Top

Published in:

2022 | OriginalPaper | Chapter

9. Science and Technology Roadmap for Adsorption of Metallic Contaminants from Aqueous Effluents Using Biopolymers and Its’ Derivatives

Authors : Ahmed Elsayid Ali, Zaira Zaman Chowdhury, Rahman F. Rafique, Rabia Ikram, Abu Nasser Mohammad Faisal, ShahJalal Shibly, Arnab Barua, Yasmin Abdul Wahab, Badrul Mohamed Jan

Published in: Advanced Industrial Wastewater Treatment and Reclamation of Water

Publisher: Springer International Publishing

Activate our intelligent search to find suitable subject content or patents.

search-config

AI-assisted search

Off

Abstract

Large amount of heavy metal pollutants are discharging by industries which are hazardous for environment. Several metallic pollutants like copper (II), nickel (II), lead (II), cadmium (II), and zinc (II) introduced in water can cause serious threat to aquatic environment. Biopolymers are promising candidate for elimination of heavy metals from waste stream. In this chapter, biopolymers based on polysaccharides can be classified into four sub-categories: homopolymers, blends of polysaccharide, copolymers, and functionalized polysaccharide or their composites. Natural biopolymers like alginate,chitosan, cellulose, chitin, and starch contain numerous surface active groups which can act as binding agent to eliminate heavy metals from water. Introduction of secondary functional groups with biopolymers enhances its’ mechanical strength which is essential for recyclability of the adsorbent to ensure economical application of biopolymers for industrial scale waste water treatment plant. This chapter provides the in-depth mechanism of heavy metal interactions with the bio-polymeric surface using π-π, dipole–dipole reaction. Furthermore, it can go for hydrogen network, or weak Van-der-walls attraction with the co-polymers, homo-polymer, blending of polymers, as well as biopolymer/composite matrix containing negative ions or electron-enriched groups. The concluding part of the chapter illustrates the adsorptive behavior of cations using kinetics and isotherms analysis of the equilibrium system for waste water treatment.

Dont have a licence yet? Then find out more about our products and how to get one now:

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

über 102.000 Bücher
über 537 Zeitschriften

aus folgenden Fachgebieten:

Automobil + Motoren
Bauwesen + Immobilien
Business IT + Informatik
Elektrotechnik + Elektronik
Energie + Nachhaltigkeit
Finance + Banking
Management + Führung
Marketing + Vertrieb
Maschinenbau + Werkstoffe
Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

inform now

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

über 67.000 Bücher
über 390 Zeitschriften

aus folgenden Fachgebieten:

Automobil + Motoren
Bauwesen + Immobilien
Business IT + Informatik
Elektrotechnik + Elektronik
Energie + Nachhaltigkeit
Maschinenbau + Werkstoffe

Jetzt Wissensvorsprung sichern!

inform now

previous chapter Ballast Water System Treatment Techniques in Marine Transportation Industry: A Case Study of M/V LOCH MELFORT

next chapter Impact of Industrial Wastewater on Environment and Human Health

Abdel-Halim E, Al-Deyab SS (2014) Preparation of poly(acrylic acid)/starch hydrogel and its application for cadmium ion removal from aqueous solutions. React Funct Polym 75:1–8. https://doi.org/10.1016/j.reactfunctpolym.2013.12.003CrossRef

Abussaud B, Asmaly HA, Ihsanullah Saleh TA, Gupta VK, Laoui T, Atieh MA (2016) Sorption of phenol from waters on activated carbon impregnated with iron oxide, aluminum oxide and titanium oxide. J Mol Liq 213. https://doi.org/10.1016/j.molliq.2015.08.044

Ahlers F, Thom I, Lambert J, Kuckuk R, Wiermann R (1999) 1H NMR analysis of sporopollenin from Typha Angustifolia. Phytochemistry 50(6):1095–1098. https://doi.org/10.1016/s0031-9422(98)00225-8CrossRef

