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Polymer Bulletin
Published in: Polymer Bulletin 8/2019

09-11-2018 | Original Paper

Silver nanoparticles embedded pectin-based hydrogel: a novel adsorbent material for separation of cationic dyes

Authors: Gangadhar Babaladimath, Vishalakshi Badalamoole

Published in: Polymer Bulletin | Issue 8/2019

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Abstract

Free radical polymerization of mixture of 2-acrylamido-2-methylpropanesulfonic acid and Pectin in the presence of N,N-methylenebisacrylamide resulted in the cross-linked graft copolymer network (Pec-g-PAMPS). Silver nanoparticles were formed and stabilized by the reduction of silver nitrate using trisodium citrate within the gel network. The hydrogel and the nanocomposite hydrogel were characterized using FTIR, TGA, XRD, SEM, EDS and TEM techniques and evaluated for removal of methylene blue from aqueous solution. The presence of Ag NPs is observed to enhance the swelling ability of the Pec-g-PAMPS gels significantly. The kinetics studies indicated the adsorption to be a second-order process and the adsorption rate was influenced by intraparticle diffusion. The adsorption isotherm was in good agreement with Freundlich model suggesting surface heterogeneity of the novel adsorbent. Further, the thermodynamic studies revealed the adsorption to be a spontaneous and exothermic process. The nanocomposite hydrogel retained 80% efficiency after three cycles indicating reusability for waste water treatment.
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Appendix
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Literature
1.
Simelane LP, Njobeh P, Elvis FK, Sadanand P (2018) Response of bacterial biosorbents to chemical treatment as influenced by cell membrane structure and impact on the adsorption behavior of dyes. Curr Sci 114:826–834CrossRef
2.
Pandey S, Mishra SB (2014) Chemical nanosensors for monitoring environmental pollution. In: Mishra A (ed) Application of nanotechnology in water research. Scrivener Publishing LLC, Beverly, pp 309–332
3.
Wu YJ, Zhang LJ, Gao CL, Ma JY, Ma XH, Han RP (2009) Adsorption of copper ions and methylene blue in a single and binary system on wheat straw. J Chem Eng Data 54:3229–3234CrossRef
4.
Hameed BH, Din AT, Ahmad AL (2007) Adsorption of methylene blue onto bamboo-based activated carbon: kinetics and equilibrium studies. J Hazard Mater 141:819–825CrossRefPubMed
5.
Makhado E, Pandey S, Nomngongo PN, Ramontja J (2017) Fast microwave-assisted green synthesis of xanthan gum grafted acrylic acid for enhanced methylene blue dye removal from aqueous solution. Carbohydr Polym 176:315–326CrossRefPubMed
6.
Pandey S (2017) A comprehensive review on recent developments in bentonite based materials used as adsorbents for wastewater treatment. J Mol Liq 241:1091–1113CrossRef
7.
Thakur S, Pandey S, Arotiba O (2017) Sol-gel derived xanthan gum/silica nanocomposite—a highly efficient cationic dyes adsorbent in aqueous system. Int J Biol Macromol 103:596–604CrossRefPubMed
8.
Kobayashi Y, Yasuda Y, Morita T (2016) Recent advances in the synthesis of copper-based nanoparticles for metal metal bonding processes. J Sci Adv Mater Devices 1:413–430CrossRef
9.
Karthika JS, Vishalakshi B (2015) Novel stimuli-responsive gellan gum–graft poly(DMAEMA) hydrogel as adsorbent for anionic dye. Int J Biol Macromol 81:648–655CrossRefPubMed
10.
Sirajo AZ, Vishalakshi B (2016) Microwave assisted synthesis of poly(diallyldimethylammonium chloride) grafted locust bean gum: swelling and dye adsorption studies. Indian J Adv Chem Sci S1:88–91
11.
