Skip to main content
Top

2020 | OriginalPaper | Chapter

39. Spezielle labortechnische Reaktoren: TAP-Reaktor

Author : Cornelia Breitkopf

Published in: Handbuch Chemische Reaktoren

Publisher: Springer Berlin Heidelberg

Activate our intelligent search to find suitable subject content or patents.

search-config
loading …

Zusammenfassung

Der TAP-Reaktor ist als spezieller Pulsreaktor ein labortechnisches Hilfsmittel zur Aufklärung von adsorptiven und diffussiven Vorgängen von Gasen in porösen Netzwerken, die in heterogen katalysierten Reaktionen maßgeblich Umsatz und Selektivität beeinflussen. Daneben können aufgrund der hohen zeitlichen Auflösung auch Aussagen zu ablaufenden Teilreaktionen erhalten werden und in eine mikrokinetische Modellierung einfließen.

Dont have a licence yet? Then find out more about our products and how to get one now:

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

  • über 102.000 Bücher
  • über 537 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Finance + Banking
  • Management + Führung
  • Marketing + Vertrieb
  • Maschinenbau + Werkstoffe
  • Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

  • über 67.000 Bücher
  • über 390 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Maschinenbau + Werkstoffe




 

Jetzt Wissensvorsprung sichern!

Literature
go back to reference Bennett, C.O.: Experiments and processes in the transient regime for heterogeneous catalysis. Adv. Catal. 44, 329–416 (2000) Bennett, C.O.: Experiments and processes in the transient regime for heterogeneous catalysis. Adv. Catal. 44, 329–416 (2000)
go back to reference Böhm, J., Hunger, B., Papp, H.: Adsorption of carbon dioxide on zeolites NaX and NaY studied by a temporal analysis of products (TAP) system. Stud. Surf. Sci. Catal. 158, 1113–1120 (2005)CrossRef Böhm, J., Hunger, B., Papp, H.: Adsorption of carbon dioxide on zeolites NaX and NaY studied by a temporal analysis of products (TAP) system. Stud. Surf. Sci. Catal. 158, 1113–1120 (2005)CrossRef
go back to reference Boonwatcharapunsakul, W., Phanawadee, P.: A new analytical expression of the gas conversion for TAP experiments with bimodal-pore-structure catalyst. Chiang Mai J. Sci. 35(1), 150–155 (2008) Boonwatcharapunsakul, W., Phanawadee, P.: A new analytical expression of the gas conversion for TAP experiments with bimodal-pore-structure catalyst. Chiang Mai J. Sci. 35(1), 150–155 (2008)
go back to reference Boudart, M.: Turnover rates in heterogeneous catalysis. Chem. Rev. 95(3), 661–666 (1995)CrossRef Boudart, M.: Turnover rates in heterogeneous catalysis. Chem. Rev. 95(3), 661–666 (1995)CrossRef
go back to reference Breitkopf, C.: Habilitationsschrift. Universität Leipzig, Leipzig (2006) Breitkopf, C.: Habilitationsschrift. Universität Leipzig, Leipzig (2006)
go back to reference Breitkopf, C., Papp, H.: Deactivation of sulfated zirconia catalysts with n-butane studied by transient experiments. In: Proceeding of 1st International Conference on Diffusion in Solids and Liquids DSL-2005 Aveiro Portugal 6.–8. Juli, S. 233–240. (2005) Breitkopf, C., Papp, H.: Deactivation of sulfated zirconia catalysts with n-butane studied by transient experiments. In: Proceeding of 1st International Conference on Diffusion in Solids and Liquids DSL-2005 Aveiro Portugal 6.–8. Juli, S. 233–240. (2005)
go back to reference Breitkopf, C., Suprun, W., Papp, H.: Transient study of 1-Butene conversion over TiO2/VOx catalysts. DGMK Tagungsbericht. Proceedings of the DGMK-Conference „C4/C5-Hydrocarbons: Routes to Higher Value-Added Products“, 281–288 (2004) Breitkopf, C., Suprun, W., Papp, H.: Transient study of 1-Butene conversion over TiO2/VOx catalysts. DGMK Tagungsbericht. Proceedings of the DGMK-Conference „C4/C5-Hydrocarbons: Routes to Higher Value-Added Products“, 281–288 (2004)
