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Polymer Bulletin
Published in: Polymer Bulletin 4/2017

04-08-2016 | Original Paper

Reversible capture and release of carbon dioxide by binary system of polyamidine and polyethylene glycol

Authors: Yoshio Furusho, Takeshi Endo

Published in: Polymer Bulletin | Issue 4/2017

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Abstract

CO2 absorbents were prepared from polyethylene glycol and the polyamidines having N,N′-disubstituted amidine structure in the main chain synthesized through acid-catalyzed melt polycondensation of orthoesters and α,ω-diamines. The homogeneous binary mixtures with the polyamidines captured CO2 much more efficiently under CO2 flow than the one with polyethyleneimine. Furthermore, we investigated the CO2 capture and release by the binary mixtures in terms of effects of the volatility and the structure of polyamidines, temperature, and polyethylene glycol. Taking into consideration the results thus obtained, we conducted CO2 capture/release cycles with the CO2 capture step at 40 °C and with the CO2 releasing step at 80 °C in an alternating manner, thereby demonstrating the repeatability of CO2 capture and release by the binary system of the polyamidine and polyethylene glycol.
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Appendix
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Metadata
Title
Reversible capture and release of carbon dioxide by binary system of polyamidine and polyethylene glycol
Authors
Yoshio Furusho
Takeshi Endo
Publication date
04-08-2016
Publisher
Springer Berlin Heidelberg
Published in
Polymer Bulletin / Issue 4/2017
Print ISSN: 0170-0839
Electronic ISSN: 1436-2449
DOI
https://doi.org/10.1007/s00289-016-1772-6

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