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Published in: Journal of Materials Science: Materials in Electronics 3/2017

11-10-2016

Structural, electrical and magnetic properties of Mn3O4/MgO nanocomposite

Authors: K. Tamizh Selvi, K. Alamelu Mangai, M. Priya, P. Suresh Kumar, M. Rathnakumari

Published in: Journal of Materials Science: Materials in Electronics | Issue 3/2017

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Abstract

The present paper deals with the synthesis of Mn3O4/MgO nanocomposite through a simple sol–gel route and their electrical and magnetic properties are discussed for electrode applications. The grain size and particle morphology of the synthesized nanocomposite are characterized using XRD and HRSEM. The elemental compositions of the synthesized samples were analyzed using EDAX spectra. The dielectric constant, dielectric loss and AC conductivity of the synthesized samples were studied in the frequency range of 100 Hz–5 MHz at different temperatures (303–573 K) using impedance spectra. The activation energy was calculated using Arrhenius plot. The vibrating sample magnetometry (VSM) study shows that the nanocomposites are found to be paramagnetic at room temperature.

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Literature
1.
go back to reference R. Tummala, R.K. Guduru, P.S. Mohanty, Nanostructured Co3O4 electrodes for supercapacitor applications from plasma spray technique. J. Power Sources 209(1), 44–51 (2012)CrossRef R. Tummala, R.K. Guduru, P.S. Mohanty, Nanostructured Co3O4 electrodes for supercapacitor applications from plasma spray technique. J. Power Sources 209(1), 44–51 (2012)CrossRef
2.
go back to reference R. Kohler, J. Proell, S. Ulrich, M. Przybylski, W. Pfleging, in Laser processing of SnO2 electrode materials for manufacturing of 3D micro batteries. Proceedings of SPIE 7921, Laser-based Micro- and Nanopackaging and Assembly V, 2011 R. Kohler, J. Proell, S. Ulrich, M. Przybylski, W. Pfleging, in Laser processing of SnO2 electrode materials for manufacturing of 3D micro batteries. Proceedings of SPIE 7921, Laser-based Micro- and Nanopackaging and Assembly V, 2011
3.
go back to reference W. Zhou, L. Ge, Z.-G. Chen, F. Liang, X. Hong-Yi, J. Motuzas, A. Julbe, Z. Zhu, Amorphous iron oxide decorated 3d heterostructured electrode for highly efficient oxygen reduction. Chem. Mater. 23(18), 4193–4198 (2011)CrossRef W. Zhou, L. Ge, Z.-G. Chen, F. Liang, X. Hong-Yi, J. Motuzas, A. Julbe, Z. Zhu, Amorphous iron oxide decorated 3d heterostructured electrode for highly efficient oxygen reduction. Chem. Mater. 23(18), 4193–4198 (2011)CrossRef
4.
go back to reference D. Chen, X. Xiong, B. Zhao, M.A. Mahmoud, M.A. El-Sayed, M. Liu, Probing structural evolution and charge storage mechanism of NiO2Hx electrode materials using in Operando Resonance Raman Spectroscopy. Adv. Sci. (2016). doi:10.1002/advs.201500433 D. Chen, X. Xiong, B. Zhao, M.A. Mahmoud, M.A. El-Sayed, M. Liu, Probing structural evolution and charge storage mechanism of NiO2Hx electrode materials using in Operando Resonance Raman Spectroscopy. Adv. Sci. (2016). doi:10.​1002/​advs.​201500433
5.
go back to reference Z. He, L. Dai, S. Liu, L. Wang, Chuanchang LiMn3O4 anchored on carbon nanotubes as an electrode reaction catalyst of V(IV)/V(V) couple for vanadium redox flow batteries. Electrochim. Acta 176(10), 1434–1440 (2015)CrossRef Z. He, L. Dai, S. Liu, L. Wang, Chuanchang LiMn3O4 anchored on carbon nanotubes as an electrode reaction catalyst of V(IV)/V(V) couple for vanadium redox flow batteries. Electrochim. Acta 176(10), 1434–1440 (2015)CrossRef
6.
go back to reference V. Subramanian, S.C. Hall, P.H. Smith, B. Rambabu, Mesoporous anhydrous RuO2 as a supercapacitor electrode material. Solid State Ion. 175(1–4), 511–515 (2004)CrossRef V. Subramanian, S.C. Hall, P.H. Smith, B. Rambabu, Mesoporous anhydrous RuO2 as a supercapacitor electrode material. Solid State Ion. 175(1–4), 511–515 (2004)CrossRef
7.