Ahsan T, Tabassum M, Rahman J, Nur M, Siddique EA (2019) Environmental analysis of arsenic in water, soil and food materials from highly contaminated area of Alampur Village, Amjhupi Union, Meherpur. Adv J Chem Sect A 3(2). https://doi.org/10.33945/sami/ajca.2020.2.7

Alomá I, Martín-Lara M, Rodríguez I, Blázquez G, Calero M (2012) Removal of nickel (II) ions from aqueous solutions by biosorption on sugarcane bagasse. J Taiwan Inst Chem Eng 43(2):275–281. https://doi.org/10.1016/j.jtice.2011.10.011CrossRef

Alvarez PJJ, Chan CK, Elimelech M, Halas NJ, Villagrán D (2018) Emerging opportunities for nanotechnology to enhance water security. Nat Nanotechnol 13(8):634–641. https://doi.org/10.1038/s41565-018-0203-2CrossRefPubMedADS

Azzam EM, Eshaq G, Rabie A, Bakr A, Abd-Elaal AA, El Metwally A, Tawfik SM (2016) Preparation and characterization of chitosan-clay nanocomposites for the removal of Cu(II) from aqueous solution. Int J Biol Macromol 89:507–517. https://doi.org/10.1016/j.ijbiomac.2016.05.004CrossRefPubMed

Bansal M, Garg U, Singh D, Garg V (2009) Removal of Cr(VI) from aqueous solutions using pre-consumer processing agricultural waste: A case study of rice husk. J Hazard Mater 162(1):312–320. https://doi.org/10.1016/j.jhazmat.2008.05.037CrossRefPubMed

Bhattacharya A, Sarani C, Kumar Roy A, Karthik D, Singh A, Kumari S, Kumar Mishra A (2019) An analysis of arsenic contamination in the groundwater of India, Bangladesh and Nepal with a special focus on the stabilisation of arsenic-laden sludge from arsenic filters. Electron J Geotechn Eng 24

Birlik E, Ersöz A, Denizli A, Say R (2006) Preconcentration of copper using double-imprinted polymer via solid phase extraction. Anal Chim Acta 565(2):145–151. https://doi.org/10.1016/j.aca.2006.02.051CrossRef

Cataldo S, Gianguzza A, Milea D, Muratore N, Pettignano A (2016) Pb(II) adsorption by a novel activated carbon-alginate composite material: a kinetic and equilibrium study. Int J Biol Macromol 92:769–778. https://doi.org/10.1016/j.ijbiomac.2016.07.099CrossRefPubMed

Cazacu G, Popa V (2014) Blends and composites based on cellulose materials. In: Dumitriu S (ed) Polysaccharides: structural diversity and functional versatility, 2nd ed. New York, Basel, Hong Kong, Marcel Dekker, pp 1141–1177

Ding Y, Jing D, Gong H, Zhou L, Yang X (2012) Biosorption of aquatic cadmium(II) by unmodified rice straw. Biores Technol 114:20–25. https://doi.org/10.1016/j.biortech.2012.01.110CrossRef

Ehrlich H, Maldonado M, Spindler KD, Eckert C, Hanke T, Born R, Goebel C, Simon P, Heinemann S, Worch H (2007) First evidence of chitin as a component of the skeletal fibers of marine sponges, part I. Verongidae (demospongia: Porifera). J Exp Zool Part B Molecular Develop Evolution 308B(4):347–356. https://doi.org/10.1002/jez.b.21156 [32]

Liu D, Zhu Y, Li Z, Tian D, Chen L, Chen P (2013) Chitin nanofibrils for rapid and efficient removal of metal ions from water system. Carbohyd Polym 98(1):483–489. https://doi.org/10.1016/j.carbpol.2013.06.015CrossRef

Elwakeel KZ, Daher AM, Abd El-Fatah AIL, Abd El Monem H, Khalil MMH (2016) Biosorption of lanthanum from aqueous solutions using magnetic alginate beads. J Dispersion Sci Technol 38(1):145–151. https://doi.org/10.1080/01932691.2016.1146617CrossRef

