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Published in: Journal of Materials Science 13/2024

19-03-2024 | Chemical routes to materials

Preparation of rGO @SA/CNF-doped copper composite aerogels and their solar-driven interfacial evaporation properties in water purification

Authors: Jiajia Gui, Yixiang Chen, Wei Wang, Dan Yu

Published in: Journal of Materials Science | Issue 13/2024

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Abstract

Solar-driven interfacial evaporation is a sustainable and green desalination method with great prospects for development in today’s severe water shortage problem. In this paper, a novel composite aerogel was prepared by hydrothermal method with sodium alginate (SA) and Cu2+ in the preparation process using reduced graphene oxide as photothermal material and cellulose nanofibers as substrate. The good hydrophilicity of nanocellulose makes the composite aerogel have strong capillary action and continuous water transport. The gel formed by ion exchange between SA and Cu2+ greatly improves dry and wet mechanical strength of the composite aerogel and ensures the stability of the evaporator for multiple recycling. Copper is doped by reduction of copper ion complexes and reduced graphene oxide have a synergistic effect to increase the photothermal response rate of the composite aerogel of 1.446 kg m−2 h−1 with evaporation efficiency of 84.87% under one standard solar irradiation. In addition, the purification of heavy metal ions, dye wastewater as well as acid and alkali solutions also has excellent results. It is expected that this study will provide some new ideas for the fields of seawater desalination and wastewater treatment.

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Literature
1.
go back to reference Al-Othman A, Tawalbeh M, El Haj Assad M, Alkayyali T, Eisa A (2018) Novel multi-stage flash (MSF) desalination plant driven by parabolic trough collectors and a solar pond: a simulation study in UAE. Desalination 443:237–244CrossRef Al-Othman A, Tawalbeh M, El Haj Assad M, Alkayyali T, Eisa A (2018) Novel multi-stage flash (MSF) desalination plant driven by parabolic trough collectors and a solar pond: a simulation study in UAE. Desalination 443:237–244CrossRef
2.
go back to reference Son HS, Shahzad MW, Ghaffour N, Ng KC (2020) Pilot studies on synergetic impacts of energy utilization in hybrid desalination system: multi-effect distillation and adsorption cycle (MED-AD). Desalination 477:114266CrossRef Son HS, Shahzad MW, Ghaffour N, Ng KC (2020) Pilot studies on synergetic impacts of energy utilization in hybrid desalination system: multi-effect distillation and adsorption cycle (MED-AD). Desalination 477:114266CrossRef
3.
go back to reference Yan J, Su Q, Xiao W, Wu Z, Chen L, Tang L, Zheng N, Gao J, Xue H (2022) A review of nanofiber membranes for solar interface evaporation. Desalination 531:115686CrossRef Yan J, Su Q, Xiao W, Wu Z, Chen L, Tang L, Zheng N, Gao J, Xue H (2022) A review of nanofiber membranes for solar interface evaporation. Desalination 531:115686CrossRef
4.
go back to reference Zhao L, Du C, Zhou C, Sun S, Jia Y, Yuan J, Song G, Zhou X, Zhao Q, Yang S (2020) Structurally ordered AgNPs@ C3N4/GO membranes toward solar-driven freshwater generation. ACS Sustain Chem Eng 8:4362CrossRef Zhao L, Du C, Zhou C, Sun S, Jia Y, Yuan J, Song G, Zhou X, Zhao Q, Yang S (2020) Structurally ordered AgNPs@ C3N4/GO membranes toward solar-driven freshwater generation. ACS Sustain Chem Eng 8:4362CrossRef
5.
go back to reference Bioinspired-and-dual-functional-nanocellulose-aerogels-for-water_2023_Nano-T.pdf Bioinspired-and-dual-functional-nanocellulose-aerogels-for-water_2023_Nano-T.pdf
6.
go back to reference Zhou X, Zhao F, Guo Y, Rosenberger B, Yu G (2019) Architecting highly hydratable polymer networks to tune the water state for solar water purification. Sci Adv 5:eaaw5484CrossRefPubMedPubMedCentral Zhou X, Zhao F, Guo Y, Rosenberger B, Yu G (2019) Architecting highly hydratable polymer networks to tune the water state for solar water purification. Sci Adv 5:eaaw5484CrossRefPubMedPubMedCentral
7.