go back to reference A.-M. Gurban, D. Burtan, L. Rotariu, C. Bala, Manganese oxide based screen-printed sensor for xenoestrogens detection. Sens. Actuators B Chem. 210, 273–280 (2015)CrossRef A.-M. Gurban, D. Burtan, L. Rotariu, C. Bala, Manganese oxide based screen-printed sensor for xenoestrogens detection. Sens. Actuators B Chem. 210, 273–280 (2015)CrossRef
8.
go back to reference S. Ibrahim, T. Charinpanitkul, E. Kobatake, M. Sriyudthsak, Nanowires nickel oxide and nanospherical manganese oxide synthesized via low temperature hydrothermal technique for hydrogen peroxide sensor. J. Chem. 2016, 1–6 (2016) S. Ibrahim, T. Charinpanitkul, E. Kobatake, M. Sriyudthsak, Nanowires nickel oxide and nanospherical manganese oxide synthesized via low temperature hydrothermal technique for hydrogen peroxide sensor. J. Chem. 2016, 1–6 (2016)
9.
go back to reference C.-H. Kuo, I.M. Mosa, A.S. Poyraz, S. Biswas, A.M. El-Sawy, W. Song, Z. Luo, Sheng-Yu. Chen, J.F. Rusling, J. He, S.L. Suib, Robust mesoporous manganese oxide catalysts for water oxidation. ACS Catal. 5(3), 1693–1699 (2015)CrossRef C.-H. Kuo, I.M. Mosa, A.S. Poyraz, S. Biswas, A.M. El-Sawy, W. Song, Z. Luo, Sheng-Yu. Chen, J.F. Rusling, J. He, S.L. Suib, Robust mesoporous manganese oxide catalysts for water oxidation. ACS Catal. 5(3), 1693–1699 (2015)CrossRef
10.
go back to reference S. Thotaa, B. Prasada, J. Kuma, Formation and magnetic behaviour of manganese oxide nanoparticles. Mater. Sci. Eng. B 167, 153–160 (2010)CrossRef S. Thotaa, B. Prasada, J. Kuma, Formation and magnetic behaviour of manganese oxide nanoparticles. Mater. Sci. Eng. B 167, 153–160 (2010)CrossRef
11.
go back to reference A.E. Beeran, F.B. Fernandez, S.S. Nazeer, R.S. Jayasree, A. John, S. Anil, S. Vellappally, A.A. Al Kheraif, P.R. Varma, Multifunctional nano manganese ferrite ferrofluid for efficient theranostic application. Colloids Surf. B Biointerfaces 1(136), 1089–1097 (2015)CrossRef A.E. Beeran, F.B. Fernandez, S.S. Nazeer, R.S. Jayasree, A. John, S. Anil, S. Vellappally, A.A. Al Kheraif, P.R. Varma, Multifunctional nano manganese ferrite ferrofluid for efficient theranostic application. Colloids Surf. B Biointerfaces 1(136), 1089–1097 (2015)CrossRef
12.
go back to reference J. Zhu, R. Duan, S. Zhang, N. Jiang, Y. Zhang, J. Zhu, The application of graphene in lithium ion battery electrode materials. Springer Plus 3, 585 (2014)CrossRef J. Zhu, R. Duan, S. Zhang, N. Jiang, Y. Zhang, J. Zhu, The application of graphene in lithium ion battery electrode materials. Springer Plus 3, 585 (2014)CrossRef
13.
go back to reference C. Photiphitak, P. Rakkwamsuk, P. Muthitamongkol, C. Thanachayanont, Performance enhancement of dye-sensitized solar cells by MgO Coating on TiO2 electrodes. Int. J. Chem. Mol. Nucl. Mater. Metall. Eng. 6(5), 463–467 (2012) C. Photiphitak, P. Rakkwamsuk, P. Muthitamongkol, C. Thanachayanont, Performance enhancement of dye-sensitized solar cells by MgO Coating on TiO2 electrodes. Int. J. Chem. Mol. Nucl. Mater. Metall. Eng. 6(5), 463–467 (2012)
14.