Esmat M, Farghali AA, Khedr MH, El-Sherbiny IM (2017) Alginate-based nanocomposites for efficient removal of heavy metal ions. Int J Biol Macromol 102:272–283. https://doi.org/10.1016/j.ijbiomac.2017.04.021CrossRefPubMed

Fan C, Li K, Li J, Ying D, Wang Y, Jia J (2017) Comparative and competitive adsorption of Pb(II) and Cu(II) using Tetraethylenepentamine modified chitosan/CoFe2O4 particles. J Hazard Mater 326:211–220. https://doi.org/10.1016/j.jhazmat.2016.12.036CrossRefPubMed

Fiol N, Villaescusa I, Martínez M, Miralles N, Poch J, Serarols J (2006) Sorption of Pb(II), Ni(II), Cu(II) and Cd(II) from aqueous solution by olive stone waste. Sep Purif Technol 50(1):132–140. https://doi.org/10.1016/j.seppur.2005.11.016CrossRef

Gautam RK, Sharma SK, Mahiya S, Chattopadhyaya MC (2014) Contamination of heavy metals in aquatic media: transport, toxicity and technologies for remediation. Heavy Metals Water. https://doi.org/10.1039/9781782620174-00001

Ge H, Huang H, Xu M, Chen Q (2016) Cellulose/poly(ethylene imine) composites as efficient and reusable adsorbents for heavy metal ions. Cellulose 23(4):2527–2537. https://doi.org/10.1007/s10570-016-0973-3CrossRef

Gopal Reddi M, Gomathi T, Saranya M, Sudha P (2017) Adsorption and kinetic studies on the removal of chromium and copper onto Chitosan-g-maliec anhydride-g-ethylene dimethacrylate. Int J Biol Macromol 104:1578–1585. https://doi.org/10.1016/j.ijbiomac.2017.01.142CrossRefPubMed

Grant SB, Saphores JD, Feldman DL, Hamilton AJ, Fletcher TD, Cook PLM, Stewardson M, Sanders BF, Levin LA, Ambrose RF, Deletic A, Brown R, Jiang SC, Rosso D, Cooper WJ, Marusic I (2012) Taking the “waste” out of “wastewater” for human water security and ecosystem sustainability. Science 337(6095):681–686. https://doi.org/10.1126/science.1216852CrossRefPubMedADS

HPS AK, Saurabh CK, Adnan AS, Fazita MRN, Syakir M, Davoudpour Y, Rafatullah M, Abdullah CM, Haafiz M, Dungani R (2016) A review on chitosan-cellulose blends and nanocellulose reinforced chitosan biocomposites: properties and their applications. Carbohyd Polym 150:216–226. https://doi.org/10.1016/j.carbpol.2016.05.028

Hande PE, Kamble S, Samui AB, Kulkarni PS (2016) Chitosan-based lead ion-imprinted interpenetrating polymer network by simultaneous polymerization for selective extraction of Lead(II). Ind Eng Chem Res 55(12):3668–3678. https://doi.org/10.1021/acs.iecr.5b04889CrossRef

Hargreaves AJ, Constantino C, Dotro G, Cartmell E, Campo P (2018) Fate and removal of metals in municipal wastewater treatment: a review. Environ Technol Rev 7(1):1–18. https://doi.org/10.1080/21622515.2017.1423398CrossRef

Herath I, Vithanage M, Bundschuh J, Maity JP, Bhattacharya P (2016) Natural arsenic in global groundwaters: distribution and geochemical triggers for mobilization. Current Pollut Rep 2(1):68–89. https://doi.org/10.1007/s40726-016-0028-2CrossRef

Hossain M, Ngo H, Guo W, Setiadi T (2012) Adsorption and desorption of copper(II) ions onto garden grass. Biores Technol 121:386–395. https://doi.org/10.1016/j.biortech.2012.06.119CrossRef