Arun Krishna K, Vishalakshi B (2017) Gellan gum-based novel composite hydrogel: evaluation as adsorbent for cationic dyes. J Appl Polym Sci 134:45527–455535CrossRef
12.
Guilherme MR, Reis AV, Paulino AT, Moia TA, Luiz HC, Mattoso Tambourgi EB (2010) Pectin-based polymer hydrogel as a carrier for release of agricultural nutrients and removal of heavy metals from wastewater. J Appl Polym Sci 117:3146–3154
13.
Chauhan GS, Kumari A, Sharma R (2007) Pectin and acrylamide based hydrogels for environment management technologies: synthesis, characterization, and metal ions sorption. J App Polym Sci 106:2158–2168CrossRef
14.
Reddy NS, Rao KM, Sudha Vani TJ, Krishna Rao KSV, Lee YI (2015) Pectin/poly(acrylamide-co-acrylamidoglycolic acid) pH sensitive semi-IPN hydrogels: selective removal of Cu2+ and Ni2+, modeling, and kinetic studies. Desalin Water Treat 57:1–12
15.
16.
Hosseinzadeh H, Khoshnood N (2016) Removal of cationic dyes by poly(AA-co AMPS)/montmorillonite nanocomposite hydrogel. J Desalin Water Treat 57:6372–6383CrossRef
17.
Kasgoz H, Durmus A, Kasgoz A (2008) Enhanced swelling and adsorption properties of AAm-AMPSNa/clay hydrogel nanocomposites for heavy metal ion removal. Polym Adv Technol 19:213–220CrossRef
18.
Atta AM, Al-Lohedan HA, ALOthman ZA, Abdel-Khalek AA, Tawfeek AM (2015) Characterization of reactive amphiphilic montmorillonite nanogels and its application for removal of toxic cationic dye and heavy metals water pollutants. J Ind Eng Chem 31:374–384CrossRef
19.
Urbano BF, Rivas BL (2013) Synthesis, characterization, and sorption properties of water-insoluble poly(2-acrylamido-2-methyl-1-propane sulfonic acid)–montmorillonite composite. Polym Bull 70:1143–1162CrossRef
20.
Sirajo AZ, Vishalakshi B (2017) Amphoteric gellan gum-based terpolymer-montmorillonite composite: synthesis, swelling and dye adsorption studies. Int J Ind chem 8:345–362CrossRef
21.
Sirajo AZ, Vishalakshi B (2017) Synthesis of locust bean gum-based terpolymer bentonite composite: evaluation for indigo carmine adsorption. Int J Adv Chem 5:61–69CrossRef
22.
Arun Krishna K, Vishalakshi B (2017) Pectin based ZnO nanocomposite hydrogel: evaluation as adsorbent for divalent metal ions from aqueous solutions. Elixir Nanotechnol 107:47326–47331
23.
Pall J, Deb MK, Deshmukh DK, Verma D (2013) Removal of methyl orange by activated carbon modified by silver nanoparticles. Appl Water Sci 3:367–374CrossRef
24.
Hosseinzadeh H (2016) Microwave-assisted synthesis of kappa-carrageenan beads containing silver nanoparticles with dye adsorption and antibacterial properties. J Nanostruct 6:132–139
25.
Varaprasad K, Mohan YM, Ravindra S, Reddy NN, Vimala K, Monika K, Sreedhar B, Raju MK (2010) Hydrogel-silver nanoparticle composites: a new generation of antimicrobials. J App Polym Sci 115:1199–1207CrossRef
26.
Babu R, Changdae Kim V, Kim S, Ahn C, Lee YI (2010) Development of semi-interpenetrating carbohydrate polymeric hydrogels embedded silver nanoparticles and its facile studies on E. coli. Carbohydr Polym 81:196–202CrossRef
27.
Ghorai S, Sarkar A, Raoufi M, Panda AB, Schönherr H, Pal S (2014) Enhanced removal of methylene blue and methyl violet dyes from aqueous solution using a nanocomposite of hydrolyzed polyacrylamide grafted xanthan gum and incorporated nanosilica. Appl Mater Interfaces 6:4766–4777CrossRef
28.
Singha V, Kumar P, Sanghi R (2012) Use of microwave irradiation in the grafting modification of the polysaccharides—a review. Prog Polym Sci 37:340–364CrossRef
29.
Coskun R, Delibas A (2012) Removal of methylene blue from aqueous solutions by poly(2-acrylamido-2-methylpropane sulfonic acid-co-itaconic acid) hydrogels. Polym Bull 68:1889–1903CrossRef
