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Journal of Sol-Gel Science and Technology
Published in: Journal of Sol-Gel Science and Technology 2/2018

11-01-2018 | Original Paper: Industrial and technological applications of sol-gel and hybrid materials

Preparation of fluoroalkyl end-capped vinyltrimethoxysilane oligomeric silica/boric acid/poly(N-methyl benzamide)-b-poly(propylene oxide) block copolymer nanocomposites – no weight loss behavior of the block copolymer in the nanocomposites even after calcination at 800 °C

Authors: Yuta Aomi, Yoshiyuki Oishi, Yuji Shibasaki, Yuki Aikawa, Mitsutoshi Jikei, Masakazu Nishida, Shohei Yamazaki, Hideo Sawada

Published in: Journal of Sol-Gel Science and Technology | Issue 2/2018

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Abstract

Fluoroalkyl end-capped vinyltirimethoxysilane oligomeric silica/boric acid nanocomposites [RF-(VM-SiO2) n -RF/B(OH)3] were prepared by the composite reaction of the corresponding fluorinated oligomer [RF-(CH2CHSi(OMe)3) n -RF, n = 2, 3; RF = CF(CF3)OC3F7: RF-(VM) n -RF] with boric acid. The nanocomposites thus obtained were tried to interact with the thermoplastic elastomers such as poly(N-methyl benzamide)-b-poly(propylene oxide) block copolymers [(MAB) m-m -b-PPO32: m = 5, 6, 7, and 8] and poly(ethersulfone)-b-poly(tetrahydrofuran)-b-poly(ethersulfone) triblock copolymer [PES-b-PTHF-b-PES] under alkaline conditions to afford the corresponding RF-(VM-SiO2) n -RF/B(OH)3/thermoplastic elastomers nanocomposites. We also tried to prepare the corresponding RF-(VM-SiO2) n -RF/thermoplastic elastomers nanocomposites under similar conditions, for comparison. In these thermoplastic elastomers, PES-b-PTHF-b-PES triblock copolymers cannot interact with the RF-(VM-SiO2) n -RF/B(OH)3 nanocomposites or the RF-(VM-SiO2) n -RF oligomeric nanoparticles to supply the expected nanocomposite products. However, it was demonstrated that the (MAB) m-m -b-PPO32 block copolymers can react with the RF-(VM-SiO2) n -RF/B(OH)3 nanocomposites under alkaline conditions to afford the RF-(VM-SiO2) n -RF/B(OH)3/(MAB) m-m -b-PPO32 nanocomposites, providing no weight loss characteristic corresponding to the contents of the block copolymers in the composites even after calcination at 800 °C, although these expected nanocomposites were isolated without purification process. The RF-(VM-SiO2) n -RF/(MAB) 5-5 -b-PPO32 nanocomposites, which were isolated under similar process, were also able to supply no weight loss in proportion to the content of the copolymer in the nanocomposites even after calcination at 800 °C.

