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Polymer Bulletin
Published in: Polymer Bulletin 12/2023

10-01-2023 | ORIGINAL PAPER

Preparation of primary magnesium battery based on kappa carrageenan with magnesium perchlorate and its application to electrochemical devices

Authors: P. Sangeetha, T. M. Selvakumari, S. Selvasekarapandian, M. Mahalakshmi

Published in: Polymer Bulletin | Issue 12/2023

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Abstract

In this work, biodegradable solid polymer electrolyte films made up of 1 g K-C with different Mwt% ratios of Mg(ClO4)2 were prepared using solution casting technique at room temperature. XRD, FTIR, AC impedance, transference number measurements and linear sweep voltammetry, studies on the structural, electrical and electrochemical behaviour of kappa carrageenan are conducted. The highest conductivity 6.28 × 10−3S/cm at room temperature is found for K-C (1 g):0.5 Mwt% of Mg(ClO4)2 biopolymer membrane. The complex formation between K-C (1 g):Mg(ClO4)2 has been confirmed by FTIR measurement. Electrochemical stability is found for highest Mg2+-ion conducting biopolymer membrane. The measurement of transference number showed that electrolytic conduction was dominated by ions. Primary Mg-ion battery has been constructed using the highest Mg-ion conducting film, and its performance is studied. The constructed primary battery exhibits an open-circuit potential of 2.36 V at room temperature.
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Literature
1.
Tripathi SK, Jain A, Gupta A, Mishra M (2012) Electrical and electrochemical studies on magnesium ion-based polymer gel electrolytes. J Solid State Electrochem 16(5):1799–1806CrossRef
2.
Dung NTK, Linh NTD, Tham DQ, Chinh NT, Tan MM, Mai TT, Hoang T (2020) Effect of magnesium perchlorate content on the mechanical, thermal stability, and dielectric properties of plasticized PMMA/PVC-g-PMMA electrolytes. Adv Polym Technol Article ID 2806242:1–9
3.
Liu W, Liu N, Sun J, Hsu PC, Li Y, Lee HW, Cui Y (2015) Ionic conductivity enhancement of polymer electrolytes with ceramic nanowire fillers. Nano Lett 15(4):2740–2745PubMedCrossRef
4.
Kotobuki M, Lu L, Savilov SV, Aldoshin SM (2017) Poly(vinylidene fluoride)-based Al ion conductive solid polymer electrolyte for Al battery. J Electrochem Soc 164(14):A3868–A3875CrossRef
5.
Premalatha M, Mathavan T, Selvasekarapandian S, Selvalakshmi S, Monisha S (2017) Incorporation of NH4Br in tamarind seed polysaccharide biopolymer and its potential use in electrochemical energy storage devices. Org Electron 50:418–425CrossRef
6.
Van de Velde F, Knutsen SH, Usov AI, Rollema HS, Cerezo AS (2002) 1H and 13C high resolution NMR spectroscopy of carrageenans: application in research and industry. Trends Food Sci Technol 13(3):73–92CrossRef
7.
Campo VL, Kawano FF, Silva Junior DB, Carvalho I (2009) Carrageenans: 526 biological properties, chemical modifications and structural analysis. Carbohyd Polym 77:167–180CrossRef
8.
9.
Ng CA, Camacho DH (2015) Polymer electrolyte system based on carrageenan-poly(3,4- ethylene dioxythiophene) (PEDOT) composite for dye sensitized solar cell. IOP Conf Ser Mater Sci Eng 79:012020CrossRef
10.
Li L, Ni R, Shao Y, Mao S (2014) Carrageenan and its applications in drug delivery. Carbohyd Polym 103:1–11CrossRef
11.
Arockia Mary I, Selvanayagam S, Selvasekarapandian S, Srikumar SR, Ponraj T, Moniha V (2019) Lithium ion conducting membrane based on K-carrageenan complexed with lithium bromide and its electrochemical applications. J Ion 25(10):5839–5855CrossRef
12.
Arockia Mary I, Selvanayagam S, Selvasekarapandian S, Chitra R, Leena Chandra MV, Ponraj T (2020) Lithium ion conducting biopolymer membrane based on K-carrageenan with LiNO3. J Ion 26:4311–4326CrossRef
13.