go back to reference Breitkopf, C., Papp, H., Li, X., Olindo, R., Lercher, J.A., Lloyd, R., Wrabetz, S., Jentoft, F.C., Meinel, K., Forster, S., Schindler, K.M., Neddermeyer, H., Widdra, W., Hofmann, A., Sauer, J.: Activation and isomerization of n-butane on sulfated zirconia model systems – an integrated study across the materials and pressure gaps. Phys. Chem. Chem. Phys. 9(27), 3600–3618 (2007). https://doi.org/10.1039/b701854aCrossRefPubMed Breitkopf, C., Papp, H., Li, X., Olindo, R., Lercher, J.A., Lloyd, R., Wrabetz, S., Jentoft, F.C., Meinel, K., Forster, S., Schindler, K.M., Neddermeyer, H., Widdra, W., Hofmann, A., Sauer, J.: Activation and isomerization of n-butane on sulfated zirconia model systems – an integrated study across the materials and pressure gaps. Phys. Chem. Chem. Phys. 9(27), 3600–3618 (2007). https://​doi.​org/​10.​1039/​b701854aCrossRefPubMed
go back to reference Burch, R.: The investigation of mechanisms in environmental catalysis using time-resolved methods. Top. Catal. 24(1–4), 97–102 (2003)CrossRef Burch, R.: The investigation of mechanisms in environmental catalysis using time-resolved methods. Top. Catal. 24(1–4), 97–102 (2003)CrossRef
go back to reference Chen, S.: Dissertation PhD. Washington University, Saint Louis (1996) Chen, S.: Dissertation PhD. Washington University, Saint Louis (1996)
go back to reference Colaris, A.H.J., Hoebink, J.H.B.J., Schouten, J.C.: CO oxidation over a supported Pt catalyst: transient kinetics using temporal analysis of products (TAP). React. Kinet. Dev. Catal. Process 122, 93–100 (1999)CrossRef Colaris, A.H.J., Hoebink, J.H.B.J., Schouten, J.C.: CO oxidation over a supported Pt catalyst: transient kinetics using temporal analysis of products (TAP). React. Kinet. Dev. Catal. Process 122, 93–100 (1999)CrossRef
go back to reference Fierro, V., Izquierdo, M.T., Schuurman, Y., Rubio, B., Mirodatos, C.: A novel approach for characterising carbon catalysts by TAP experiments. Charact. Porous. Solids VI 144, 255–260 (2002a) Fierro, V., Izquierdo, M.T., Schuurman, Y., Rubio, B., Mirodatos, C.: A novel approach for characterising carbon catalysts by TAP experiments. Charact. Porous. Solids VI 144, 255–260 (2002a)
go back to reference Fierro, V., Schuurman, Y., Mirodatos, C., Duplan, J.L., Verstraete, J.: Study of the cracking reaction of linear and branched hexanes under protolytic conditions by non-stationary kinetics. Chem. Eng. J. 90(1–2)., PII S1385–8947(02)00075–X) (2002b). https://doi.org/10.1016/S1385-8947(02)00075-X Fierro, V., Schuurman, Y., Mirodatos, C., Duplan, J.L., Verstraete, J.: Study of the cracking reaction of linear and branched hexanes under protolytic conditions by non-stationary kinetics. Chem. Eng. J. 90(1–2)., PII S1385–8947(02)00075–X) (2002b). https://​doi.​org/​10.​1016/​S1385-8947(02)00075-X
go back to reference Gleaves, J.T., Centi, G.: The reaction-mechanism of alkane selective oxidation on vanadyl pyrophosphate catalysts – features gleaned from TAP reactor transient-response studies. Catal. Today 16(1), 69–78 (1993)CrossRef Gleaves, J.T., Centi, G.: The reaction-mechanism of alkane selective oxidation on vanadyl pyrophosphate catalysts – features gleaned from TAP reactor transient-response studies. Catal. Today 16(1), 69–78 (1993)CrossRef
go back to reference Hu, R.R., Cheng, Y., Ding, Y.L., Xie, L.Y., Wang, D.Z.: A TAP study of CO adsorption on Ag-doped manganese oxide octahedral molecular sieve. Acta Chim. Sin. 65(18), 2001–2006 (2007a) Hu, R.R., Cheng, Y., Ding, Y.L., Xie, L.Y., Wang, D.Z.: A TAP study of CO adsorption on Ag-doped manganese oxide octahedral molecular sieve. Acta Chim. Sin. 65(18), 2001–2006 (2007a)
go back to reference Huinink, J.P., Hoebink, J.H.B.J., Marin, G.B.: Pulse experiments over catalyst beds: a window of measurable reaction rate coefficients. Can. J. Chem. Eng. 74(5), 580–585 (1996)CrossRef Huinink, J.P., Hoebink, J.H.B.J., Marin, G.B.: Pulse experiments over catalyst beds: a window of measurable reaction rate coefficients. Can. J. Chem. Eng. 74(5), 580–585 (1996)CrossRef