Ibrahim AG, Saleh AS, Elsharma EM, Metwally E, Siyam T (2019) Chitosan-g-maleic acid for effective removal of copper and nickel ions from their solutions. Int J Biol Macromol 121:1287–1294. https://doi.org/10.1016/j.ijbiomac.2018.10.107CrossRefPubMed

Imam EA, El-Tantawy El-Sayed I, Mahfouz MG, Tolba AA, Akashi T, Galhoum AA, Guibal E (2018) Synthesis of α-aminophosphonate functionalized chitosan sorbents: effect of methyl vs phenyl group on uranium sorption. Chem Eng J 352:1022–1034. https://doi.org/10.1016/j.cej.2018.06.003CrossRef

Jung WJ, Song YS (2019) Expression pattern of β-glucanase and production of water-soluble polysaccharide in Pedobacter sp. PR-M6. J Chitin Chitosan 24(1):16–23. https://doi.org/10.17642/jcc.24.1.3

Sardar UR, Bhargavi E, Devi I, Bhunia B, Tiwari ON (2018) Advances in exopolysaccharides based bioremediation of heavy metals in soil and water: a critical review. Carbohyd Polym 199:353-364. https://doi.org/10.1016/j.carbpol.2018.07.037

Kahraman HT (2017) Development of an adsorbent via chitosan nano-organoclay assembly to remove hexavalent chromium from wastewater. Int J Biol Macromol 94:202–209. https://doi.org/10.1016/j.ijbiomac.2016.09.111CrossRefPubMed

Kanmani P, Aravind J, Kamaraj M, Sureshbabu P, Karthikeyan S (2017) Environmental applications of chitosan and cellulosic biopolymers: a comprehensive outlook. Biores Technol 242:295–303. https://doi.org/10.1016/j.biortech.2017.03.119CrossRef

Khoramzadeh E, Nasernejad B, Halladj R (2013) Mercury biosorption from aqueous solutions by Sugarcane Bagasse. J Taiwan Inst Chem Eng 44(2):266–269. https://doi.org/10.1016/j.jtice.2012.09.004CrossRef

Krishnani K, Meng X, Christodoulatos C, Boddu V (2008) Biosorption mechanism of nine different heavy metals onto biomatrix from rice husk. J Hazard Mater 153(3):1222–1234. https://doi.org/10.1016/j.jhazmat.2007.09.113CrossRefPubMed

Kumar PS, Ramalingam S, Kirupha SD, Murugesan A, Vidhyadevi T, Sivanesan S (2011) Adsorption behavior of nickel(II) onto cashew nut shell: Equilibrium, thermodynamics, kinetics, mechanism and process design. Chem Eng J 167(1):122–131. https://doi.org/10.1016/j.cej.2010.12.010CrossRef

Lagoa R, Rodrigues J (2009) Kinetic analysis of metal uptake by dry and gel alginate particles. Biochem Eng J 46(3):320–326. https://doi.org/10.1016/j.bej.2009.06.007CrossRef

Leyva-Ramos R, Landin-Rodriguez L, Leyva-Ramos S, Medellin-Castillo N (2012) Modification of corncob with citric acid to enhance its capacity for adsorbing cadmium(II) from water solution. Chem Eng J 180:113–120. https://doi.org/10.1016/j.cej.2011.11.021CrossRef

Lim AP, Aris AZ (2014) A review on economically adsorbents on heavy metals removal in water and wastewater. Rev Environ Sci Bio/technol 13(2):163–181. https://doi.org/10.1007/s11157-013-9330-2CrossRefADS

Liu P, Borrell PF, Božič M, Kokol V, Oksman K, Mathew AP (2015) Nanocelluloses and their phosphorylated derivatives for selective adsorption of Ag+, Cu2+ and Fe3+ from industrial effluents. J Hazard Mater 294:177–185. https://doi.org/10.1016/j.jhazmat.2015.04.001CrossRefPubMed

