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2016 | OriginalPaper | Chapter

Ring Expansions of Azirines and Azetines

Authors : Alexander F. Khlebnikov, Mikhail S. Novikov

Published in: Synthesis of 4- to 7-membered Heterocycles by Ring Expansion

Publisher: Springer International Publishing

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Abstract

The syntheses of various heterocycles based on the ring expansion of azirines and azetines are described. A structural diversity of heterocycles can be prepared starting from these strained compounds due to their extremal reactivity involving nucleophilic, electrophilic, and metal-catalyzed additions, cycloadditions of different types, and thermal and catalytic isomerizations. Although the chemistry of azetines is not so diverse, some specific heterocyclic compounds can be synthesized only from azetines. The present survey covers research published up to early beginning of 2015.

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Metadata
Title
Ring Expansions of Azirines and Azetines
Authors
Alexander F. Khlebnikov
Mikhail S. Novikov
Copyright Year
2016
DOI
https://doi.org/10.1007/7081_2015_154