go back to reference Xiao L, Chen X, Yang X, Sun J, Geng J (2020) Recent advances in polymer-based photothermal materials for biological applications. ACS Appl Polym Mater 2:4273CrossRef Xiao L, Chen X, Yang X, Sun J, Geng J (2020) Recent advances in polymer-based photothermal materials for biological applications. ACS Appl Polym Mater 2:4273CrossRef
8.
go back to reference Liu J, Liu Q, Ma D, Yuan Y, Yao J, Zhang W, Su H, Su Y, Gu J, Zhang D (2019) Simultaneously achieving thermal insulation and rapid water transport in sugarcane stems for efficient solar steam generation. J Mater Chem A 7:9034CrossRef Liu J, Liu Q, Ma D, Yuan Y, Yao J, Zhang W, Su H, Su Y, Gu J, Zhang D (2019) Simultaneously achieving thermal insulation and rapid water transport in sugarcane stems for efficient solar steam generation. J Mater Chem A 7:9034CrossRef
9.
go back to reference Min P, Liu J, Li X, An F, Liu P, Shen Y, Koratkar N, Yu Z-Z (2018) Thermally conductive phase change composites featuring anisotropic graphene aerogels for real-time and fast-charging solar-thermal energy conversion. Adv Funct Mater 28:1805365CrossRef Min P, Liu J, Li X, An F, Liu P, Shen Y, Koratkar N, Yu Z-Z (2018) Thermally conductive phase change composites featuring anisotropic graphene aerogels for real-time and fast-charging solar-thermal energy conversion. Adv Funct Mater 28:1805365CrossRef
10.
go back to reference Kuang Y, Chen C, Chen G, Pei Y, Pastel G, Jia C, Song J, Mi R, Yang B, Das S, Hu L (2019) Bioinspired solar-heated carbon absorbent for efficient cleanup of highly viscous crude oil. Adv Funct Mater 29:1900162CrossRef Kuang Y, Chen C, Chen G, Pei Y, Pastel G, Jia C, Song J, Mi R, Yang B, Das S, Hu L (2019) Bioinspired solar-heated carbon absorbent for efficient cleanup of highly viscous crude oil. Adv Funct Mater 29:1900162CrossRef
11.
go back to reference Xiong ZC, Zhu YJ, Wang ZY, Chen YQ, Yu HP (2021) Tree-inspired ultralong hydroxyapatite nanowires-based multifunctional aerogel with vertically aligned channels for continuous flow catalysis, water disinfection, and solar energy-driven water purification. Adv Funct Mater 32:2106978CrossRef Xiong ZC, Zhu YJ, Wang ZY, Chen YQ, Yu HP (2021) Tree-inspired ultralong hydroxyapatite nanowires-based multifunctional aerogel with vertically aligned channels for continuous flow catalysis, water disinfection, and solar energy-driven water purification. Adv Funct Mater 32:2106978CrossRef
12.
go back to reference Ji M, Liu H, Cheng M, Huang L, Yang G, Bao F, Huang G, Huang Y, Hu Y, Cong G, Yu J, Zhu C, Xu J (2022) Plasmonic metal nanoparticle loading to enhance the photothermal conversion of carbon fibers. J Phys Chem C 126:2454CrossRef Ji M, Liu H, Cheng M, Huang L, Yang G, Bao F, Huang G, Huang Y, Hu Y, Cong G, Yu J, Zhu C, Xu J (2022) Plasmonic metal nanoparticle loading to enhance the photothermal conversion of carbon fibers. J Phys Chem C 126:2454CrossRef
13.
go back to reference Ghim D, Jiang Q, Cao S, Singamaneni S, Jun Y-S (2018) Mechanically interlocked 1T/2H phases of MoS2 nanosheets for solar thermal water purification. Nano Energy 53:949CrossRef Ghim D, Jiang Q, Cao S, Singamaneni S, Jun Y-S (2018) Mechanically interlocked 1T/2H phases of MoS2 nanosheets for solar thermal water purification. Nano Energy 53:949CrossRef
14.
go back to reference Wu X, Robson ME, Phelps JL, Tan JS, Shao B, Owens G, Xu H (2018) A flexible photothermal cotton-CuS nanocage-agarose aerogel towards portable solar steam generation. Nano Energy 56:708CrossRef Wu X, Robson ME, Phelps JL, Tan JS, Shao B, Owens G, Xu H (2018) A flexible photothermal cotton-CuS nanocage-agarose aerogel towards portable solar steam generation. Nano Energy 56:708CrossRef
15.
