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20-11-2023 | Original Article

Regulating interfacial stability of SiO_x anode with fluoride-abundant solid–electrolyte interphase by fluorine-functionalized additive

Authors: Subin Lee, Taeeun Yim

Published in: Rare Metals | Issue 2/2024

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Abstract

Silicon oxide (SiO_x) has received remarkable attention as a next-generation battery material; however, the sudden decrease in the cycling retention constitutes a significant challenge in facilitating its application. Tris(2,2,2-trifluoroethyl) phosphite (TTFP), which can control parasitic reactions such as the pulverization of SiO_x anode materials and electrolyte decomposition, has been proposed to improve the lifespan of the cell. The electrochemical reduction of TTFP results in solid-electrolyte interphase (SEI) layers that are mainly composed of LiF, which occur at a higher potential than the working potential of the SiO_x anode and carbonate-based solvents. The electrolyte with TTFP exhibited a substantial improvement in cycling retention after 100 cycles, whereas the standard electrolyte showed acutely decreased retention. The thickness of the SiO_x anode with TTFP also changed only slightly without any considerable delamination spots, whereas the SiO_x anode without TTFP was prominently deformed by an enormous volume expansion with several internal cracks. The cycled SiO_x anode with TTFP exhibited less increase in resistance after cycling than that in the absence of TTFP, in addition to fewer decomposition adducts in corresponding X-ray photoelectron spectroscopy (XPS) analyses between the cycled SiO_x anodes. These results demonstrate that TTFP formed SEI layers at the SiO_x interface, which substantially reduced the pulverization of the SiO_x anode materials; in addition, electrolyte decomposition at the interface decreased, which led to improved cycling retention.

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Title: Regulating interfacial stability of SiOx anode with fluoride-abundant solid–electrolyte interphase by fluorine-functionalized additive
Authors: Subin Lee
Taeeun Yim
Publication date: 20-11-2023
Publisher: Nonferrous Metals Society of China
Published in: Rare Metals / Issue 2/2024
Print ISSN: 1001-0521
Electronic ISSN: 1867-7185
DOI: https://doi.org/10.1007/s12598-023-02474-y

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