Luo W, Bai Z, Zhu Y (2018) Fast removal of Co(ii) from aqueous solution using porous carboxymethyl chitosan beads and its adsorption mechanism. RSC Adv 8(24):13370–13387. https://doi.org/10.1039/c7ra13064cCrossRefADS

Luo X, Yuan J, Liu Y, Liu C, Zhu X, Dai X, Ma Z, Wang F (2017) Improved solid-phase synthesis of phosphorylated cellulose microsphere adsorbents for highly effective Pb2+ removal from water: batch and fixed-bed column performance and adsorption mechanism. ACS Sustain Chem Eng 5(6):5108–5117. https://doi.org/10.1021/acssuschemeng.7b00472CrossRef

Ma X, Liu X, Anderson DP, Chang PR (2015) Modification of porous starch for the adsorption of heavy metal ions from aqueous solution. Food Chem 181:133–139. https://doi.org/10.1016/j.foodchem.2015.02.089CrossRefPubMed

Mogoşanu GD, Grumezescu AM (2014) Natural and synthetic polymers for wounds and burns dressing. Int J Pharm 463(2):127–136. https://doi.org/10.1016/j.ijpharm.2013.12.015CrossRefPubMed

Mohammad N, Atassi Y, Tally M (2017) Synthesis and swelling behavior of metal-chelating superabsorbent hydrogels based on sodium alginate-g-poly(AMPS-co-AA-co-AM) obtained under microwave irradiation. Polym Bull 74(11):4453–4481. https://doi.org/10.1007/s00289-017-1967-5CrossRef

Mohammadzadeh Pakdel P, Peighambardoust SJ (2018) Review on recent progress in chitosan-based hydrogels for wastewater treatment application. Carbohyd Polym 201:264–279. https://doi.org/10.1016/j.carbpol.2018.08.070CrossRef

Mohammed N, Grishkewich N, Tam KC (2018) Cellulose nanomaterials: promising sustainable nanomaterials for application in water/wastewater treatment processes. Environ Sci Nano 5(3):623–658. https://doi.org/10.1039/c7en01029jCrossRef

Monier M, Ayad D, Wei Y, Sarhan A (2010) Adsorption of Cu(II), Co(II), and Ni(II) ions by modified magnetic chitosan chelating resin. J Hazard Mater 177(1–3):962–970. https://doi.org/10.1016/j.jhazmat.2010.01.012CrossRefPubMed

Muzzarelli RA (2011) Potential of chitin/chitosan-bearing materials for uranium recovery: an interdisciplinary review. Carbohyd Polym 84(1):54–63. https://doi.org/10.1016/j.carbpol.2010.12.025CrossRef

Naushad M, Ahamad T, Sharma G, Al-Muhtaseb AH, Albadarin AB, Alam MM, ALOthman ZA, Alshehri SM, Ghfar AA (2016) Synthesis and characterization of a new starch/SnO2 nanocomposite for efficient adsorption of toxic Hg2+ metal ion. Chem Eng J 300:306-316. https://doi.org/10.1016/j.cej.2016.04.084

Negm NA, El Sheikh R, El-Farargy AF, Hefni HH, Bekhit M (2015) Treatment of industrial wastewater containing copper and cobalt ions using modified chitosan. J Ind Eng Chem 21:526–534. https://doi.org/10.1016/j.jiec.2014.03.015CrossRef

Nussinovitch A, Dagan O (2015) Hydrocolloid liquid-core capsules for the removal of heavy-metal cations from water. J Hazard Mater 299:122–131. https://doi.org/10.1016/j.jhazmat.2015.06.013CrossRefPubMed

Olivera S, Muralidhara HB, Venkatesh K, Guna VK, Gopalakrishna K, Kumar K (2016) Potential applications of cellulose and chitosan nanoparticles/composites in wastewater treatment: a review. Carbohyd Polym 153:600–618. https://doi.org/10.1016/j.carbpol.2016.08.017