go back to reference Maryam G, Nasir M, Mohammad K (2023) Facile fabrication of robust superhydrophobic polyurethane sponge modified with polydopamine- silica nanoparticle for effective oil/water separation. React Funct Polym 191:105657CrossRef Maryam G, Nasir M, Mohammad K (2023) Facile fabrication of robust superhydrophobic polyurethane sponge modified with polydopamine- silica nanoparticle for effective oil/water separation. React Funct Polym 191:105657CrossRef
16.
go back to reference Zhuoran Y, Wenting L, Chunyu Y, Liru C, Wei G (2023) A polydopamine modified floral foam three-dimensional water evaporator for desalination via a directional self-assembly technology. Mater Lett 349:134802CrossRef Zhuoran Y, Wenting L, Chunyu Y, Liru C, Wei G (2023) A polydopamine modified floral foam three-dimensional water evaporator for desalination via a directional self-assembly technology. Mater Lett 349:134802CrossRef
17.
go back to reference Zhang B, Wong PW, An AK (2021) Photothermally enabled MXene hydrogel membrane with integrated solar-driven evaporation and photodegradation for efficient water purification. Chem Eng J 430:133054CrossRef Zhang B, Wong PW, An AK (2021) Photothermally enabled MXene hydrogel membrane with integrated solar-driven evaporation and photodegradation for efficient water purification. Chem Eng J 430:133054CrossRef
18.
go back to reference Wu YG, Xue CH, Guo XJ, Huang MC, Wang HD, Ma CQ, Wang X, Shao ZY (2023) Highly efficient solar-driven water evaporation through a cotton fabric evaporator with wettability gradient. Chem Eng J 471:144313CrossRef Wu YG, Xue CH, Guo XJ, Huang MC, Wang HD, Ma CQ, Wang X, Shao ZY (2023) Highly efficient solar-driven water evaporation through a cotton fabric evaporator with wettability gradient. Chem Eng J 471:144313CrossRef
19.
go back to reference Yuan P, Men C, Zhao L, Cao P, Yang Z, Niu Y, Zhang Y, Yu Y, Li Q (2022) Spontaneous salt-preventing solar-thermal water evaporator with a high evaporation efficiency through dual-mode water transfer. ACS Appl Mater Interfaces 14:15549CrossRefPubMed Yuan P, Men C, Zhao L, Cao P, Yang Z, Niu Y, Zhang Y, Yu Y, Li Q (2022) Spontaneous salt-preventing solar-thermal water evaporator with a high evaporation efficiency through dual-mode water transfer. ACS Appl Mater Interfaces 14:15549CrossRefPubMed
20.
go back to reference Ziyu G, Zirui Y, Daoping X (2023) Efficient solar water evaporation enabled by Ti3O5/Ti4O7-based melamine-urea–formaldehyde aerogel evaporators. Chem Eng J 466:143055CrossRef Ziyu G, Zirui Y, Daoping X (2023) Efficient solar water evaporation enabled by Ti3O5/Ti4O7-based melamine-urea–formaldehyde aerogel evaporators. Chem Eng J 466:143055CrossRef
21.
go back to reference Fan D, Lu Y, Zhang H, Xu H, Lu C, Tang Y, Yang X (2021) Synergy of photocatalysis and photothermal effect in integrated 0D perovskite oxide/2D MXene heterostructures for simultaneous water purification and solar steam generation. Appl Catal B Environ 295:120285CrossRef Fan D, Lu Y, Zhang H, Xu H, Lu C, Tang Y, Yang X (2021) Synergy of photocatalysis and photothermal effect in integrated 0D perovskite oxide/2D MXene heterostructures for simultaneous water purification and solar steam generation. Appl Catal B Environ 295:120285CrossRef
22.
go back to reference Hu T, Chen K, Li L, Zhang J (2021) Carbon nanotubes@silicone solar evaporators with controllable salt-tolerance for efficient water evaporation in a closed system. J Mater Chem A 9:17502CrossRef Hu T, Chen K, Li L, Zhang J (2021) Carbon nanotubes@silicone solar evaporators with controllable salt-tolerance for efficient water evaporation in a closed system. J Mater Chem A 9:17502CrossRef
23.
go back to reference Manli Y, Ting C, Jinsheng S, Jinyong Z, Yu Z, Lili W (2021) Synergy of photothermal effect in integrated 0D natural melanin/2D reduced graphene oxide for effective solar steam generation and water purification. Colloids Surfaces A Physicochem Eng Aspects 632:127786 Manli Y, Ting C, Jinsheng S, Jinyong Z, Yu Z, Lili W (2021) Synergy of photothermal effect in integrated 0D natural melanin/2D reduced graphene oxide for effective solar steam generation and water purification. Colloids Surfaces A Physicochem Eng Aspects 632:127786
24.
