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2014 | OriginalPaper | Chapter

Structural and Luminescent Properties of Carbonized Silicon Oxide Thin Layers

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Abstract

A critical review of structural and white light emission properties of carbonized silicon oxide thin layers (SiOC) is presented. Methods of synthesis of the SiOC layers, effects of thermal treatments, spectral properties and degradation of photoluminescence are analyzed. SiOC layers were synthesized by two methods: (1) magnetron deposition of a-SiC:H thin films on Si wafer followed by oxidation in flow oxygen or water vapor at temperature of 450–600 °C; (2) thermal treatment of porous silicon layer (grown on p-type Si wafer by anodization in HF/C2H5OH solution) in flow of acetylene (850–1050 °C) followed by oxidation in flow of water vapor (600–850 °C). Working hypothesis is that main contribution in broad band photoluminescence (400–700 nm) of the materials originates from carbon nano-clusters. Hence, original experimental data and other published data are discussed in frame of this working hypothesis.

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Metadata
Title
Structural and Luminescent Properties of Carbonized Silicon Oxide Thin Layers
Author
Andrii V. Vasin
Copyright Year
2014
DOI
https://doi.org/10.1007/978-3-319-08804-4_14