Pehlivan E, Altun T, Parlayici (2012) Modified barley straw as a potential biosorbent for removal of copper ions from aqueous solution. Food Chem 135(4):2229–2234. https://doi.org/10.1016/j.foodchem.2012.07.017

Pereira FV, Gurgel LVA, Gil LF (2010) Removal of Zn2+ from aqueous single metal solutions and electroplating wastewater with wood sawdust and sugarcane bagasse modified with EDTA dianhydride (EDTAD). J Hazard Mater 176(1–3):856–863. https://doi.org/10.1016/j.jhazmat.2009.11.115CrossRefPubMed

Rajamani M, Rajendrakumar K (2019) Chitosan-boehmite desiccant composite as a promising adsorbent towards heavy metal removal. J Environ Manage 244:257–264. https://doi.org/10.1016/j.jenvman.2019.05.056CrossRefPubMed

Ren Y, Zhang M, Zhao D (2008) Synthesis and properties of magnetic Cu(II) ion imprinted composite adsorbent for selective removal of copper. Desalination 228(1–3):135–149. https://doi.org/10.1016/j.desal.2007.08.013CrossRef

Riaz T, Ahmad A, Saleemi S, Adrees M, Jamshed F, Hai AM, Jamil T (2016) Synthesis and characterization of polyurethane-cellulose acetate blend membrane for chromium (VI) removal. Carbohyd Polym 153:582–591. https://doi.org/10.1016/j.carbpol.2016.08.011CrossRef

Rocha CG, Zaia DAM, Alfaya RVDS, Alfaya AADS (2009) Use of rice straw as biosorbent for removal of Cu(II), Zn(II), Cd(II) and Hg(II) ions in industrial effluents. J Hazard Mater 166(1):383–388. https://doi.org/10.1016/j.jhazmat.2008.11.074CrossRefPubMed

Rojas S, Horcajada P (2020) Metal-organic frameworks for the removal of emerging organic contaminants in water. Chem Rev 120(16):8378–8415. https://doi.org/10.1021/acs.chemrev.9b00797CrossRefPubMed

Sargın D, Arslan G (2015) Chitosan/sporopollenin microcapsules: Preparation, characterisation and application in heavy metal removal. Int J Biol Macromol 75:230–238. https://doi.org/10.1016/j.ijbiomac.2015.01.039CrossRefPubMed

Schleuter D, Günther A, Paasch S, Ehrlich H, Kljajić Z, Hanke T, Bernhard G, Brunner E (2013) Chitin-based renewable materials from marine sponges for uranium adsorption. Carbohyd Polym 92(1):712–718. https://doi.org/10.1016/j.carbpol.2012.08.090CrossRef

Sha L, Xueyi G, Ningchuan F, Qinghua T (2009) Adsorption of Cu2+ and Cd2+ from aqueous solution by mercapto-acetic acid modified orange peel. Colloids Surf B 73(1):10–14. https://doi.org/10.1016/j.colsurfb.2009.04.021CrossRef

Sharma PR, Chattopadhyay A, Zhan C, Sharma SK, Geng L, Hsiao BS (2018) Lead removal from water using carboxycellulose nanofibers prepared by nitro-oxidation method. Cellulose 25(3):1961–1973. https://doi.org/10.1007/s10570-018-1659-9CrossRef

Sousa FW, Oliveira AG, Ribeiro JP, Rosa MF, Keukeleire D, Nascimento RF (2010) Green coconut shells applied as adsorbent for removal of toxic metal ions using fixed-bed column technology. J Environ Manage 91(8):1634–1640. https://doi.org/10.1016/j.jenvman.2010.02.011CrossRefPubMed

Stela DE, Valentina DM, Shankar G (2015) Recent developments in composite biosorbents and their applications for wastewater treatment. J Environ Chem Eng 19:42–58

