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Published in: Colloid and Polymer Science 6/2004

01-04-2004 | Original Contribution

Production of poly(methyl methacrylate) particles by dispersion polymerization with mercaptopropyl terminated poly(dimethylsiloxane) stabilizer in supercritical carbon dioxide

Authors: Syuji Fujii, Hideto Minami, Masayoshi Okubo

Published in: Colloid and Polymer Science | Issue 6/2004

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Abstract.

Poly(methyl methacrylate) (PMMA) particles were produced by dispersion polymerization of methyl methacrylate in the presence of mercaptopropyl terminated poly(dimethylsiloxane) (MP-PDMS) in supercritical carbon dioxide at about 30 MPa for 24 h at 65 °C. The particle diameter could be controlled in a size range of submicron to micron by varying MP-PDMS concentration. The MP-PDMS worked as not only a chain transfer agent but also a colloidal stabilizer, which was named “tran stab.”

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Metadata
Title
Production of poly(methyl methacrylate) particles by dispersion polymerization with mercaptopropyl terminated poly(dimethylsiloxane) stabilizer in supercritical carbon dioxide
Authors
Syuji Fujii
Hideto Minami
Masayoshi Okubo
Publication date
01-04-2004
Publisher
Springer-Verlag
Published in
Colloid and Polymer Science / Issue 6/2004
Print ISSN: 0303-402X
Electronic ISSN: 1435-1536
DOI
https://doi.org/10.1007/s00396-003-0977-z

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