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Glass and Ceramics

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01-07-2013

Relation between the phase composition and durability of ceramic brick older than 600 yr at the Ipat’evskii monastery

Author: V. Z. Abdrakhimov

Published in: Glass and Ceramics | Issue 3-4/2013

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Abstract

Research has shown that the brick in the Ipat’evskii monastery was made using clay with high content of quartz SiO₂ = 65 – 72%, calcium oxide CaO = 10 – 15% and Fe₂O₃ = 8 – 12%. Owing to the crystallization of mullite in the samples studied the bricks have high durability. Wollastonite, which was formed due to the elevated CaO content in the clay, creates a dense framework that impedes any change in the previous volume, i.e., it noticeably decreases stress and shrinkage in the ceramic samples.

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Here and below, content by weight, %, unless otherwise stipulated.

V. Z. Abdrakhimov, “Effect of the phase composition on the durability of ceramic facing of the Samarkand Shakhi-Zinda ensemble,” Steklo Keram., No. 3, 38–40 (2012); V. Z. Abdrakhimov, “Effect of the phase composition on the durability of ceramic facing of the Shakhi-Zinda ensemble in Samarkand,” Glass Ceram., 69(3–4), 104–106 (2012).

E. S. Abdrakhimova, V. Z. Abdrakhimov, and I. V. Kovkov, “X-ray Phase and electron-microscope study of the phase composition of brick from the Nizhny Novgorod kremlin,” Materialovedenie, No. 4, 49–54 (2008).

E. S. Abdrakhimova and V. Z. Abdrakhimov, “Transformation of iron oxides during firing of beidellite clay,” Zh. Neorg. Khim., 54(1), 42–46 (2009).

E. S. Abdrakhimova and V. Z. Abdrakhimov, “Structural transformations of iron compounds in clayey materials according to Mössbauer spectroscopy data,” Zh. Fiz. Khim., 80(7), 1227–1232 (2006).

E. S. Abdrakhimova and V. Z. Abdrakhimov, “Synthesis of mullite from technogenic raw material and pyrophyllite,” Zh. Neorg. Khim., 52(3), 395–400 (2007).

E. S. Abdrakhimova and V. Z. Abdrakhimov, “On the question of mullite,” Ogneup. Tekh. Keram., No. 3, 40–46 (2006).

E. S. Abdrakhimova and V. Z. Abdrakhimov, “Formation of mullite during firing of acid-resisting materials,” Materialovedenie, No. 4, 26–31 (2003).

Title: Relation between the phase composition and durability of ceramic brick older than 600 yr at the Ipat’evskii monastery
Author: V. Z. Abdrakhimov
Publication date: 01-07-2013
Publisher: Springer US
Published in: Glass and Ceramics / Issue 3-4/2013
Print ISSN: 0361-7610
Electronic ISSN: 1573-8515
DOI: https://doi.org/10.1007/s10717-013-9518-5

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