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Cellulose

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01-10-2009

Solution behavior and surface properties of carboxymethylcellulose acetate butyrate

Authors: Jorge Amim Jr., Denise F. S. Petri, Francisco C. B. Maia, Paulo B. Miranda

Published in: Cellulose | Issue 5/2009

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Abstract

Solution behavior of carboxymethylcellulose acetate butyrate (CMCAB) in acetone and ethyl acetate has been investigated by small-angle X-ray scattering (SAXS) and capillary viscometry and correlated with the characteristics of CMCAB films. Viscosity and SAXS measurements showed that ethyl acetate is a better solvent than acetone for CMCAB. Thin films of CMCAB were deposited onto silicon wafers (Si/SiO₂) by spin coating. AFM images revealed that CMCAB spin coated films from solutions prepared in ethyl acetate were homogeneous and flat. However, films obtained from solutions in acetone were very rough. Contact angle measurements with polar and apolar test liquids characterized CMCAB surfaces as hydrophobic and allowed estimating the surface energy of CMCAB. Sum frequency generation vibrational spectroscopy was used to understand the role played by solvents and to gain insight about molecular orientation at Si/SiO₂/CMCAB interface.

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Title: Solution behavior and surface properties of carboxymethylcellulose acetate butyrate
Authors: Jorge Amim Jr.
Denise F. S. Petri
Francisco C. B. Maia
Paulo B. Miranda
Publication date: 01-10-2009
Publisher: Springer Netherlands
Published in: Cellulose / Issue 5/2009
Print ISSN: 0969-0239
Electronic ISSN: 1572-882X
DOI: https://doi.org/10.1007/s10570-009-9295-z

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