorbent for determination of trace trichlorfon residue in vegetables by capillary electrophoresis. Adv Polym Technol. https://​doi.​org/​10.​1002/​adv.​21745
25.
Wang XL, Tang QH, Wang QQ, Qiao XG, Xu ZX (2014) Study of a molecularly imprinted solid-phase extraction coupled with high-performance liquid chromatography for simultaneous determination of trace trichlorfon and monocrotophos residues in vegetables. J Sci Food Agric 94:1409–1415CrossRef
26.
27.
Zhu XL, Cai JB, Yang J, Su QD, Gao Y (2006) Films coated with molecular imprinted polymers for the selective stir bar sorption extraction of monocrotophos. J Chromatogr A 1131:37–44CrossRef
28.
Xu SF, Li JH, Chen LX (2011) Molecularly imprinted core–shell nanoparticles for determination of trace atrazine by reversible addition-fragmentation chain transfer surface imprinting. J Mater Chem 21:4346–4351CrossRef
29.
Lu AH, Salabas EL, Schuth F (2007) Magnetic nanoparticles: synthesis, protection, functionalization, and application. Angew Chem Int Ed 46:1222–1244CrossRef
30.
Xu SY, Guo CJ, Li YX, Yu ZR, Wei CH, Tang YW (2014) Methyl parathion imprinted polymer nanoshell coated on the magnetic nanocore for selective recognition and fast adsorption and separation in soils. J Hazard Mater 264:34–41CrossRef
31.
Lu CH, Wang Y, Li Y, Yang HH, Chen X, Wang XR (2009) Bifunctional superparamagnetic surface molecularly imprinted polymer core–shell nanoparticles. J Mater Chem 19:1077–1079CrossRef
32.
Miao SS, Wu MS, Zuo HG, Jiang C, Jin SF, Lu YC, Yang H (2015) Core–shell magnetic molecularly imprinted polymers as sorbent for sulfonylurea herbicide residues. J Agric Food Chem 63:3634–3645CrossRef
33.
Ma GF, Chen LG (2014) Determination of chlorpyrifos in rice based on magnetic molecularly imprinted polymers coupled with high-performance liquid chromatography. Food Anal Methods 7:377–388CrossRef
34.
Pan JM, Li LZ, Hang H, Wu RR, Dai XH, Shi WD, Yan YS (2013) Fabrication and evaluation of magnetic/hollow double-shelled imprinted sorbents formed by Pickering emulsion polymerization. Langmuir 29:8170–8178CrossRef
35.
Liu BH, Han MY, Guan GJ, Wang SH, Liu RY, Zhang ZP (2011) Highly-controllable molecular imprinting at superparamagnetic iron oxide nanoparticles for ultrafast enrichment and separation. J Phys Chem C 115:17320–17327CrossRef
36.
Zhou MC, Hu NN, Shu SH, Wang M (2015) Molecularly imprinted nanomicrospheres as matrix solid-phase dispersant combined with gas chromatography for determination of four phosphorothioate pesticides in carrot and yacon. J Anal Methods Chem. https://​doi.​org/​10.​1155/​2015/​385167
37.
Zhang L, Liu XY, Qiu J, Yao X, Zhou PY, Li MQ (2014) Preparation and characterization of broad-spectrum artificial antibody for OPPs based on dummy imprinting technique. Int J Polym Anal Charact 19:510–521CrossRef
38.
Liu J, Sun ZK, Deng YH, Zou Y, Li CY, Guo XH, Xiong LQ, Gao Y, Li FY, Zhao DY (2009) Highly water-dispersible biocompatible magnetite particles with low cytotoxicity stabilized by citrate groups. Angew Chem Int Ed 48:5989–5993CrossRef
39.
Liu WJ, Yan XY, Yong GP, Liu SM (2014) One-pot synthesis of yolk–shell mesoporous carbon spheres with high magnetisation. J Mater Chem A 2:9600–9606CrossRef
40.
41.
Chang LM, Chen SN, Li X (2012) Synthesis and properties of core–shell magnetic molecular imprinted polymers. Appl Surf Sci 258:6660–6664CrossRef
42.
Izutsu H, Nair PK, Maeda K, Kiyozumi Y, Mizukami F (1997) Structure and properties of TiO2 SiO2 prepared by sol–gel method in the presence of tartaric acid. Mater Res Bull 32:1303–1311CrossRef
43.
Yang R, Liu YX, Yan XY, Liu SM, Zheng HS (2016) An effective method for the synthesis of yolk–shell magnetic mesoporous carbon-surface molecularly imprinted microspheres. J Mater Chem A 4:9807–9815CrossRef
44.
Mangold KM, Schuster J, Weidlich C (2011) Synthesis and properties of magnetite/polypyrrole core–shell nanocomposites and polypyrrole hollow spheres. Electrochim Acta 56:3616–3619CrossRef
45.
Zhang XB, Tong HW, Liu SM, Yong GP, Guan YF (2013) An improved Stöber method towards uniform and monodisperse Fe3O4@C nanospheres. J Mater Chem A 1:7488–7493CrossRef
46.
Ma ZY, Guan YP, Liu HZ (2005) Synthesis and characterization of micron-sized monodisperse superparamagnetic polymer particles with amino groups. J Polym Sci A Polym Chem 43:3433–3439CrossRef
47.
Chang TT, Liu YX, Yan XY, Liu SM, Zheng HS (2016) One-pot synthesis of uniform and monodisperse superparamagnetic molecularly imprinted polymer nanospheres through a sol–gel process for selective recognition of bisphenol A in aqueous media. RSC Adv 6:66297–66306CrossRef
48.
Stober W, Fink A, Bohn E (1968) Controlled growth of monodisperse silica spheres in the micron size range. J Colloids Interface Sci 26:62–69CrossRef
Metadata
Title
Preparation and evaluation of superparamagnetic core–shell dummy molecularly imprinted polymer for recognition and extraction of organophosphorus pesticide
Authors
Mengxing Wei
Xiangyang Yan
Shaomin Liu
Yuxin Liu
Publication date
26-12-2017
Publisher
Springer US
Published in
Journal of Materials Science / Issue 7/2018
Print ISSN: 0022-2461
Electronic ISSN: 1573-4803
DOI
https://doi.org/10.1007/s10853-017-1935-3

Other articles of this Issue 7/2018

Journal of Materials Science 7/2018 Go to the issue

Polymers

Poly(NIPAAm-co-Ru(bpy) 3 2+ ) hydrogels crosslinked by double-bond end-capped Pluronic F127: preparation, properties and coupling with the BZ reaction

Energy materials

Augmentation of power conversion efficiency of amorphous silicon solar cell employing poly(methyl methacrylate-co-acrylic acid) nanospheres encapsulated with gold nanoparticles

Chemical routes to materials

One-step hydrothermal synthesis of peony-like Ag/Bi2WO6 as efficient visible light-driven photocatalyst toward organic pollutants degradation

Chemical routes to materials

Visible light photocatalytic oxidative desulfurization using Ti-MCM-41-loaded iron phthalocyanine combined with ionic liquid extraction

Composites

Effects of nano-SiO2 on the permeability-related properties of cement-based composites with different water/cement ratios

Energy materials

Fabrication of hierarchical MoO3–PPy core–shell nanobelts and “worm-like” MWNTs–MnO2 core–shell materials for high-performance asymmetric supercapacitor

Premium Partners

    Image Credits