Christopher Selvin P, Perumal P, Selvasekarapandian S, Monisha S, Boopathi G, Leena Chandra MV (2018) Study of proton-conducting polymer electrolyte based on K-carrageenan and NH4SCN for electrochemical devices. Ionics 24(11):3535–3542 CrossRef
14.
Zainuddin NK, Samsudin AS (2018) Investigation on the effect of NH4Br at transport properties in k–carrageenan based biopolymer electrolytes via structural and electrical analysis. Mater Today Commun 14:199–209CrossRef
15.
Karthikeyan S, Selvasekarapandian S, Premalatha M, Monisha S, Boopathi G, Aristatil G, Arun A, Madeswaran S (2017) Proton-conducting I-carrageenan-based biopolymer electrolyte for fuel cell application. Ionics 23(10):2775–2780CrossRef
16.
Moniha V, Alagar M, Selvasekarapandian S, Sundaresan B, Boopathi G (2018) Conductive bio-polymer electrolyte iota-carrageenan with ammonium nitrate for application in electrochemical devices. J Non-Cryst Solids 481(C):424–434CrossRef
17.
Shuhaimi NEA, Alias NA, Majid SR, Arof AK (2008) Electrical double layer capacitor with proton conducting k- carrageenan-chitosan electrolytes. Funct Mater Lett 01(03):195–201CrossRef
18.
Koketsu T, Ma J, Morgan BJ, Body M, Legein C, Dachraoui W, Dambournet D (2017) Reversible magnesium and aluminium ions insertion in cation-deficient anatase TiO2. Nat Mater 16(11):1142–1148PubMedCrossRef
19.
Sheha E (2016) Ion transport properties of magnesium bromide/dimethyl sulfoxide non-aqueous liquid electrolyte. J Adv Res 7(1):29–36PubMedCrossRef
20.
Manjuladevi R, Thamilselvan M, Selvasekarapandian S, Mangalam R, Premalatha M, Monisha S (2017) Mg-ion conducting blend polymer electrolyte based on poly(vinyl alcohol)-poly (acrylonitrile) with magnesium perchlorate. Solid State Ion 308:90–100CrossRef
21.
Mahalakshmi M, Selvanayagam S, Selvasekarapandian S, Moniha V, Manjuladevi R, Sangeetha P (2019) Characterization of biopolymer electrolytes based on cellulose acetates with magnesium perchlorate (Mg(ClO4)2) for energy storage devices. J Sci Adv Mater Devices 4(2):276–284CrossRef
22.
Mangalam R, Thamilselvan M, Selvasekarapandian S, Jayakumar S, Manjuladevi R (2016) Polyvinyl pyrrolidone/Mg(ClO4)2 solid polymer electrolyte: structural and electrical studies. Ionics 23(10):2837–2843CrossRef
23.
Shanmuga Priya S, Karthika M, Selvasekarapandian S, Manjuladevi R, Monisha S (2018) Study of biopolymer I-carrageenan with magnesium perchlorate. Ionics 24(12):3861–3875CrossRef
24.
Perumal P, Abhilash KP, Sivaraj P, Selvin PC (2019) Study on Mg-ion conducting solid biopolymer electrolytes based on tamarind seed polysaccharide for magnesium ion batteries. Mater Res Bull 118:110490CrossRef
25.
Hodge RM, Edward GH, Simon GP (1996) Water absorption and states of water in semicrystalline poly (vinyl alcohol) films. Polymer 37(8):1371–1376CrossRef
26.
Pereira L, Amado AM, Critchley AT, van de Velde F, Ribeiro-Claro PJA (2009) Identification of selected seaweed polysaccharides (phycocolloids) by vibrational spectroscopy (FTIR-ATR and FTRaman). Food Hydrocoll 23(7):1903–1909CrossRef
27.
Mishra R, Baskaran N, Ramakrishnan PA, Rao KJ (1998) Lithium ion conduction in extreme polymer in salt regime. Solid State Ion 112(3):261–273CrossRef
28.
Ramya CS, Selvasekarapandian S, Savitha T, Hirankumar G, Baskaran R, Bhuvaneswari MS, Angelo PC (2006) Conductivity and thermal behavior of proton conducting polymer electrolyte based on poly (N-vinyl pyrrolidone). Eur Polym J 42(10):2672–2677CrossRef
29.
Kim C, Lee G, Liou K, Ryu KS, Kang SG, Chang SH (1999) Polymer electrolytes prepared by polymerizing mixtures of polymerizable PEO-oligomers, copolymer of PVDC and poly (acrylonitrile), and lithium triflate. Solid State Ion 123(1–4):251–257CrossRef
30.
Martins JT, Cerqueira MA, Bourbon AI, Pinheiro AC, Souza BWS, Vicente AA (2012) Synergistic effects between k-carrageenan and locust bean gum on physicochemical properties of edible films made thereof. Food Hydrocoll 29(2):280–289CrossRef
