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Published in: European Journal of Wood and Wood Products 4/2021

16-02-2021 | Brief Original

Purification of tall oil fatty acids by removing of stilbenes

Authors: Andrey N. Evdokimov, Alexander V. Kurzin, Larisa M. Popova, Victorija B. Franchuk

Published in: European Journal of Wood and Wood Products | Issue 4/2021

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Abstract

The composition of tall oil fatty acids includes rosin acids and unsaponifiable substances as impurities. The latter include stilbenes. The total content of stilbenes in tall oil and fatty acids can reach 1%. The presence of stilbenes contributes to the deterioration of fatty acids color during storage and production of some derivatives. The existing methods for removing stilbenes are based on the treatment of sorbents, formaldehyde and boron trifluoride etherate. The phosphorus pentoxide treatment has a purifying effect, which allowed reducing the pinosylvin ethers content to 0.05%.

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Literature
go back to reference Berbalk H, Pieh G, Eichinger K (1975) Untersuchungen über die Zusammensetzung der unverseifbaren Bestandteile in Fettsäuredestillaten aus Tallöl (Studies on the composition of unsaponifiable, non acidic constituents in fatty acid distillates from tall oil). Monatsh Chem 106(4):833–837. https://doi.org/10.1007/BF00900861 (in German)CrossRef Berbalk H, Pieh G, Eichinger K (1975) Untersuchungen über die Zusammensetzung der unverseifbaren Bestandteile in Fettsäuredestillaten aus Tallöl (Studies on the composition of unsaponifiable, non acidic constituents in fatty acid distillates from tall oil). Monatsh Chem 106(4):833–837. https://​doi.​org/​10.​1007/​BF00900861 (in German)CrossRef
go back to reference Doyle WC Jr (1969) Treatment of tall oil fatty acids. Patent US3433815 A Doyle WC Jr (1969) Treatment of tall oil fatty acids. Patent US3433815 A
go back to reference Mokkila K (2019) Method of recovering pinosylvin and other related compounds from crude tall oil. Patent CA2720889 C Mokkila K (2019) Method of recovering pinosylvin and other related compounds from crude tall oil. Patent CA2720889 C
go back to reference Wicke AF Jr, McLaughin HE, Stump JH Jr (1966) Process for removing stilbene from tall oil fatty acids. Patent US3257438 A Wicke AF Jr, McLaughin HE, Stump JH Jr (1966) Process for removing stilbene from tall oil fatty acids. Patent US3257438 A
Metadata
Title
Purification of tall oil fatty acids by removing of stilbenes
Authors
Andrey N. Evdokimov
Alexander V. Kurzin
Larisa M. Popova
Victorija B. Franchuk
Publication date
16-02-2021
Publisher
Springer Berlin Heidelberg
Published in
European Journal of Wood and Wood Products / Issue 4/2021
Print ISSN: 0018-3768
Electronic ISSN: 1436-736X
DOI
https://doi.org/10.1007/s00107-021-01663-9

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