Top

Optical and Quantum Electronics

Published in:

01-01-2024

Structural, optical, and dielectric properties of PVC/ZnMn₂O₄/PbS polymers with and without MWCNTs

Authors: A. M. El-naggar, Zein K. Heiba, A. M. Kamal, Mohamed Bakr Mohamed

Published in: Optical and Quantum Electronics | Issue 1/2024

Activate our intelligent search to find suitable subject content or patents.

search-config

AI-assisted search

Off

Abstract

Polyvinyl chloride ‘PVC’/(1-x)ZnMn₂O₄/xPbS (with and without multiwalled carbon nanotubes, MWCNTs) polymers were formed using solid state reactions and co-precipitation procedures. Rietveld analysis was applied to investigate the structure and microstructure properties of (1-x)ZnMn₂O₄/xPbS fillers. TEM image of the filler displayed a homogenous particle morphology with particle size 10–50 nm. The influence of nanofiller on the optical absorbance, transmittance, reflectance, refractive index, extinction coefficient, dielectric constant, and energy loss functions data of PVC polymer, with and without addition of MWCNTs, was explored. In general, the absorbance of doped PVC enhanced, and transmittance dropped. The direct/indirect optical bandgap energies E_g of PVC (4.3 and 4.09 eV) reduced attaining the lowest values (3.6 and 2.32 eV) upon loading with x = 0.1 nanofiller/MWCNTs. Also, the emitted fluorescence spectra (FL) greatly reduced; pristine PVC emitted a blue color while doped PVC emitted a blue-orange color. The effect of frequency and fillers on the dielectric constant, electric moduli, ac conductivity and energy density of all polymers was studied.

previous article Quantum hyper-entangled system with multiple qubits based on spontaneous parametric down-conversion and birefringence effect

next article Optimization and performance investigation of 1-Toffoli gate quantum full adders for spin-torque-based n-qubit architecture

Dont have a licence yet? Then find out more about our products and how to get one now:

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

über 67.000 Bücher
über 390 Zeitschriften

aus folgenden Fachgebieten:

Automobil + Motoren
Bauwesen + Immobilien
Business IT + Informatik
Elektrotechnik + Elektronik
Energie + Nachhaltigkeit
Maschinenbau + Werkstoffe

Jetzt Wissensvorsprung sichern!

inform now

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

über 102.000 Bücher
über 537 Zeitschriften

aus folgenden Fachgebieten:

Automobil + Motoren
Bauwesen + Immobilien
Business IT + Informatik
Elektrotechnik + Elektronik
Energie + Nachhaltigkeit
Finance + Banking
Management + Führung
Marketing + Vertrieb
Maschinenbau + Werkstoffe
Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

inform now

Springer Professional "Wirtschaft"

Online-Abonnement

Mit Springer Professional "Wirtschaft" erhalten Sie Zugriff auf:

über 67.000 Bücher
über 340 Zeitschriften

aus folgenden Fachgebieten:

Bauwesen + Immobilien
Business IT + Informatik
Finance + Banking
Management + Führung
Marketing + Vertrieb
Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

inform now

Abdelhamied, M.M., Abdelreheem, A.M., Atta, A., Plastics: Influence of ion beam and silver nanoparticles on dielectric properties of flexible PVA/PANI Polymer composite films. Rubber and Composites. 51(1), 1 (2022)ADS

Abdel Maksoud, M.I.A., Bekhit, M., Waly c, A.L., Awed, A.S.: Optical and dielectric properties of polymer nanocomposite based on PVC matrix and Cu/Cu2O. Phys. E. 148, 115661 (2023)

Abdulwahid, R.T., Abdullah, O.G., Aziz, S.B., Hussein, S.A., Muhammad, F.F., Yahya, M.Y.: The study of structural and optical properties of PVA:PbO₂ based solid polymer nanocomposites. J. Mater. Sci: Mater. Electron. 27, 12112 (2016)

Abouhaswa, A.S., Taha, T.A.: Tailoring the optical and dielectric properties of PVC/CuO Nanocomposites. Polym. Bull. 77, 600 (2020)

Alghamdi, H.M., Rajeh, A.: Synthesis of CoFe2O4/MWCNTs nanohybrid and its Effect on the Optical, Thermal, and Conductivity of PVA/CMC Composite as an application in Electrochemical devices. J. Inorg. Organomet. Polym Mater. 32(5), 1935–1949 (2022)