go back to reference S.-G. Hwang, J.-E. Hong, G.-O. Kim, H.M. Jeong, K.S. Ryu, Graphene anchored with NiO–MnO2 nanocomposites for use as an electrode material in supercapacitors. ECS Solid State Lett. 2(1), M8–M11 (2013)CrossRef S.-G. Hwang, J.-E. Hong, G.-O. Kim, H.M. Jeong, K.S. Ryu, Graphene anchored with NiO–MnO2 nanocomposites for use as an electrode material in supercapacitors. ECS Solid State Lett. 2(1), M8–M11 (2013)CrossRef
15.
go back to reference N. Thapliyal, N.S.E. Osman, H. Patel, R. Karpoormath, R.N. Goyal, T. Moyo, R. Patel, NiO–ZrO2 nanocomposite modified electrode for the sensitive and selective determination of efavirenz, an anti-HIV drug. RSC Adv. 5, 40057–40064 (2015)CrossRef N. Thapliyal, N.S.E. Osman, H. Patel, R. Karpoormath, R.N. Goyal, T. Moyo, R. Patel, NiO–ZrO2 nanocomposite modified electrode for the sensitive and selective determination of efavirenz, an anti-HIV drug. RSC Adv. 5, 40057–40064 (2015)CrossRef
16.
go back to reference Q. Zhang, Y. Liu, Y. Duan, F. Nianqing, Q. Liu, Y. Fang, Q. Sun, Y. Lin, Mn3O4/graphene composite as counter electrode in dye-sensitized solar cells. RSC Adv. 4, 15091–15097 (2014)CrossRef Q. Zhang, Y. Liu, Y. Duan, F. Nianqing, Q. Liu, Y. Fang, Q. Sun, Y. Lin, Mn3O4/graphene composite as counter electrode in dye-sensitized solar cells. RSC Adv. 4, 15091–15097 (2014)CrossRef
17.
go back to reference Y. Yamashita, N. Yamamoto, K. Itsumi, Y. Hosono, Effects of manganese oxides/gold composite electrode on piezoelectric properties of lead magnesium niobate titanate single crystal. Jpn. J. Appl. Phys. 50(9S2), 09NC05-1–09NC05-3 (2011) Y. Yamashita, N. Yamamoto, K. Itsumi, Y. Hosono, Effects of manganese oxides/gold composite electrode on piezoelectric properties of lead magnesium niobate titanate single crystal. Jpn. J. Appl. Phys. 50(9S2), 09NC05-1–09NC05-3 (2011)
18.
go back to reference L. Jianming, C. Xiaomei, RuO2/MnO2 composite materials for high-performance supercapacitor electrodes. J. Semicond. 36(8), 083006-1–083006-5 (2015) L. Jianming, C. Xiaomei, RuO2/MnO2 composite materials for high-performance supercapacitor electrodes. J. Semicond. 36(8), 083006-1–083006-5 (2015)
19.
go back to reference D.K. Fork, F.A. Ponce, J.C. Tramontana, T.H. Geballe, Epitaxial MgO on Si(001) for Y–Ba–Cu–O thin-film growth by pulsed laser deposition. Appl. Phys. Lett. 58, 2294 (1991)CrossRef D.K. Fork, F.A. Ponce, J.C. Tramontana, T.H. Geballe, Epitaxial MgO on Si(001) for Y–Ba–Cu–O thin-film growth by pulsed laser deposition. Appl. Phys. Lett. 58, 2294 (1991)CrossRef
20.
go back to reference S.K. Shukla, G.K. Parashar, A.P. Mishra, P. Puneet, B.C. Yadav, R.K. Shukla, L.M. Bali, G.C. Dubey, Nano-like magnesium oxide films and its significance in optical fiber humidity sensor. Sens. Actuators B Chem. 98(1), 5–11 (2004)CrossRef S.K. Shukla, G.K. Parashar, A.P. Mishra, P. Puneet, B.C. Yadav, R.K. Shukla, L.M. Bali, G.C. Dubey, Nano-like magnesium oxide films and its significance in optical fiber humidity sensor. Sens. Actuators B Chem. 98(1), 5–11 (2004)CrossRef
21.
go back to reference A. Umar, M.M. Rahman, Y.-B. Hahn, MgO polyhedral nanocages and nanocrystals based glucose biosensor. Electrochem. Commun. 11, 1353–1357 (2009)CrossRef A. Umar, M.M. Rahman, Y.-B. Hahn, MgO polyhedral nanocages and nanocrystals based glucose biosensor. Electrochem. Commun. 11, 1353–1357 (2009)CrossRef
22.