Graphical abstract

https://static-content.springer.com/image/art%3A10.1007%2Fs10971-017-4563-0/MediaObjects/10971_2017_4563_Figa_HTML.gif
previous article Structural, optical, and magnetic studies of iodine-doped CdO nanopowders and films
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Literature
1.
Chrusciel JJ, Janowska G, Fejdys M (2012) J Therm Anal Calorim 109:1049–1058CrossRef
2.
3.
Sreejith KJ, Prabhakaran PV, Laly KP, Dimple R, Packirisamy S (2016) Ceram Int 42:15285–15293CrossRef
4.
Soraru GD, Babonneau F, Maurina S, Vicens J (1998) J Non-Cryst Solids 224:173–1CrossRef
5.
6.
Xie S, Wang Y, Lei Y, Wang B, Wu N, Gou Y, Fang D (2015) RSC Adv 5:64911–64917CrossRef
7.
8.
Woilliams HM, Dawson EA, Barnes PA, Rand B, Brydson RMD (2007) Micro Mesoporous Mater 99:261–267CrossRef
9.
10.
11.
12.
Hoshi S, Kojima A, Endou H, Otani S, Satou T, Nakaido Y, Hasegawa Y (1994) Tanso 161:23CrossRef
13.
Devapal D, Packirisamy S, Sreejith KJ, Ravindran PV, George BK (2010) J Inorg Organomet Polym 20:666–674CrossRef
14.
Schiavon MA, Armelin NA, Yoshida IVP (2008) Mater Chem Phys 112:1047–1054CrossRef
15.
Bai HW, Wen G, Huang XX, Han ZX, Zhong B, Hu ZX, Zhang XD (2011) J Eur Ceram Soc 31:977–940CrossRef
16.
Wenjun Z, Jian S, Youcai C, Xueqin W, Jingli Z (2012) CIES J 63:3365–3371
17.
Bai HW, Wen G, Huang XX, Han ZX, Zhong B, Hu ZX, Zhang XD (2011) J Eur Ceram Soc 31:931–940CrossRef
18.
19.
Siqueira RL, Yoshida IVP, Paradini LC, Schiavon MA (2007) Mater Res 10:147–151CrossRef
20.
Soraru GD, Babonneau F, Gervais C, Dallabona N (2000) J Sol-Gel Sci Technol 18:11–19CrossRef
21.
Ameduri B, Sawada H (eds) (2016) Fluorinated polymers: vol 1. Synthesis, Properties, Processing and Simulation. RSC, Cambridge
22.
Ameduri B, Sawada H (eds) (2016) Fluorinated polymers: vol 2. Applications. RSC, Cambridge
23.
24.
25.
26.
Takashima H, Iwaki K, Furukuwa R, Takishita K, Sawada H (2008) J Colloid Interface Sci 320:436–444CrossRef
27.
Kijima T, Nishida M, Fukaya H, Yoshida M, Sawada H (2013) J Polym Sci Part A: Polym Chem 51:2555–2564CrossRef
28.
29.
30.
Sawada H, Sasaki A, Sasazawa K (2009) Colloid Surf A: Physicochem Eng Asp 337:57–60CrossRef
31.
32.
Soma S, Mizutani Y, Sugiya M, Sawada H (2014) J Polym Sci, Part A: Polym Chem 52:1869–1877CrossRef
33.
Sawada E, Kakehi H, Chounan Y, Miura M, Sato Y, Isu N, Sawada H (2010) Compos Part B 41:498–502CrossRef
34.
Guo S, Yoshioka H, Kakehi H, Kato Y, Miura M, Isu N, Ameduri B, Sawada H (2012) J Colloid Interface Sci 387:141–145CrossRef
35.
Guo S, Yoshioka H, Kato Y, Kakehi H, Miura M, Isu N, Manseri A, Sawada H, Ameduri B (2014) Eur Polym J 58:79–89CrossRef
36.
Mulazim Y, Kahraman MV, Apohan NK, Kiziltas S, Gungor A (2011) J Appl Polym Sci 120:2112–2121CrossRef
37.
Aomi Y, Nishida M, Sawada H (2016) J Polym Sci, Part A: Polym Chem 54:3835–3845CrossRef
38.
Sawada H, Nakayama M, J (1991) Chem Soc Chem Commun 677–678
39.
Mori T, Masukawa S, Kikkawa T, Fujimori A, Satoh A, Matsumoto K, Jikei M, Oishi Y, Shibasaki Y (2017) RSC Adv 7:33812–33821CrossRef
40.
41.
Sawada H, Suzuki T, Takashima H, Takishita K (2008) Colloid Polym Sci 286:1569–1574CrossRef
42.
Gervais C, Babonneau F, Dallabonna N, Soraru GD (2001) J Am Cerm Soc 84:2160–2164CrossRef
43.
Soraru GD, Babonneau F, Maurina S, Vicens J (1998) J Non-Crystallogr Solids 224:173–183CrossRef
44.
Yamada K, Shimizu T, Deguchi K, Ando S, Kamada H, Kobayashi T (2011) Polym. Preprints Jpn. 60, No 1, 2D26
45.
46.
47.
Turner GL, Smith KA, Kirkpatrick RJ, Oldfield E (1986) J Magn Res 67:544–550
48.
Sawada H, Narumi T, Kodama S, Kamijo M, Ebara R, Sugiya M, Iwasaki Y (2007) Colloid Polym Sci 285:977–983CrossRef
49.
50.
Sawada H, Kakehi H, Tashima T, Nishiyama Y, Miura M, Isu N (2009) J Appl Polym Sci 112:3482–3487CrossRef
51.
Goto Y, Matsuki Y, Nishida M, Oyama S, Chikama K, Sawada H (2011) Colloid Polym Sci 290:11–21CrossRef
52.
Sawada H, Tashima T, Nishiyama Y, Kikuchi M, Kostov G, Goto Y, Ameduri B (2011) Macromolecules 44:1114–1124CrossRef
53.
Sawada H, Matsuki Y, Goto Y, Kodama S, Sugiya M, Nishiyama Y (2010) Bull Chem Soc Jpn 83:75–81CrossRef
54.
Sawada H, Kikuchi M, Nishida M, Polym. Sci. Part J (2011) A: Polym Chem 2011:1070–1078. 49
55.
Sawada H, Tashima T, Kakehi H, Nishiyama Y, Kikuchi M, Miura M, Sato Y, Isu N (2010) Polym J 42:167–171CrossRef
Metadata
Title
Preparation of fluoroalkyl end-capped vinyltrimethoxysilane oligomeric silica/boric acid/poly(N-methyl benzamide)-b-poly(propylene oxide) block copolymer nanocomposites – no weight loss behavior of the block copolymer in the nanocomposites even after calcination at 800 °C
Authors
Yuta Aomi
Yoshiyuki Oishi
Yuji Shibasaki
Yuki Aikawa
Mitsutoshi Jikei
Masakazu Nishida
Shohei Yamazaki
Hideo Sawada
Publication date
11-01-2018
Publisher
Springer US
Published in
Journal of Sol-Gel Science and Technology / Issue 2/2018
Print ISSN: 0928-0707
Electronic ISSN: 1573-4846
DOI
https://doi.org/10.1007/s10971-017-4563-0

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