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Published in: Journal of Materials Science: Materials in Electronics 10/2013

01-10-2013

Sintering, densification and crystallization of Ca–Al–B–Si–O glass/Al2O3 composites for LTCC application

Authors: Ming Liu, Hongqing Zhou, Xiaoying Xu, Zhenxing Yue, Min Liu, Haikui Zhu

Published in: Journal of Materials Science: Materials in Electronics | Issue 10/2013

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Abstract

Ca–Al–B–Si–O glass/Al2O3 composites were prepared based on the borosilicate glass powders (D50 = 2.84) and Al2O3 ceramic powders (D50 = 3.26), and the sintering, densification, crystallization of samples were investigated. The shrinkage of sample starts to have a sharp increase at 600 °C. The shrinkage of sample starts to have a further rapid increase after the glass softening temperature of about 713 °C. Glass/Al2O3 composites can be sintered at 875 °C/15 min and exhibit better properties of a relative density of 98.4 %, a λ value of 2.89 W/mK, a ε r value of 7.82 and a tan δ value of 5.3 × 10−4. The interface between glass and Al2O3 grains and the interface between anorthite and glass phase depicts a good compatibility according to transmission electron microcopy test. It is the low sintering temperature, high density and good compatibility with Ag electrodes that, guarantee borosilicate glass/Al2O3 composites suitable for low temperature co-fired ceramic materials.

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Metadata
Title
Sintering, densification and crystallization of Ca–Al–B–Si–O glass/Al2O3 composites for LTCC application
Authors
Ming Liu
Hongqing Zhou
Xiaoying Xu
Zhenxing Yue
Min Liu
Haikui Zhu
Publication date
01-10-2013
Publisher
Springer US
Published in
Journal of Materials Science: Materials in Electronics / Issue 10/2013
Print ISSN: 0957-4522
Electronic ISSN: 1573-482X
DOI
https://doi.org/10.1007/s10854-013-1351-7

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