go back to reference H.M. Ali, M.D. Azhar, M. Saleem, Q.S. Saeed, A. Saieed, Heat transfer enhancement of car radiator using aqua based magnesium oxide nanofluids. Therm. Sci. Y 19(6), 2039–2048 (2015)CrossRef H.M. Ali, M.D. Azhar, M. Saleem, Q.S. Saeed, A. Saieed, Heat transfer enhancement of car radiator using aqua based magnesium oxide nanofluids. Therm. Sci. Y 19(6), 2039–2048 (2015)CrossRef
23.
go back to reference J. Zang, H. Qian, Z. Wei, Y. Cao, M. Zheng, Q. Dong, Reduced graphene oxide supported MnO nanoparticles with excellent lithium storage performance. Electrochim. Acta 118, 112–117 (2014)CrossRef J. Zang, H. Qian, Z. Wei, Y. Cao, M. Zheng, Q. Dong, Reduced graphene oxide supported MnO nanoparticles with excellent lithium storage performance. Electrochim. Acta 118, 112–117 (2014)CrossRef
24.
go back to reference S.-D. Kim, B.-J. Kim, J.-H. Yoon, J.-S. Kim, Design, fabrication and characterization of a low-power gas sensor with high sensitivity to CO gas. J. Korean Phys. Soc. 51, 2069–2076 (2007)CrossRef S.-D. Kim, B.-J. Kim, J.-H. Yoon, J.-S. Kim, Design, fabrication and characterization of a low-power gas sensor with high sensitivity to CO gas. J. Korean Phys. Soc. 51, 2069–2076 (2007)CrossRef
25.
go back to reference S.T. Myung, S. Komaba, N. Kumagai, Hydrothermal synthesis and electrochemical behavior of orthorhombic LiMnO2. Electrochim. Acta 47(20), 3287–3295 (2002)CrossRef S.T. Myung, S. Komaba, N. Kumagai, Hydrothermal synthesis and electrochemical behavior of orthorhombic LiMnO2. Electrochim. Acta 47(20), 3287–3295 (2002)CrossRef
26.
go back to reference K.T. Selvi, K. Alamelumangai, M. Priya, M. Rathnakumari, P.S. Kumar, S. Sagadevan, Studies on synthesis, structural, surface morphological and electrical properties of Pr6O11–MgO nanocomposite. J. Mater. Sci. Mater. Electron. 27(6), 6457–6463 (2016)CrossRef K.T. Selvi, K. Alamelumangai, M. Priya, M. Rathnakumari, P.S. Kumar, S. Sagadevan, Studies on synthesis, structural, surface morphological and electrical properties of Pr6O11–MgO nanocomposite. J. Mater. Sci. Mater. Electron. 27(6), 6457–6463 (2016)CrossRef
27.
go back to reference A. Ashok, T. Somaiah, D. Ravinder, C. Venkateshwarlu, C. Reddy, K. Rao, M. Prasad, Electrical properties of cadmium substitution in nickel ferrites. World J. Condens. Matter Phys. 2, 257–266 (2012)CrossRef A. Ashok, T. Somaiah, D. Ravinder, C. Venkateshwarlu, C. Reddy, K. Rao, M. Prasad, Electrical properties of cadmium substitution in nickel ferrites. World J. Condens. Matter Phys. 2, 257–266 (2012)CrossRef
28.
go back to reference G.N.S. Vijayakumar, S. Devashankar, M. Rathnakumari, P. Sureshkumar, Synthesis of electrospun ZnO/CuO nanocomposite fibers and their dielectric and non-linear optic studies. J. Alloy. Compd. 507, 225–229 (2010)CrossRef G.N.S. Vijayakumar, S. Devashankar, M. Rathnakumari, P. Sureshkumar, Synthesis of electrospun ZnO/CuO nanocomposite fibers and their dielectric and non-linear optic studies. J. Alloy. Compd. 507, 225–229 (2010)CrossRef
29.