Al-Qahtani, S.D., Aljohani, M., Al-bonayan, A.M., Alsharief, H.H., Alrefaee, S.H., Almotairy, A.R.Z.: El-Metwaly, Development of rare-earth doped aluminate embedded into electrospun polyvinyl chloride nanofibers for information encryption. Reactive and Functional Polymers. 188, 105609 (2023)

Aziz, S.B., Ahmed, H.M., Hussein, A.M., Fathulla, A.B., Wsw, R.M., Hussein, R.T.: Tuning the absorption of ultraviolet spectra and optical parameters of aluminum doped PVA based solid polymer composites. J. Mater. Sci. : Mater. Electron. 26, 8022 (2015)

Aziz, S.B.: Modifying poly(Vinyl Alcohol) (PVA) from insulator to small-bandgap polymer: A Novel Approach for Organic Solar cells and Optoelectronic devices. J. Electron. Mater. 45, 736 (2016)ADS

Brunner, A.J.: X-ray diffraction pattern of poly(vinyl chloride). Polym. Lett. 10, 379 (1972)

Chen, Y., Liu, H., Xia, M., Cai, M., Nie, Z., Gao, J.: Green multifunctional PVA composite hydrogel-membrane for the efficient purification of emulsified oil wastewater containing Pb2 + ions. Sci. Total Environ. 856, 159271 (2023)PubMedADS

D’Andrade, B., Forrest, S.R.: Formation of triplet excimers and dimers in amorphous organic thin films and light emitting devices. Chem. Phys. 286(2), 321 (2003)

Ebnalwaleda, A.A., Thabet, A.: Controlling the optical constants of PVC nanocomposite films for optoelectronic applications. J. Synth. Met. 220, 374 (2016)

El–Hachemi, B., Miloud, S., MSabah, T., Souad, O., Zineddine, B., Boubekeur, S.M., Toufik: Halimi, Ouahiba, structural, electrical and optical properties of PVC/ZnTe nanocomposite thin films. Inorg. Organomet. Polym. 31, 3637 (2021)

El-naggar, A.M., Heiba, Z.K., Kamal, A.M., Abd-Elkader, O.H., Lakshminarayana, G., Mohamed, M.B.: Linear and nonlinear optical characteristics of PVA/CMC/PEG blended polymer loaded with ZnS formed at different temperatures. J. Mater. Sci.: Mater. Electron. 34(2), 114 (2023)

El-naggar, A.M., Heiba, Z.K., Mohamed, M.B., Kamal, A.M., Lakshminarayana, G., Abd-Elkader, O.H.: Effect of MnS/ZnS nanocomposite on the structural, linear, and nonlinear optical properties of PVA/CMC blended polymer. Opt. Mater. 128, 112379 (2022)

El-Naggar, A.M., Heiba, Z.K., Kamal, A.M., Abd-Elkader, O.H., Mohamed, M.B.: Structural, optical, and dielectric performance of PVA/PVP/PEG blend loaded with nano CoFe2 – xErxO4 ferrite. J. Mater. Sci.: Mater. Electron. 34(6), 566 (2023)

El-Naggar, A.M., Heiba, Z.K., Kamal, A.M., Abd-Elkader, O.H., Mohamed, M.B.: Impact of ZnS/Mn on the Structure. Optical, and Electric Properties of PVC Polymer, Polymers 15(9), 2091 (2023)PubMed

El-Sharkawy, R.M., Abdou, F.S., Gizawy, M.A., Allam, E.A., Mahmoud, M.E.: Bismuth oxide nanoparticles (Bi2O3 NPs) embedded into recycled- poly (vinyl chloride) plastic sheets as a promising shielding material for gamma radiation. Radiat. Phys. Chem. 208, 110838 (2023)

Hadi, J.M., Aziz, S.B., Mustafa, M.S., Hamsan, M.H., Abdulwahid, R.T., Kadir, M.F.Z., Ghareeb, H.O.: Role of nano-capacitor on dielectric constant enhancement in PEO:NH 4 SCN:xCeO₂ polymer nano-composites: Electrical and electrochemical properties. J. Mater. Sci. Technol. 9(4), 9283 (2020)

Hadi, J.M., Aziz, S.B., Nofal, M.M., Hussein, S.A., Hafiz, M.H., Brza, M.A., Abdulwahid, R.T., Kadir, M.F.Z., Woo, H.J.: Electrical, dielectric property and electrochemical performances of plasticized silver ion-conducting chitosan-based polymer nanocomposites. Membranes 10, 151 (2020)PubMed