go back to reference Huang J, He Y, Wang L, Huang Y, Jiang B (2017) Bifunctional Au@TiO2 core–shell nanoparticle films for clean water generation by photocatalysis and solar evaporation. Energy Convers Manag 132:452CrossRef Huang J, He Y, Wang L, Huang Y, Jiang B (2017) Bifunctional Au@TiO2 core–shell nanoparticle films for clean water generation by photocatalysis and solar evaporation. Energy Convers Manag 132:452CrossRef
25.
go back to reference Meng S, Tang CY, Jia J, Yang J, Yang MB, Yang W (2022) A wave-driven piezoelectric solar evaporator for water purification. Adv Energy Mater 12:2200087CrossRef Meng S, Tang CY, Jia J, Yang J, Yang MB, Yang W (2022) A wave-driven piezoelectric solar evaporator for water purification. Adv Energy Mater 12:2200087CrossRef
26.
go back to reference Sun Y, Zong X, Qu D, Chen G, An L, Wang X, Sun Z (2021) Water management by hierarchical structures for highly efficient solar water evaporation. J Mater Chem A 9(11):7122–7128CrossRef Sun Y, Zong X, Qu D, Chen G, An L, Wang X, Sun Z (2021) Water management by hierarchical structures for highly efficient solar water evaporation. J Mater Chem A 9(11):7122–7128CrossRef
27.
go back to reference Wang X, Gan Q, Chen R, Peng H, Zhang T, Ye M (2020) Water delivery channel design in solar evaporator for efficient and durable water evaporation with salt rejection. ACS Sustain Chem Eng 8(21):7753–7761CrossRef Wang X, Gan Q, Chen R, Peng H, Zhang T, Ye M (2020) Water delivery channel design in solar evaporator for efficient and durable water evaporation with salt rejection. ACS Sustain Chem Eng 8(21):7753–7761CrossRef
28.
go back to reference Wei Z, Wan Z, Cai C, Fu Y (2023) Cellulose-based evaporator with dual boost of water transportation and photothermal conversion for highly solar-driven evaporation. Int J Biol Macromol 242:125018CrossRefPubMed Wei Z, Wan Z, Cai C, Fu Y (2023) Cellulose-based evaporator with dual boost of water transportation and photothermal conversion for highly solar-driven evaporation. Int J Biol Macromol 242:125018CrossRefPubMed
29.
go back to reference Jin-Kun X, Jia-Zhi G, Meng D, Yun-Fei Z, Sheng-Gao W, Zhi-Dong L, Fei-Peng D, Ping F (2022) Reduced graphene oxide/Ag nanoparticle aerogel for efficient solar water evaporation. J Alloys Compd 930:167404 Jin-Kun X, Jia-Zhi G, Meng D, Yun-Fei Z, Sheng-Gao W, Zhi-Dong L, Fei-Peng D, Ping F (2022) Reduced graphene oxide/Ag nanoparticle aerogel for efficient solar water evaporation. J Alloys Compd 930:167404
30.
go back to reference Tu C, Cai W, Chen X, Ouyang X, Zhang H, Zhang Z (2019) A 3D-structured sustainable solar-driven steam generator using super-black nylon flocking materials. Small 15:1902070CrossRef Tu C, Cai W, Chen X, Ouyang X, Zhang H, Zhang Z (2019) A 3D-structured sustainable solar-driven steam generator using super-black nylon flocking materials. Small 15:1902070CrossRef
31.
go back to reference Zhu M, Liu X, Tian Y, Caratenuto A, Chen F, Zheng Y (2022) Dome-arrayed chitosan/PVA hydrogel-based solar evaporator for steam generation. Sci Rep 12(1):4403CrossRefPubMedPubMedCentral Zhu M, Liu X, Tian Y, Caratenuto A, Chen F, Zheng Y (2022) Dome-arrayed chitosan/PVA hydrogel-based solar evaporator for steam generation. Sci Rep 12(1):4403CrossRefPubMedPubMedCentral
32.
