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Published in:
1994 | OriginalPaper | Chapter
Structure-Reactivity Relationships in Acyclic Diene Metathesis (ADMET) Polymerization
Author : K. B. Wagener
Published in: Progress in Pacific Polymer Science 3
Publisher: Springer Berlin Heidelberg
Included in: Professional Book Archive
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The structure/reactivity behavior for pure hydrocarbon diene monomers, and for dienes containing heteroatoms has been examined. Steric hindrance is the controlling factor for hydrocarbon monomers, and intramolecular electronic interactions determine the reactivity of dienes possessing heteroatom functionality. This electronic interaction phenomenon is termed the “Negative Neighboring Group Effect”.