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Published in: Journal of Sol-Gel Science and Technology 1/2018

14-03-2018 | Original Paper: Sol-gel and hybrid materials for dielectric, electronic, magnetic and ferroelectric applications

Sol-gel synthesis of ZnO/Zn2-xFexTiO4 powders: structural properties, electrical conductivity and dielectric behavior

Authors: Izabella Dascalu, Cristian Hornoiu, Jose Maria Calderon-Moreno, Madalin Enache, Daniela Culita, Simona Somacescu

Published in: Journal of Sol-Gel Science and Technology | Issue 1/2018

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Abstract

The aim of this work was an investigation of structural and electrical properties of ZnO/Zn2-xFexTiO4 (x = 0.7, 1, 1.4) powders. The compounds obtained by sol-gel method are characterized by several techniques: X-ray diffraction (XRD), N2 adsorption–desorption isotherms, scanning and transmission electron microscopy (SEM and TEM), X-ray photoelectron spectroscopy (XPS), electrical and dielectrical measurements. The XRD, SEM and XPS analysis confirmed the formation of ZnFeTiO4 inverse spinel structure. The electrical and dielectrical properties of ZnO/Zn2-xFexTiO4 (x = 0.7, 1, 1.4) were measured by impedance spectroscopy, revealing a decrease in the electrical conductivity and the dielectric constant with Fe content.

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Appendix
Available only for authorised users
Literature
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go back to reference Chesler P, Hornoiu C, Mihaiu S, Vladut C, Calderon-Moreno JM, Anastasescu M, Moldovan C, Firtat B, Brasoveanu C, Muscalu G, Stan I, Gartner M (2016) Nanostructured SnO2–ZnO composite gas sensors for selective detection of carbon monoxide. Beilstein J Nanotechnol 7:2045–2056. https://doi.org/10.3762/bjnano.7.195 CrossRef Chesler P, Hornoiu C, Mihaiu S, Vladut C, Calderon-Moreno JM, Anastasescu M, Moldovan C, Firtat B, Brasoveanu C, Muscalu G, Stan I, Gartner M (2016) Nanostructured SnO2–ZnO composite gas sensors for selective detection of carbon monoxide. Beilstein J Nanotechnol 7:2045–2056. https://​doi.​org/​10.​3762/​bjnano.​7.​195 CrossRef
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go back to reference Sing KSW, Everett DH, Haul RAW, Moscou L, Pierotti RA, Rouquerol J, Siemieniewska T (1985) Reporting physisorption data for gas/solid systems with special reference to the determination of surface area and porosity (IUPAC Recommendations 1984), Pure & Appl Chem 57:603–619. https://doi.org/10.1351/pac198557040603 Sing KSW, Everett DH, Haul RAW, Moscou L, Pierotti RA, Rouquerol J, Siemieniewska T (1985) Reporting physisorption data for gas/solid systems with special reference to the determination of surface area and porosity (IUPAC Recommendations 1984), Pure & Appl Chem 57:603–619. https://​doi.​org/​10.​1351/​pac198557040603
Metadata
Title
Sol-gel synthesis of ZnO/Zn2-xFexTiO4 powders: structural properties, electrical conductivity and dielectric behavior
Authors
Izabella Dascalu
Cristian Hornoiu
Jose Maria Calderon-Moreno
Madalin Enache
Daniela Culita
Simona Somacescu
Publication date
14-03-2018
Publisher
Springer US
Published in
Journal of Sol-Gel Science and Technology / Issue 1/2018
Print ISSN: 0928-0707
Electronic ISSN: 1573-4846
DOI
https://doi.org/10.1007/s10971-018-4623-0

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