31.
Subba Reddy CV, Han X, Zhu Q-Y, Mai L-Q, Chen W (2006) Conductivity and discharge characteristics of (PVC + NaClO4) polymer electrolyte systems. Eur Polym J 42:3114–3120CrossRef
32.
Selvalakshmi S, Vijaya N, Selvasekarapandian S, Premalatha M (2016) Biopolymer agar-agar doped with NH4SCN as solid polymer electrolyte for electrochemical cell application. J Appl Polym Sci 134(15):44702CrossRef
33.
PaGcalsu V, Popescu V, Popescu GL, Dudescu MC, Borodi G, Dinescu AM, Moldovan M (2013) Obtaining and characterizing alginate/k-carrageenan hydrogel cross-linked with adipic dihydrazide. Adv Mater Sci Eng 2013:1–12CrossRef
34.
Vijaya N, Selvasekarapandian S, Hirankumar G, Karthikeyan S, Nithya H, Ramya CS, Prabu M (2012) Structural, vibrational, thermal, and conductivity studies on proton-conducting polymer electrolyte based on poly (N-vinylpyrrolidone). Ionics 18(1–2):91–99CrossRef
35.
NirmalaDevi G, Chitra S, Selvasekarapandian S, Premalatha M, Monisha S, Saranya J (2017) Synthesis and characterization of dextrin-based polymer electrolytes for potential applications in energy storage devices. Ionics 23(12):3377–3388CrossRef
36.
Ramesh S, Arof A (2001) Ionic conductivity studies of plasticized poly(vinyl chloride) polymer electrolytes. Mater Sci Eng B 85(1):11–15CrossRef
37.
Ramya CS, Selvasekarapandian S, Savitha T, Hirankumar G, Angelo PC (2007) Vibrational and impedance spectroscopic study on PVP–NH4SCN based polymer electrolytes. Phys B 393(1–2):11–17CrossRef
38.
Boukamp B (1986) A nonlinear least squares fit procedure for analysis of immittance data of electrochemical systems. Solid State Ion 20(1):31–44CrossRef
39.
Perumal P, Christopher Selvin P, Selvasekarapandian S (2018) Characterization of biopolymer pectin with lithium chloride and its applications to electrochemical devices. Ionics 24(1):3259–3270CrossRef
40.
Ponmani S, Prabhu MR (2018) Development and study of solid polymer electrolytes based on PVdF-HFP/PVAc: Mg (ClO4)2 for Mg ion batteries. J Mater Sci Mater Electron 29(17):15086–15096CrossRef
41.
Tiankhoon L, Ataollahi N, Hassan NH, Ahmad A (2016) Studies of porous solid polymeric electrolytes based on poly(vinylidene fluoride) and poly(methyl methacrylate) grafted natural rubber for applications in electrochemical devices. J Solid State Electrochem 20(1):203–213CrossRef
42.
Pandey GP, Agrawal RC, Hashmi SA (2011) Performance studies on composite gel polymer electrolytes for rechargeable magnesium battery application. J Phys Chem Solids 72(12):1408–1413CrossRef
43.
Wagner JB, Wagner CJ (1957) Electrical conductivity measurements on cuprous halides. J Chem Phys 26(6):1597–1601CrossRef
44.
Chandra S (1981) Superionic solids-principles and applications. Sole distributors for the U.S.A., Elsevier North-Holland, Amsterdam, New York (DLC) 81210776 :(OCoLC)7808989
45.
Evans J, Vincent CA, Bruce PG (1987) Electrochemical measurement of transference numbers in polymer electrolytes. J Polym 28(13):2324–2328CrossRef
46.
Manjuladevi R, Thamilselvan M, Selvasekarapandian S, Christopher Selvin P, Mangalam R, Monisha S (2017) Preparation and characterization of blend polymer electrolyte film based on poly(vinyl alcohol)-poly(acrylonitrile)/MgCl2 for energy storage devices. Ionics 24(4):1083–1095CrossRef
Metadata
Title
Preparation of primary magnesium battery based on kappa carrageenan with magnesium perchlorate and its application to electrochemical devices
Authors
P. Sangeetha
T. M. Selvakumari
S. Selvasekarapandian
M. Mahalakshmi
Publication date
10-01-2023
Publisher
Springer Berlin Heidelberg
Published in
Polymer Bulletin / Issue 12/2023
Print ISSN: 0170-0839
Electronic ISSN: 1436-2449
DOI
https://doi.org/10.1007/s00289-022-04669-2

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