Heiba, Z.K., Mohamed, M.B., El-naggar, A.M., Altowairqi, Y.: Structure and dielectric properties of ZnMn2O4/NiFe2O4 nanocomposite. Appl. Phys. A. 127(8), 1 (2021)

Heiba, Z.K., Mohamed, M.B., Badawi, A.: Structural and optical properties of (1 – x)ZnMn2O4/xPbS nanocomposites. J. Mater. Sci.: Mater. Electron. 33(14), 11354 (2022)

Heiba, Z.K., El-naggar, A.M., Kamal, A.M., Abd-Elkader, O.H., Mohamed, M.B.: Optical and dielectric properties of PVC/TiO2/TBAI ionic liquid polymer electrolyte. Opt. Mater. 139, 113764 (2023)

Howell, F.S., Bose, R.A., Macedo, P.B., Moynihan, C.T.: Electrical relaxation in a glass-forming molten salt. J. Phys. Chem. 78(6), 639 (1974)

Isasi, J., L´opez, M.L., Veiga, M.L., Ruiz-Hitzky, E., Pico, C.: Structural characterization, and electrical properties of a novel defect pyrochlore. J. Solid State Chem. 116, 290 (1995)ADS

Ismail, M.S., Elamin, A.A., Abdel-Wahab, F., Elbashar, Y.H., Mahasen, M.M.: Improving the refractive index by engineering PbS/PVA nano polymer composite for optoelectronic applications. Opt. Mater. 131, 112639 (2022)

Kh, H., Rasheed, A.A., Kareem: Effect of Multiwalled Carbon Nanotube reinforcement on the Opto-Electronic properties of Polyaniline/c-Si Heterojunction. J. Opt. Commun. 42(1), 25–29 (2021)

Khairy, Y., Mohammed, M.I., Elsaeedy, H.I., Yahia, I.S.: Optical and electrical properties of SnBr2-doped polyvinyl alcohol (PVA) polymeric solid electrolyte for electronic and optoelectronic applications. Optik. 228, 166129 (2021)ADS

Lakowicz, J.R.: Quenching of fluorescence. In: (eds) In: Principles of Fluorescence Spectroscopy. Springer, Boston, MA (2006)

Liu, Z., Tian, Y., Yang, J., Li, A., Wang, Y., Ren, J., Fang, M., Tang, B.Z., Li, Z.: Direct demonstration of triplet excimer in purely organic room temperature phosphorescence through rational molecular design. Light Sci. Appl. 11, 142 (2022)PubMedPubMedCentralADS

Lutterotti, L.: Total pattern fitting for the combined size–strain–stress–texture determination in thin film diffraction. Nucl. Inst. Methods Phys. Res. B. 268, 334 (2010)ADS

Mahmoud, W.E., Al-Ghamdi, A.A.: The influence of cd (ZnO) on the structure, optical and thermal stabilities of polyvinyl chloride nanocomposites. Polym. Compos. 32(7), 1143 (2011)

Marianne, Gilbert: Crystallinity in poly(vinyl chloride). Polym. Rev. 34(1), 77 (1994)

Mergen, O.B.: Effect of MWCNT addition on the optical band gap of PVA/CS transient biocomposites. J. Compos. Mater. 55(29), 4347–4359 (2021)ADS

Mohamed, M.B., Abdel-Kader, M.H.: Effect of annealed ZnS nanoparticles on the structural and optical properties of PVA Polymer nanocomposite. Mater. Chem. Phys. 241, 122285 (2020)

Mohamed, S.A., Al-Ghamdi, A.A., Sharma, G.D., Mansy, M.K.E.: Effect of ethylene carbonate as a plasticizer on CuI/PVA nanocomposite: Structure, optical and electrical properties. J. Adv. Res. 5, 79 (2014)PubMed

Mohammed, M.I., Yahia, I.S., Abd El-Mongy, S.: Simple fabrication of PVA/PEG blend doped with methyl blue dye with superior optical limiting performance: Enhanced luminescence property, structural, and dielectric properties. Mater. Sci. Eng., B. 291, 116390 (2023)

Naik, J., Bhajantri, R.F., Rathod, S.G., Sheela, T., Ravindrachary, V.: Synthesis and characterization of multifunctional ZnBr2/PVA Polymer dielectrics. J. Adv. Dielectr. 06(04), 1650028 (2016)ADS