go back to reference B.K. Barick, R.N.P. Choudhary, D.K. Pradhan, Phase transition and electrical properties of lanthanum-modified sodium bismuth titanate. Mater. Chem. Phys. 132, 1007–1014 (2012)CrossRef B.K. Barick, R.N.P. Choudhary, D.K. Pradhan, Phase transition and electrical properties of lanthanum-modified sodium bismuth titanate. Mater. Chem. Phys. 132, 1007–1014 (2012)CrossRef
30.
go back to reference C.J. Kevane, Oxygen vacancies and electrical conduction in metal oxides. Phys. Rev. 133, A1431 (1964)CrossRef C.J. Kevane, Oxygen vacancies and electrical conduction in metal oxides. Phys. Rev. 133, A1431 (1964)CrossRef
31.
go back to reference U. Dash, S. Sahoo, S.K.S. Paritosh Chaudhuri, K.P. Parashar, Electrical properties of bulk and nano Li2TiO3 ceramics: a comparative study. J. Adv. Ceram. 3(2), 89–97 (2014)CrossRef U. Dash, S. Sahoo, S.K.S. Paritosh Chaudhuri, K.P. Parashar, Electrical properties of bulk and nano Li2TiO3 ceramics: a comparative study. J. Adv. Ceram. 3(2), 89–97 (2014)CrossRef
32.
go back to reference S.C. Chaudhari, R.N. Patil, Dielectric behavior and A. C. conductivity in Cu–Ti ferrites. Adv. Appl. Sci. Res. 3(6), 3848–3854 (2012) S.C. Chaudhari, R.N. Patil, Dielectric behavior and A. C. conductivity in Cu–Ti ferrites. Adv. Appl. Sci. Res. 3(6), 3848–3854 (2012)
33.
go back to reference A. Shukla, R.N.P. Choudhary, Study of electrical properties of La3/Mn4-modified PbTiO3 nanoceramics. J. Mater. Sci. 47, 5074–5085 (2012)CrossRef A. Shukla, R.N.P. Choudhary, Study of electrical properties of La3/Mn4-modified PbTiO3 nanoceramics. J. Mater. Sci. 47, 5074–5085 (2012)CrossRef
34.
go back to reference M. Nasir, M. Zulfequar, Estimation the density of localized state glassy Se100–xZnx thin films by using space charge limited conduction measurement. New J. Glass Ceram. 2(2), (2012) M. Nasir, M. Zulfequar, Estimation the density of localized state glassy Se100–xZnx thin films by using space charge limited conduction measurement. New J. Glass Ceram. 2(2), (2012)
35.
go back to reference R. Regmi, R. Tackett, G. Lawes, Suppression of low-temperature magnetic states in Mn3O4 nanoparticles. J. Magn. Magn. Mater. 321, 2296 (2009)CrossRef R. Regmi, R. Tackett, G. Lawes, Suppression of low-temperature magnetic states in Mn3O4 nanoparticles. J. Magn. Magn. Mater. 321, 2296 (2009)CrossRef
36.
go back to reference A. Giri, N. Goswami, M. Pal, M.T.Z. Myint, S. Al-Harthi, A. Singha, B. Ghosh, J. Dutta, S.K. Pal, Rational surface modification of Mn3O4 nanoparticles to induce multiple photoluminescence and room temperature ferromagnetism. J. Mater. Chem. C 1, 1885–1895 (2013)CrossRef A. Giri, N. Goswami, M. Pal, M.T.Z. Myint, S. Al-Harthi, A. Singha, B. Ghosh, J. Dutta, S.K. Pal, Rational surface modification of Mn3O4 nanoparticles to induce multiple photoluminescence and room temperature ferromagnetism. J. Mater. Chem. C 1, 1885–1895 (2013)CrossRef
37.
go back to reference S.N. Piramanayagam, T.C. Chong, Developments in Data Storage: Materials Perspective (Wiley, New York, 2011)CrossRef S.N. Piramanayagam, T.C. Chong, Developments in Data Storage: Materials Perspective (Wiley, New York, 2011)CrossRef
Metadata
Title
Structural, electrical and magnetic properties of Mn3O4/MgO nanocomposite
Authors
K. Tamizh Selvi
K. Alamelu Mangai
M. Priya
P. Suresh Kumar
M. Rathnakumari
Publication date
11-10-2016
Publisher
Springer US
Published in
Journal of Materials Science: Materials in Electronics / Issue 3/2017
Print ISSN: 0957-4522
Electronic ISSN: 1573-482X
DOI
https://doi.org/10.1007/s10854-016-5799-0

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