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Supramolecular Hybrid Organic/Inorganic Nanomaterials Based on Metalloporphyrins and Phthalocyanines Read chapter Read first chapter

2016 | OriginalPaper | Chapter

Spirobifluorenyl-Porphyrins and their Derived Polymers for Homogeneous or Heterogeneous Catalysis

Authors : Joëlle Rault-Berthelot, Cyril Poriel

Published in: Electrochemistry of N4 Macrocyclic Metal Complexes

Publisher: Springer International Publishing

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Abstract

Decorating porphyrin cores at their meso positions by one, two or four 9,9′-Spirobifluorenyl (SBF) units is an interesting design strategy to obtain efficient and recyclable heterogeneous catalysts for various chemical reactions. The synthesis of metalloporphyrin polymers (RuIICO, FeIIICl, MnIIICl) is easily performed along anodic oxidation of their related monomers or along copolymerization of their monomers in presence of 9,9′-SBF. The efficiency of this polymerization mainly depends on the number of SBF units around the porphyrin cores and on the nature of the metal ion within the porphyrin ligand. Polymer catalysts in heterogeneous phase appear as efficient as the monomer catalysts in homogeneous phase. The main interest of catalysis with polymers is that they can be very easily separated from the reaction medium after reaction by a simple filtration and that they can be washed and reused without loss of their activity. The recyclability of metalloporphyrins polymers is of high interest in the field of catalysis. For asymmetric catalysis, recyclable chiral polymetalloporphyrins based on the SBF scaffold are also of high interest. The chirality may be introduced either by the dimethanoanthracenyl (DMA) units linked to SBF units (acting as electropolymerizable entities) or by a chiral SBF fragment which can be electropolymerizable. Compared to other porphyrin immobilization processes, anodic oxidation is hence a relatively easy tool as the polymer is directly obtained on the anode surface, easily separated under its insoluble form and directly usable as recyclable catalyst for many chemical reactions.

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previous chapter Electrochemical Oxidation and Electroanalysis of Organic Pollutants on Electrodes Modified with Metallophthalocyanines (MPcs)
next chapter Electrosynthesis of Oligo- and Polyporphyrins Based on Oxidative Coupling of Macrocycles
Footnotes
1
In the αα atropisomer, the substituents attached to the meso position are situated on the same side of the porphyrin plane wheras in the αβ atropisomer, the substituents attached to the meso position are situated on the opposite sides of the porphyrin plane.
 
2
No X-Ray structure is nevertheless reported for spirobifluorenyl-porphyrins which could confirme a possible deformation of the macrocycle.
 
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Metadata
Title
Spirobifluorenyl-Porphyrins and their Derived Polymers for Homogeneous or Heterogeneous Catalysis
Authors
Joëlle Rault-Berthelot
Cyril Poriel
Copyright Year
2016
Book
Electrochemistry of N4 Macrocyclic Metal Complexes

Print ISBN: 978-3-319-31330-6

Electronic ISBN: 978-3-319-31332-0

Copyright Year: 2016

DOI
https://doi.org/10.1007/978-3-319-31332-0_9