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2003 | OriginalPaper | Chapter
Spin Transition of 1D, 2D and 3D Iron(II) Complex Polymers The Tug-of-War between Elastic Interaction and a Shock-Absorber Effect
Authors : Petra J. van Koningsbruggen, Matthias Grunert, Peter Weinberger
Published in: Molecular Magnets Recent Highlights
Publisher: Springer Vienna
Included in: Professional Book Archive
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The structures of linear chain Fe(II) spin-crossover compounds of α,β-and α,ω-bis (tetrazol-l-yl)alkane type ligands are described in relation to their magnetic properties. The first threefold interlocked 3-D catenane Fe(II) spin-transition system, [µ-tris(1,4-bis(tetrazol-l-yl)butane-N1,N1′) iron(II)] bis(perchlorate), will be discussed. An analysis is made among the structures and the cooperativity of the spin-crossover behaviour of polynuclear Fe(II) spin-transition materials.