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Journal of Coatings Technology and Research

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08-07-2021

Reversible thermochromic performance of cresol red-boric acid system loaded on fibrous mesoporous silica microspheres coating material

Authors: Tingting Yu, Liang Cheng, Haocheng Cai, Geng Li, Xu Wang, Linghan Kong, Jianbo Zhan, Hao Wang, Ying Zhang, Zhenhua Yu, Han Zheng

Published in: Journal of Coatings Technology and Research | Issue 5/2021

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Abstract

In this study, the fibrous mesoporous silica F-SiO₂ was functionalized with 3-aminopropyltriethoxysilane (APTES). The reversible thermochromic composites of fibrous mesoporous silica (F-SiO₂) and amino group-modified fibrous mesoporous silica (F-SiO₂-NH₂) microspheres loaded with cresol red-boric acid (CR-BA) were termed as S2 (F-SiO₂/CR-BA) and SN2 (F-SiO2-NH₂/CR-BA), respectively. The materials obtained were characterized by infrared spectroscopy, transmission electron microscopy, scanning and transmission electron microscopy, differential scanning calorimetry, and thermogravimetric analysis. The fibrous morphology of this rigid carrier was maintained after loading with the CR-BA composite system. Owing to the APTES modification, the F-SiO₂-NH₂/CR-BA composites underwent more severe color changes than the F-SiO₂/CR-BA composites. In addition, the F-SiO₂-NH₂/CR-BA composites can recover the original color in only 210 s, illustrating excellent reversibility.

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Title: Reversible thermochromic performance of cresol red-boric acid system loaded on fibrous mesoporous silica microspheres coating material
Authors: Tingting Yu
Liang Cheng
Haocheng Cai
Geng Li
Xu Wang
Linghan Kong
Jianbo Zhan
Hao Wang
Ying Zhang
Zhenhua Yu
Han Zheng
Publication date: 08-07-2021
Publisher: Springer US
Published in: Journal of Coatings Technology and Research / Issue 5/2021
Print ISSN: 1547-0091
Electronic ISSN: 1935-3804
DOI: https://doi.org/10.1007/s11998-021-00504-x

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