Gupta VK, Carrott PJ, Singh R, Chaudhary M, Kushwaha S (2016) Cellulose: a review as natural, modified and activated carbon adsorbent. Biores Technol 216:1066-1076. https://doi.org/10.1016/j.biortech.2016.05.106

Tabasum S, Noreen A, Maqsood MF, Umar H, Akram N, Nazli ZIH, Chatha SAS, Zia KM (2018) A review on versatile applications of blends and composites of pullulan with natural and synthetic polymers. Int J Biol Macromol 120:603–632. https://doi.org/10.1016/j.ijbiomac.2018.07.154CrossRefPubMed

Tan G, Xiao D (2009) Adsorption of cadmium ion from aqueous solution by ground wheat stems. J Hazard Mater 164(2–3):1359–1363. https://doi.org/10.1016/j.jhazmat.2008.09.082CrossRefPubMed

Tan G, Yuan H, Liu Y, Xiao D (2010) Removal of lead from aqueous solution with native and chemically modified corncobs. J Hazard Mater 174(1–3):740–745. https://doi.org/10.1016/j.jhazmat.2009.09.114CrossRefPubMed

Torab-Mostaedi M, Asadollahzadeh M, Hemmati A, Khosravi A (2013) Equilibrium, kinetic, and thermodynamic studies for biosorption of cadmium and nickel on grapefruit peel. J Taiwan Inst Chem Eng 44(2):295–302. https://doi.org/10.1016/j.jtice.2012.11.001CrossRef

Vakili M, Rafatullah M, Salamatinia B, Abdullah AZ, Ibrahim MH, Tan KB, Gholami Z, Amouzgar P (2014) Application of chitosan and its derivatives as adsorbents for dye removal from water and wastewater: A review. Carbohyd Polym 113:115–130. https://doi.org/10.1016/j.carbpol.2014.07.007CrossRef

van Loosdrecht MCM, Brdjanovic D (2014) Anticipating the next century of wastewater treatment. Science 344(6191):1452–1453. https://doi.org/10.1126/science.1255183CrossRefPubMedADS

Vandenbossche M, Jimenez M, Casetta M, Traisnel M (2014) Remediation of heavy metals by biomolecules: a review. Crit Rev Environ Sci Technol 45(15):1644–1704. https://doi.org/10.1080/10643389.2014.966425CrossRef

Varma A, Deshpande S, Kennedy J (2004) Metal complexation by chitosan and its derivatives: a review. Carbohyd Polym 55(1):77–93. https://doi.org/10.1016/j.carbpol.2003.08.005CrossRef

Velazquez-Jimenez LH, Pavlick A, Rangel-Mendez JR (2013) Chemical characterization of raw and treated agave bagasse and its potential as adsorbent of metal cations from water. Ind Crops Prod 43:200–206. https://doi.org/10.1016/j.indcrop.2012.06.049CrossRef

Wang G, Xin Y, Uyama H (2015) Facile fabrication of mesoporous poly(ethylene- co -vinyl alcohol)/chitosan blend monoliths. Carbohyd Polym 132:345–350. https://doi.org/10.1016/j.carbpol.2015.06.040CrossRef

Wang J, Liu M, Duan C, Sun J, Xu Y (2019) Preparation and characterization of cellulose-based adsorbent and its application in heavy metal ions removal. Carbohyd Polym 206:837–843. https://doi.org/10.1016/j.carbpol.2018.11.059CrossRef

Wang J, Wei L, Ma Y, Li K, Li M, Yu Y, Wang L, Qiu H (2013) Collagen/cellulose hydrogel beads reconstituted from ionic liquid solution for Cu(II) adsorption. Carbohyd Polym 98(1):736–743. https://doi.org/10.1016/j.carbpol.2013.06.001CrossRef

Werber JR, Osuji CO, Elimelech M (2016) Erratum: Materials for next-generation desalination and water purification membranes. Nat Rev Mater. https://doi.org/10.1038/natrevmats.2016.37CrossRef

