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Published in: Journal of Materials Engineering and Performance 7/2012

01-07-2012

Role of RE Element Nd on Boronizing Kinetics of Steels

Authors: Z. G. Su, X. X. Lv, J. An, Y. L. Yang, S. J. Sun

Published in: Journal of Materials Engineering and Performance | Issue 7/2012

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Abstract

Boronizing of AISI 1045 and ASTM W1-111/2 steels was carried out by pack boriding using Nd2O3-containing agent in the temperature range of 1053 to 1213 K. The effect of RE element Nd on boronizing kinetics was analyzed in terms of possible chemical reactions in boriding agent, surface elemental distribution and morphology evolution of the steels boronized at different temperatures. The results showed that the RE element Nd has two opposite effects on boronizing process, i.e., promoting effect at high temperatures and hindering effect at low temperatures. Boronizing using Nd2O3-containing agent can remarkably reduce the diffusion activation energy at higher temperatures. Empirical equations relating the boride layer thickness with processing time and temperature are established. Based on these equations, the contour diagrams of boride layer thickness for the studied steels boronized with addition of 5% Nd2O3 are presented.

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Literature
1.
go back to reference B. Selcuk, R. Lpek, and M.B. Karamis, A Study of Friction and Wear Behaviour of Carburized, Carbonnitrided and Borided AISI, 1020 and 5115 Steels, J. Mater. Process. Technol., 1020, 2003(141), p 189–196 B. Selcuk, R. Lpek, and M.B. Karamis, A Study of Friction and Wear Behaviour of Carburized, Carbonnitrided and Borided AISI, 1020 and 5115 Steels, J. Mater. Process. Technol., 1020, 2003(141), p 189–196
2.
go back to reference S. Sen, I. Ozbek, U. Sen, and C. Bindal, Mechanical Behavior of Borides Formed on Borided Cold Work Tool Steel, Surf. Coat. Technol., 2001, 135, p 173–177CrossRef S. Sen, I. Ozbek, U. Sen, and C. Bindal, Mechanical Behavior of Borides Formed on Borided Cold Work Tool Steel, Surf. Coat. Technol., 2001, 135, p 173–177CrossRef
3.
go back to reference O. Ozdemir, M.A. Omar, M. Usta, S. Zeytin, C. Bindal, and A.H. Ucisik, An Investigation on Boriding Kinetics of AISI, 316 Stainless Steel, Vacuum, 2009, 83, p 175–179CrossRef O. Ozdemir, M.A. Omar, M. Usta, S. Zeytin, C. Bindal, and A.H. Ucisik, An Investigation on Boriding Kinetics of AISI, 316 Stainless Steel, Vacuum, 2009, 83, p 175–179CrossRef
4.
go back to reference S. Sen, U. Sen, and C. Bindal, An Approach to Kinetics Study of Borided Steels, Surf. Coat. Technol., 2005, 191, p 274–285CrossRef S. Sen, U. Sen, and C. Bindal, An Approach to Kinetics Study of Borided Steels, Surf. Coat. Technol., 2005, 191, p 274–285CrossRef
5.
go back to reference C.M. Li, B.L. Shen, G.J. Li, and C. Yang, Effect of Boronized Temperature and Time on Microstructure and Abrasion Wear Resistance of Cr12Mn2V2 High Chromium Cast Iron, Surf. Coat. Technol., 2008, 202, p 5882–5886CrossRef C.M. Li, B.L. Shen, G.J. Li, and C. Yang, Effect of Boronized Temperature and Time on Microstructure and Abrasion Wear Resistance of Cr12Mn2V2 High Chromium Cast Iron, Surf. Coat. Technol., 2008, 202, p 5882–5886CrossRef
6.
go back to reference L.G. Yu, X.J. Chen, K.A. Khor, and G. Sundararajan, Fe/Fe2B Phase Transformation During SPS Pack-boriding: Boride Layer Growth Kinetics, Acta Mater., 2005, 53, p 2361–2368CrossRef L.G. Yu, X.J. Chen, K.A. Khor, and G. Sundararajan, Fe/Fe2B Phase Transformation During SPS Pack-boriding: Boride Layer Growth Kinetics, Acta Mater., 2005, 53, p 2361–2368CrossRef
7.
8.
go back to reference F.S. Chen and K.L. Wang, The Kinetics and Mechanism of Multi-component Diffusion on AISI, 1045 Steel, Surf. Coat. Technol., 1045, 1999(115), p 239–248 F.S. Chen and K.L. Wang, The Kinetics and Mechanism of Multi-component Diffusion on AISI, 1045 Steel, Surf. Coat. Technol., 1045, 1999(115), p 239–248
9.
go back to reference X.M. Gao, M. Wen, W.X. Han, R. Wang, and Y. Long, Effect of Rare Earth Elements on Improving Boronizing Layer, J. Chin. Rare Earth Soc., 1997, 15(4), p 350–353 X.M. Gao, M. Wen, W.X. Han, R. Wang, and Y. Long, Effect of Rare Earth Elements on Improving Boronizing Layer, J. Chin. Rare Earth Soc., 1997, 15(4), p 350–353
10.