go back to reference Imbihl, R., Scheibe, A., Zeng, Y.F., Gunther, S., Kraehnert, R., Kondratenko, V.A., Baerns, M., Offermans, W.K., Jansen, A.P.J., van Santen, R.A.: Catalytic ammonia oxidation on platinum: mechanism and catalyst restructuring at high and low pressure. Phys. Chem. Chem. Phys. 9(27), 3522–3540 (2007). https://doi.org/10.1039/b700866jCrossRefPubMed Imbihl, R., Scheibe, A., Zeng, Y.F., Gunther, S., Kraehnert, R., Kondratenko, V.A., Baerns, M., Offermans, W.K., Jansen, A.P.J., van Santen, R.A.: Catalytic ammonia oxidation on platinum: mechanism and catalyst restructuring at high and low pressure. Phys. Chem. Chem. Phys. 9(27), 3522–3540 (2007). https://​doi.​org/​10.​1039/​b700866jCrossRefPubMed
go back to reference Jentoft, F.C.: Habilitationsschrift. Humboldt-Universität zu Berlin, Berlin (2005) Jentoft, F.C.: Habilitationsschrift. Humboldt-Universität zu Berlin, Berlin (2005)
go back to reference Kartheuser, B., Hodnett, B.K., Zanthoff, H., Baerns, M.: Transient experiments on the selective oxidation of methane to formaldehyde over V2O5/SiO2 studied in the temporal-analysis-of-products reactor. Catal. Lett. 21(3–4), 209–214 (1993). https://doi.org/10.1007/BF00769472CrossRef Kartheuser, B., Hodnett, B.K., Zanthoff, H., Baerns, M.: Transient experiments on the selective oxidation of methane to formaldehyde over V2O5/SiO2 studied in the temporal-analysis-of-products reactor. Catal. Lett. 21(3–4), 209–214 (1993). https://​doi.​org/​10.​1007/​BF00769472CrossRef
go back to reference Keil, F.: Diffusion und Chemische Reaktionen in der Gas/Feststoff-Katalyse, S. 281. Springer, Berlin-Heidelberg (1999)CrossRef Keil, F.: Diffusion und Chemische Reaktionen in der Gas/Feststoff-Katalyse, S. 281. Springer, Berlin-Heidelberg (1999)CrossRef
go back to reference Keipert, O.P., Baerns, M.: Interaction of C2-C6 hydrocarbons with surfaces of H-ZSM-5 and Ga-H-ZSM-5 zeolites. Zeolites Relat. Microporous Mater. State Art. 1994(84), 1757–1764 (1994) Keipert, O.P., Baerns, M.: Interaction of C2-C6 hydrocarbons with surfaces of H-ZSM-5 and Ga-H-ZSM-5 zeolites. Zeolites Relat. Microporous Mater. State Art. 1994(84), 1757–1764 (1994)
go back to reference Li, X., Nagaoka, K., Simon, L.J., Lercher, J.A., Wrabetz, S., Jentoft, F.C., Breitkopf, C., Matysik, S., Papp, H.: Interaction between sulfated zirconia and alkanes: prerequisites for active sites – formation and stability of reaction intermediates. J. Catal. 230, 214–225 (2005)CrossRef Li, X., Nagaoka, K., Simon, L.J., Lercher, J.A., Wrabetz, S., Jentoft, F.C., Breitkopf, C., Matysik, S., Papp, H.: Interaction between sulfated zirconia and alkanes: prerequisites for active sites – formation and stability of reaction intermediates. J. Catal. 230, 214–225 (2005)CrossRef
go back to reference Mirodatos, C.: How transient kinetics may unravel methane activation mechanisms. Nat. Gas Convers. V 119, 99–106 (1998) Mirodatos, C.: How transient kinetics may unravel methane activation mechanisms. Nat. Gas Convers. V 119, 99–106 (1998)
go back to reference Morterra, C., Cerrato, G.: Titrating surface acidity of sulfated zirconia catalysts: is the adsorption of pyridine a suitable probe? From Phys. Chem. Chem. Phys. 1(11), 2825–2831 (1999)CrossRef Morterra, C., Cerrato, G.: Titrating surface acidity of sulfated zirconia catalysts: is the adsorption of pyridine a suitable probe? From Phys. Chem. Chem. Phys. 1(11), 2825–2831 (1999)CrossRef
go back to reference Müller-Erlwein, E.: Chemische Reaktionstechnik. Teubner, Stuttgart/Leipzig (1998) Müller-Erlwein, E.: Chemische Reaktionstechnik. Teubner, Stuttgart/Leipzig (1998)
go back to reference Nijhuis, T.A., van den Broeke, L.J.P., Linders, M.J.G., Makee, M., Kapteijn, F., Moulijn, J.A.: Modeling of the transient sorption and diffusion processes in microporous materials at low pressure. Catal. Tod. 53(2), 189–205 (1999a)CrossRef Nijhuis, T.A., van den Broeke, L.J.P., Linders, M.J.G., Makee, M., Kapteijn, F., Moulijn, J.A.: Modeling of the transient sorption and diffusion processes in microporous materials at low pressure. Catal. Tod. 53(2), 189–205 (1999a)CrossRef
