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Published in: Journal of Sol-Gel Science and Technology 2/2015

01-02-2015 | Original Paper

Preparation and separation properties of porous norbornane-bridged silica membrane

Authors: Joji Ohshita, Haruna Muragishi, Kazuki Yamamoto, Tomonobu Mizumo, Masakoto Kanezashi, Toshinori Tsuru

Published in: Journal of Sol-Gel Science and Technology | Issue 2/2015

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Abstract

Bis(trimethoxysilyl)norbornane (BTMSN) bearing a highly rigid norbornane bridge was employed as a new silica membrane precursor. The membrane prepared by subjecting BTMSN to the sol–gel process was examined for gas and water separation, and the results were compared with those of ethylene- and ethenylene-bridged silica membranes reported previously. Interestingly, the gas permeability of the BTMSN silica membrane was higher than that of the ethylene- and ethenylene-bridged silica membranes, whereas the water permeability was rather suppressed. The moderately high H2/SF6 permeance ratio of 1,160 and the NaCl rejection of 95 % (2,000 ppm aqueous NaCl) obtained for the BTMSN silica membrane clearly indicate its potential application to gas and water separation.

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Metadata
Title
Preparation and separation properties of porous norbornane-bridged silica membrane
Authors
Joji Ohshita
Haruna Muragishi
Kazuki Yamamoto
Tomonobu Mizumo
Masakoto Kanezashi
Toshinori Tsuru
Publication date
01-02-2015
Publisher
Springer US
Published in
Journal of Sol-Gel Science and Technology / Issue 2/2015
Print ISSN: 0928-0707
Electronic ISSN: 1573-4846
DOI
https://doi.org/10.1007/s10971-014-3542-y

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