go back to reference X.K. Tao, G.X. Dong, R.S. Peng, and Y.C. Sun, Study on Co-permeation of Solid Rare-earth Element, Boron and Vanadium, J. Chin. Rare Earth Soc., 2001, 19(2), p 178–181 X.K. Tao, G.X. Dong, R.S. Peng, and Y.C. Sun, Study on Co-permeation of Solid Rare-earth Element, Boron and Vanadium, J. Chin. Rare Earth Soc., 2001, 19(2), p 178–181
11.
go back to reference B. Xu, C.M. Feng, and Y.P. Song, Study on Pack RE-chrome-boronizing, Trans. Met. Heat Treat., 2000, 21(1), p 61–64 B. Xu, C.M. Feng, and Y.P. Song, Study on Pack RE-chrome-boronizing, Trans. Met. Heat Treat., 2000, 21(1), p 61–64
12.
go back to reference J.Z. Zhang, Z.L. Yang, and K.Y. Wei, Study of the Catalysis and Diffusion Mechanism by Rare Earth (RE) Elements During the Thermo-chemical Treatment, Mater. Rev., 2006, 20, p p223–p225 J.Z. Zhang, Z.L. Yang, and K.Y. Wei, Study of the Catalysis and Diffusion Mechanism by Rare Earth (RE) Elements During the Thermo-chemical Treatment, Mater. Rev., 2006, 20, p p223–p225
13.
go back to reference F. Xie, B.T. Ma, and J.W. He, The Effects of Rare Earth in Steels on the Thermochemical Treatments and the Functional Mechanisms of the Rare Earths, Rare Met. Mater. Eng., 1997, 26, p p52–p57 F. Xie, B.T. Ma, and J.W. He, The Effects of Rare Earth in Steels on the Thermochemical Treatments and the Functional Mechanisms of the Rare Earths, Rare Met. Mater. Eng., 1997, 26, p p52–p57
14.
go back to reference I. Ozbek and C. Bindal, Mechanical Properties of Boronized AISI, W4 Steel, Surf. Coat. Technol., 2002, 154, p p14–p20CrossRef I. Ozbek and C. Bindal, Mechanical Properties of Boronized AISI, W4 Steel, Surf. Coat. Technol., 2002, 154, p p14–p20CrossRef
15.
go back to reference I. Uslu, H. Comert, M. Ipek, O. Ozdemir, and C. Bindal, Evaluation of Borides Formed on AISI, P20 Steel, Mater. Des., 2007, 28, p p55–p56CrossRef I. Uslu, H. Comert, M. Ipek, O. Ozdemir, and C. Bindal, Evaluation of Borides Formed on AISI, P20 Steel, Mater. Des., 2007, 28, p p55–p56CrossRef
16.
go back to reference V. Jain and G. Sundararajan, Influence of the Pack Thickness of the Boronizing Mixture on the Boriding of Steel, Surf. Coat. Technol., 2002, 149, p p21–p26CrossRef V. Jain and G. Sundararajan, Influence of the Pack Thickness of the Boronizing Mixture on the Boriding of Steel, Surf. Coat. Technol., 2002, 149, p p21–p26CrossRef
17.
go back to reference M.F. Yan, Z.R. Liu, and F.Y. Zhu, Progress in Rare Earth Thermochemical Treatment, Heat Treat. Met., 2003, 28(3), p 1–6 M.F. Yan, Z.R. Liu, and F.Y. Zhu, Progress in Rare Earth Thermochemical Treatment, Heat Treat. Met., 2003, 28(3), p 1–6
18.
go back to reference S. Sen, U. Sen, and C. Bindal, The Growth Kinetics of Borides Formed on Boronized AISI, 4140 steel, Vacuum, 2005, 77, p p195–p202CrossRef S. Sen, U. Sen, and C. Bindal, The Growth Kinetics of Borides Formed on Boronized AISI, 4140 steel, Vacuum, 2005, 77, p p195–p202CrossRef
19.
go back to reference K. Genel, I. Ozebek, and C. Bindal, Kinetics of Boriding of AISI, W1 steel, Mater. Sci. Eng. A, 2003, 347, p 311–314CrossRef K. Genel, I. Ozebek, and C. Bindal, Kinetics of Boriding of AISI, W1 steel, Mater. Sci. Eng. A, 2003, 347, p 311–314CrossRef
20.
go back to reference I. Campos, G. Ramı′rez, U. Figueroa, J. Martınez, and O. Morales, Evaluation of Boron Mobility on the Phase FeB, Fe2B and Diffusion Zone in AISI, 1045 and M2 Steels, Appl. Surf. Sci., 2007, 253, p 3469–3475CrossRef I. Campos, G. Ramı′rez, U. Figueroa, J. Martınez, and O. Morales, Evaluation of Boron Mobility on the Phase FeB, Fe2B and Diffusion Zone in AISI, 1045 and M2 Steels, Appl. Surf. Sci., 2007, 253, p 3469–3475CrossRef
21.
go back to reference A.K. Sinha, Boriding (Boronizing) ASM Handbook, OH, USA, J. Heat Treat., 1991, 4, p 437–447 A.K. Sinha, Boriding (Boronizing) ASM Handbook, OH, USA, J. Heat Treat., 1991, 4, p 437–447
22.
go back to reference I. Barin, Thermochemical Data of Pure Substance, 3rd ed., Wiley-VCH Verlag Gmbh, New York, 1995CrossRef I. Barin, Thermochemical Data of Pure Substance, 3rd ed., Wiley-VCH Verlag Gmbh, New York, 1995CrossRef
Metadata
Title
Role of RE Element Nd on Boronizing Kinetics of Steels
Authors
Z. G. Su
X. X. Lv
J. An
Y. L. Yang
S. J. Sun
Publication date
01-07-2012
Publisher
Springer US
Published in
Journal of Materials Engineering and Performance / Issue 7/2012
Print ISSN: 1059-9495
Electronic ISSN: 1544-1024
DOI
https://doi.org/10.1007/s11665-011-0053-7

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