30.
Jayaramudu T, Raghavendra GM, Varaprasad K, Sadiku R, Ramam K, Raju MK (2013) Iota-Carrageenan-based biodegradable Ag0 nanocomposite hydrogels for the inactivation of bacteria. Carbohydr Polym 95:188–194CrossRefPubMed
31.
Babaladimath G, Badalamoole V (2018) Pectin-graft-poly(2-acrylamido-2-methyl-1-propane sulfonic acid) silver nanocomposite hydrogel beads: evaluation as matrix material for sustained release formulations of ketoprofen and antibacterial assay. J Polym Res 25:202CrossRef
32.
Nesic AR, Panic VV, Onjia AE, Velickovic SJ (2015) The enhanced removal of cationic dyes in binary system using novelcopolymers with two kinds of acidic groups. Colloids Surf A Physicochem Eng Asp 476:24–34CrossRef
33.
Vanamudan A, Bandwala K, Pamidimukkala P (2014) Adsorption property of Rhodamine 6G onto chitosan-graft-(N-vinyl pyrrolidone)/montmorillonite composite. Int J Biol Macromol 69:506–513CrossRefPubMed
34.
Weber WJ, Morris JC (1963) Kinetics of adsorption on carbon from solution. J San Eng Div Am Soc Civ Eng 89:31–59
35.
Sen TK, Afroze S, Ang HM (2011) Equilibrium, kinetics and mechanism of removal of methylene blue from aqueous solution by adsorption onto pine cone biomass of pinus radiate. Water Air Soil Pollut 218:499–515CrossRef
36.
Bhattacharyya KG, Sharma A (2004) Adsorption of Pb(II) from aqueous solution by Azadirachta indica (Neem) leaf powder. J Hazard Mater B 113:97–109CrossRef
37.
Freundlich HMF (1906) Kinetics and thermodynamics of adsorption methylene blue onto tea waste/CuFe2O4 composite. J Phys Chem 57:385–471
38.
Mittal H, Parashar V, Mishra SB, Mishra AK (2014) Fe3O4 MNPs and gum xanthan based hydrogels nanocomposites for the efficient capture of malachite green from aqueous solution. Chem Eng J 255:471–482CrossRef
39.
Langmuir I (1918) The adsorption of gases on plane surfaces of glass, mica and platinum. J Am Chem Soc 40:1361–1403CrossRef
40.
Mittal H, Maity A, Ray SS (2015) Effective removal of cationic dyes from aqueous solution using gum ghatti-based biodegradable hydrogel. Int J Biol Macromol 79:8–20CrossRefPubMed
41.
Chen L, Li Y, Du Q, Wang Z, Xia Y, Yedinak E, Lou J, Ci L (2017) High performance agar/graphene oxide composite aerogel for methylene blue removal. Carbohydr Polym 155:345–353CrossRefPubMed
42.
Tonga DS, Wua CW, Adebajob MO, Jina GC, Yua WH, Jic SF, Zhoua CH (2018) Adsorption of methylene blue from aqueous solution onto porous cellulose derived carbon/montmorillonite nanocomposites. Appl Clay Sci 161:256–264CrossRef
43.
44.
Shi H, Li W, Zhong L, Xu C (2014) Methylene blue adsorption from aqueous solution by magnetic cellulose/graphene oxide composite: equilibrium, kinetics, and thermodynamics. Ind Eng Chem Res 53:1108–1118CrossRef
45.
Pal S, Ghorai S, Das C, Samrat S, Ghosh A, Panda AB (2012) Carboxymethyl tamarind-g-poly(acrylamide)/silica: a high performance hybrid nanocomposite for adsorption of methylene blue dye. Ind Eng Chem Res 51:15546–15556CrossRef
46.
Atta A, Akl MA, Youssef AM, Ibraheim MA (2013) Superparamagnetic core-shell polymeric nanocomposites for efficient removal of methylene blue from aqueous solutions. Adsorpt Sci Technol 31:397–419CrossRef
Metadata
Title
Silver nanoparticles embedded pectin-based hydrogel: a novel adsorbent material for separation of cationic dyes
Authors
Gangadhar Babaladimath
Vishalakshi Badalamoole
Publication date
09-11-2018
Publisher
Springer Berlin Heidelberg
Published in
Polymer Bulletin / Issue 8/2019
Print ISSN: 0170-0839
Electronic ISSN: 1436-2449
DOI
https://doi.org/10.1007/s00289-018-2584-7

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