go back to reference Phanawadee, P.: Dissertation PhD, Washington University, Saint Louis (1997) Phanawadee, P.: Dissertation PhD, Washington University, Saint Louis (1997)
go back to reference Phanawadee, P., Shekhtman, S.O., Jarungmanorom, C., Yablonsky, G.S., Gleaves, J.T.: Uniformity in a thin-zone multi-pulse TAP experiment: numerical analysis. Chem. Eng. J. 58(11), 2215–2227 (2003)CrossRef Phanawadee, P., Shekhtman, S.O., Jarungmanorom, C., Yablonsky, G.S., Gleaves, J.T.: Uniformity in a thin-zone multi-pulse TAP experiment: numerical analysis. Chem. Eng. J. 58(11), 2215–2227 (2003)CrossRef
go back to reference Redekop, E.A., Yablonsky, G.S., Galvita, V.V., Constaes, D., Fushimi, R., Gleaves, J.T., Marin, G.B.: Momentary equilibrium in transient kinetics and its application for estimating the concentration of catalytic sites. Ind. Eng. Chem. Res. 52(44), 15417–15427 (2013). https://doi.org/10.1021/ie400677bCrossRef Redekop, E.A., Yablonsky, G.S., Galvita, V.V., Constaes, D., Fushimi, R., Gleaves, J.T., Marin, G.B.: Momentary equilibrium in transient kinetics and its application for estimating the concentration of catalytic sites. Ind. Eng. Chem. Res. 52(44), 15417–15427 (2013). https://​doi.​org/​10.​1021/​ie400677bCrossRef
go back to reference Teschner, D., Novell-Leruth, G., Farra, R., Knop-Gericke, A., Schlogl, R., Szentmiklosi, L., Hevia, M.G., Soerijanto, H., Schomacker, R., Perez-Ramirez, J., Lopez, N.: In situ surface coverage analysis of RuO2-catalysed HCl oxidation reveals the entropic origin of compensation in heterogeneous catalysis. Nat. Chem. 4(9), 739–745 (2012). https://doi.org/10.1038/NCHEM.1411CrossRefPubMed Teschner, D., Novell-Leruth, G., Farra, R., Knop-Gericke, A., Schlogl, R., Szentmiklosi, L., Hevia, M.G., Soerijanto, H., Schomacker, R., Perez-Ramirez, J., Lopez, N.: In situ surface coverage analysis of RuO2-catalysed HCl oxidation reveals the entropic origin of compensation in heterogeneous catalysis. Nat. Chem. 4(9), 739–745 (2012). https://​doi.​org/​10.​1038/​NCHEM.​1411CrossRefPubMed
go back to reference Veen, A.C. van, Zanthoff, H.W., Hinrichsen, O., Muhler, M.: Fixed-bed microreactor for transient kinetic experiments with strongly adsorbing gases under high vacuum conditions. J. Vac. Sci. Technol. A 19(2), 651–655 (2001). DOI https://doi.org/10.1116/1.1344910 Veen, A.C. van, Zanthoff, H.W., Hinrichsen, O., Muhler, M.: Fixed-bed microreactor for transient kinetic experiments with strongly adsorbing gases under high vacuum conditions. J. Vac. Sci. Technol. A 19(2), 651–655 (2001). DOI https://​doi.​org/​10.​1116/​1.​1344910
go back to reference Zanthoff, H.-W., Sananes-Schulz, M., Buchholz, S.A., Baerns, M.: Report of the BMBF Project no. 03D0024C1. Dechema, Bochum (1998) Zanthoff, H.-W., Sananes-Schulz, M., Buchholz, S.A., Baerns, M.: Report of the BMBF Project no. 03D0024C1. Dechema, Bochum (1998)
go back to reference Zheng, X.L., Veith, G.M., Redekop, E., Lo, C.S., Yablonsky, G.S., Gleaves, J.T.: Oxygen and CO adsorption on Au/SiO2 catalysts prepared by magnetron sputtering: the role of oxygen storage. Ind. Eng. Chem. Res. 49(21), 10428–10437 (2010). https://doi.org/10.1021/ie100547fCrossRef Zheng, X.L., Veith, G.M., Redekop, E., Lo, C.S., Yablonsky, G.S., Gleaves, J.T.: Oxygen and CO adsorption on Au/SiO2 catalysts prepared by magnetron sputtering: the role of oxygen storage. Ind. Eng. Chem. Res. 49(21), 10428–10437 (2010). https://​doi.​org/​10.​1021/​ie100547fCrossRef
Metadata
Title
Spezielle labortechnische Reaktoren: TAP-Reaktor
Author
Cornelia Breitkopf
Copyright Year
2020
Publisher
Springer Berlin Heidelberg
DOI
https://doi.org/10.1007/978-3-662-56434-9_47