Nofal, M.M., Aziz, S.B., Hadi, J.M., Karim, W.O., Dannoun, E.M.A., Hussein, A.M., Hussen, S.A.: Polymer composites with 0.98 transparencies and small optical energy band gap using a promising green methodology: structural and optical properties. Polymers 13, 164 (2021)

Palma, T.L., Vieira, B., Nunes, J., Lourenço, J.P., Monteiro, O.C., Costa, M.C.: Photodegradation of chloramphenicol and paracetamol using PbS/TiO2 nanocomposites produced by green synthesis. J Iran Chem. Soc. 17, 2013 (2020)

Rajabi, H.R., Naghiha, R., Kheirizadeh, M., Sadatfaraji, H., Mirzaei, A., Alvand, Z.M.: Microwave assisted extraction as an efficient approach for biosynthesis of zinc oxide nanoparticles: Synthesis, characterization, and biological properties. Mater. Sci. Eng. C. 78, 1109 (2017)

Reddy, C.V.S., Han, X., Zhu, Q.Y., Mai, L.Q., Chen, W.: Dielectric spectroscopy studies on (PVP + PVA) polyblend film. Microelectron. Eng. 83, 281 (2006)

Rodríguez-Carvajal, J.: Recent advances in magnetic structure determination by neutron powder diffraction. Phys. B (Amsterdam Neth). 192, 55 (1993)ADS

Suma, G.R., Subramani, N.K., Shilpa, K.N., Sachhidananda, S., Satyanarayana, S.V.: Effect of Ce_0.5Zr_0.5O₂ nano fillers on structural and optical behaviors of poly(vinyl alcohol). J. Mater. Sci. : Mater. Electron. 28(14), 10707 (2017)

Taha, T.A., Azab, A.A.: AC conductivity and dielectric properties of borotellurite glass. J. Electr. Mater. 45(10), 5170 (2016)ADS

Taha, T.A., Hassona, A., Elrabaie, S., Attia, M.T.: Micro–structure, thermal, and dielectric performance of polyester nanocomposites containing nano–Ni0.5Zn0.5Fe2O4. Appl. Phys. A. 126, 761 (2020)ADS

Yassin, A.Y., Raouf Mohamed, A., Abdelghany, A.M., Abdelrazek, E.M.: Enhancement of dielectric properties and AC electrical conductivity of nanocomposite using poly (vinyl chloride-co-vinyl acetate-co-2- hydroxypropyl acrylate) filled with graphene oxide. J. Mater. Sci.: Mater. Electron. 29, 15931–15159 (2018)

Yilmaz, M., Pekdemir, M.E., Ozen Oner, E.: Evaluation of Pb doped Poly(lactic acid) (PLA) / poly(ethylene glycol) (PEG) blend composites regarding physicochemical and radiation shielding properties. Radiat. Phys. Chem. 202, 110509 (2023)

Title: Structural, optical, and dielectric properties of PVC/ZnMn2O4/PbS polymers with and without MWCNTs
Authors: A. M. El-naggar
Zein K. Heiba
A. M. Kamal
Mohamed Bakr Mohamed
Publication date: 01-01-2024
Publisher: Springer US
Published in: Optical and Quantum Electronics / Issue 1/2024
Print ISSN: 0306-8919
Electronic ISSN: 1572-817X
DOI: https://doi.org/10.1007/s11082-023-05589-9

Springer Professional

Abstract

Please log in to get access to your license.

Dont have a licence yet? Then find out more about our products and how to get one now:

Springer Professional "Technik"

Springer Professional "Wirtschaft+Technik"

Springer Professional "Wirtschaft"

Other articles of this Issue 1/2024

A comprehensive study on optical, physical, mechanical and radiation shielding properties of calcium bismuth borophosphate glass–ceramics with distinct V2O5 contents

Modeling and analysis of a photonic crystal embedded ENZ gyrotropic metatronic amplifier using the mode matching technique

Growth and optical properties of (Na0.5Bi0.5)(Mo1−xWx)O4 (x = 0.25) single crystal: a potential candidate for optoelectronic devices

Eco-friendly synthesis of tin oxide nanoparticles utilizing the buckthorn leaf extracts

On the solitonic wave structures for the perturbed nonlinear Schrödinger equation arising in optical fibers

Efficiency droop free UV-C LED by introducing p-doped LQB and p-n-p-n-p doped AlGaN hole injection layer