Witek-Krowiak A (2012) Analysis of temperature-dependent biosorption of Cu2+ ions on sunflower hulls: Kinetics, equilibrium and mechanism of the process. Chem Eng J 192:13–20. https://doi.org/10.1016/j.cej.2012.03.075CrossRef

Wu MT, Tsai YL, Chiu CW, Cheng CC (2016) Synthesis, characterization, and highly acid-resistant properties of crosslinking β-chitosan with polyamines for heavy metal ion adsorption. RSC Adv 6(106):104754–104762. https://doi.org/10.1039/c6ra21993dCrossRefADS

Xiang B, Fan W, Yi X, Wang Z, Gao F, Li Y, Gu H (2016) Dithiocarbamate-modified starch derivatives with high heavy metal adsorption performance. Carbohyd Polym 136:30–37. https://doi.org/10.1016/j.carbpol.2015.08.065CrossRef

Xu SM, Feng S, Peng G, Wang JD, Yushan A (2005) Removal of Pb (II) by crosslinked amphoteric starch containing the carboxymethyl group. Carbohyd Polym 60(3):301–305. https://doi.org/10.1016/j.carbpol.2005.01.018CrossRef

Yang D, Li L, Chen B, Shi S, Nie J, Ma G (2019) Functionalized chitosan electrospun nanofiber membranes for heavy-metal removal. Polymer 163:74–85. https://doi.org/10.1016/j.polymer.2018.12.046CrossRef

Yang R, Su Y, Aubrecht KB, Wang X, Ma H, Grubbs RB, Hsiao BS, Chu B (2015) Thiol-functionalized chitin nanofibers for As (III) adsorption. Polymer 60:9–17. https://doi.org/10.1016/j.polymer.2015.01.025CrossRef

Yule B, Roberts S, Marshall J (2000) The thermal evolution of sporopollenin. Org Geochem 31(9):859–870. https://doi.org/10.1016/s0146-6380(00)00058-9CrossRef

Zaman CZ, Pal K, Yehye WA, Sagadevan S, Shah ST, Adebisi GA, Johan RB (2017) Pyrolysis: a sustainable way to generate energy from waste. INTECH. https://doi.org/10.1016/j.colsurfa.2011.12.014

Zhang X, Shen J, Pan S, Qian J, Pan B (2020) Metastable zirconium phosphate under nanoconfinement with superior adsorption capability for water treatment. Adv Func Mater 30(12):1909014. https://doi.org/10.1002/adfm.201909014CrossRef

Zhao F, Repo E, Yin D, Sillanpää ME (2013) Adsorption of Cd(II) and Pb(II) by a novel EGTA-modified chitosan material: Kinetics and isotherms. J Colloid Interface Sci 409:174–182. https://doi.org/10.1016/j.jcis.2013.07.062CrossRefPubMedADS

Zhao X, Yu X, Wang X, Lai S, Sun Y, Yang D (2021) Recent advances in metal-organic frameworks for the removal of heavy metal oxoanions from water. Chem Eng J 407:127221. https://doi.org/10.1016/j.cej.2020.127221

Title: Science and Technology Roadmap for Adsorption of Metallic Contaminants from Aqueous Effluents Using Biopolymers and Its’ Derivatives
Authors: Ahmed Elsayid Ali
Zaira Zaman Chowdhury
Rahman F. Rafique
Rabia Ikram
Abu Nasser Mohammad Faisal
ShahJalal Shibly
Arnab Barua
Yasmin Abdul Wahab
Badrul Mohamed Jan
Publisher: Springer International Publishing
Book: Advanced Industrial Wastewater Treatment and Reclamation of Water
Print ISBN: 978-3-030-83810-2

Electronic ISBN: 978-3-030-83811-9

Copyright Year: 2022
DOI: https://doi.org/10.1007/978-3-030-83811-9_9