go back to reference Li W, Feng W, Wu S, Wang W, Yu D (2022) Synergy of photothermal effect in integrated 0D Ti2O3 nanoparticles/1D carboxylated carbon nanotubes for multifunctional water purification. Sep Purif Technol 292:120989CrossRef Li W, Feng W, Wu S, Wang W, Yu D (2022) Synergy of photothermal effect in integrated 0D Ti2O3 nanoparticles/1D carboxylated carbon nanotubes for multifunctional water purification. Sep Purif Technol 292:120989CrossRef
33.
go back to reference Jhang J-W, Chou Y-H, Wang T-H, Hsieh M-H, Chiang W-H (2022) One-pot green reduction and surface decoration of graphene oxide nanosheets with PEGylated chitosan for application in cancer photothermal therapy. J Taiwan Inst Chem Eng 134:104359CrossRef Jhang J-W, Chou Y-H, Wang T-H, Hsieh M-H, Chiang W-H (2022) One-pot green reduction and surface decoration of graphene oxide nanosheets with PEGylated chitosan for application in cancer photothermal therapy. J Taiwan Inst Chem Eng 134:104359CrossRef
34.
go back to reference Chen J, Li H, Zhang L, Du C, Fang T, Hu J (2020) Direct reduction of graphene oxide/nanofibrillated cellulose composite film and its electrical conductivity research. Sci Rep 10(1):3124CrossRefPubMedPubMedCentral Chen J, Li H, Zhang L, Du C, Fang T, Hu J (2020) Direct reduction of graphene oxide/nanofibrillated cellulose composite film and its electrical conductivity research. Sci Rep 10(1):3124CrossRefPubMedPubMedCentral
35.
go back to reference Li Z, Wang M, Chen L, Ji H, Yu H-Y (2023) Highly efficient carbonization of nanocellulose to biocarbon aerogels with ultrahigh light absorption efficiency and evaporation rate as bifunctional solar/electric driven steam generator for water purification. Sustain Mater Technol 36:e00649 Li Z, Wang M, Chen L, Ji H, Yu H-Y (2023) Highly efficient carbonization of nanocellulose to biocarbon aerogels with ultrahigh light absorption efficiency and evaporation rate as bifunctional solar/electric driven steam generator for water purification. Sustain Mater Technol 36:e00649
36.
go back to reference Yang J, Han X, Yang W, Hu J, Zhang C, Liu K, Jiang S (2023) Nanocellulose-based composite aerogels toward the environmental protection: Preparation, modification and applications. Environ Res 236:116736CrossRefPubMed Yang J, Han X, Yang W, Hu J, Zhang C, Liu K, Jiang S (2023) Nanocellulose-based composite aerogels toward the environmental protection: Preparation, modification and applications. Environ Res 236:116736CrossRefPubMed
37.
go back to reference Gong C, Ni J-P, Tian C, Su Z-H (2021) Research in porous structure of cellulose aerogel made from cellulose nanofibrils. Int J Biol Macromol 172:573CrossRefPubMed Gong C, Ni J-P, Tian C, Su Z-H (2021) Research in porous structure of cellulose aerogel made from cellulose nanofibrils. Int J Biol Macromol 172:573CrossRefPubMed
38.
go back to reference Nguyen BN, Cudjoe E, Douglas A, Scheiman D, McCorkle L, Meador MAB, Rowan SJ (2016) Polyimide cellulose nanocrystal composite aerogels. Macromolecules 49(5):1692CrossRef Nguyen BN, Cudjoe E, Douglas A, Scheiman D, McCorkle L, Meador MAB, Rowan SJ (2016) Polyimide cellulose nanocrystal composite aerogels. Macromolecules 49(5):1692CrossRef
39.
go back to reference Li J, Jing Y, Xing G, Liu M, Cui Y, Sun H, Zhu Z, Liang W, Li A (2022) Solar-driven interfacial evaporation for water treatment: advanced research progress and challenges. J Mater Chem A 10:18470CrossRef Li J, Jing Y, Xing G, Liu M, Cui Y, Sun H, Zhu Z, Liang W, Li A (2022) Solar-driven interfacial evaporation for water treatment: advanced research progress and challenges. J Mater Chem A 10:18470CrossRef
Metadata
Title
Preparation of rGO @SA/CNF-doped copper composite aerogels and their solar-driven interfacial evaporation properties in water purification
Authors
Jiajia Gui
Yixiang Chen
Wei Wang
Dan Yu
Publication date
19-03-2024
Publisher
Springer US
Published in
Journal of Materials Science / Issue 13/2024
Print ISSN: 0022-2461
Electronic ISSN: 1573-4803
DOI
https://doi.org/10.1007/s10853-024-09484-w

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