Skip to main content
Top
Published in: Journal of Materials Science 6/2015

01-03-2015 | Original Paper

Synergistic effect of vegetable protein and silicon addition on geopolymeric foams properties

Authors: Letizia Verdolotti, Barbara Liguori, Ilaria Capasso, Agostino Errico, Domenico Caputo, Marino Lavorgna, Salvatore Iannace

Published in: Journal of Materials Science | Issue 6/2015

Log in

Activate our intelligent search to find suitable subject content or patents.

search-config
loading …

Abstract

Organic–inorganic hybrid foams based on an alkali alumino-silicate matrix were prepared using different foaming methods. Firstly, silico-aluminate inorganic matrix, activated through a sodium silicate solution, was prepared at room temperature. The obtained viscous paste was expanded by means of silicon metal redox reaction in alkaline media in combination with protein-assisted foaming. The foamed systems were hardened at defined temperature and time and then characterized by FTIR, scanning electron microscopy, and compression tests. The high temperature behavior and specific surface area were also evaluated. The experimental findings highlighted that the combination of silicon metal and vegetable protein allowed tailoring hybrid foams with enhanced properties: good yield strength and thermal resistance typical of geopolymeric foam with a ductile behavior (toughness) and low density typical of organic foams.

Dont have a licence yet? Then find out more about our products and how to get one now:

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

  • über 102.000 Bücher
  • über 537 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Finance + Banking
  • Management + Führung
  • Marketing + Vertrieb
  • Maschinenbau + Werkstoffe
  • Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

  • über 67.000 Bücher
  • über 390 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Maschinenbau + Werkstoffe




 

Jetzt Wissensvorsprung sichern!

Literature
1.
go back to reference Landi E, Medri V, Papa E, Dedecek J, Klein P, Benito P, Vaccari A (2013) Alkali-bonded ceramics with hierarchical tailored porosity. Appl Clay Sci 73:56–64CrossRef Landi E, Medri V, Papa E, Dedecek J, Klein P, Benito P, Vaccari A (2013) Alkali-bonded ceramics with hierarchical tailored porosity. Appl Clay Sci 73:56–64CrossRef
2.
go back to reference Kamseu E, Nait-Ali B, Bignozzi MC, Leonelli C, Rossignol S, Smith DS (2012) Bulk composition and microstructure dependence of effective thermal conductivity of porous inorganic polymer cements. J Eur Ceram Soc 32(8):1593–1603CrossRef Kamseu E, Nait-Ali B, Bignozzi MC, Leonelli C, Rossignol S, Smith DS (2012) Bulk composition and microstructure dependence of effective thermal conductivity of porous inorganic polymer cements. J Eur Ceram Soc 32(8):1593–1603CrossRef
4.
go back to reference Van Bonin W, Nehen U, Von Gizycki U (1975) Hydrogen peroxides blowing agent for silicate foams. US Patent 3,864,137 Van Bonin W, Nehen U, Von Gizycki U (1975) Hydrogen peroxides blowing agent for silicate foams. US Patent 3,864,137
5.
go back to reference Vaou V, Panias D (2010) Thermal insulating foamy geopolymers from perlite. Miner Eng 23:1146–1151CrossRef Vaou V, Panias D (2010) Thermal insulating foamy geopolymers from perlite. Miner Eng 23:1146–1151CrossRef
6.
go back to reference Prud’Homme E, Michaud P, Joussein E, Peyratout C, Smith A, Rossignol S (2011) In situ inorganic foams prepared from various clays at low temperature. Appl Clay Sci 51(1):15–22CrossRef Prud’Homme E, Michaud P, Joussein E, Peyratout C, Smith A, Rossignol S (2011) In situ inorganic foams prepared from various clays at low temperature. Appl Clay Sci 51(1):15–22CrossRef
7.
go back to reference Studart AR, Gonzenbach UT, Tervoort E, Gauckler LJ (2006) Processing routes to macroporous ceramics: a review. J Am Ceram Soc 89(6):1771–1789CrossRef Studart AR, Gonzenbach UT, Tervoort E, Gauckler LJ (2006) Processing routes to macroporous ceramics: a review. J Am Ceram Soc 89(6):1771–1789CrossRef
9.
go back to reference Scheffler M, Colombo P (2005) Cellular ceramics: structure, manufacturing, properties and applications. Wiley–VCH Verlag GmbH, Weinheim, Germany Scheffler M, Colombo P (2005) Cellular ceramics: structure, manufacturing, properties and applications. Wiley–VCH Verlag GmbH, Weinheim, Germany
10.
go back to reference Lyckfeldt O, Brandt J, Lesca S (2000) Protein forming—a novel shaping technique for ceramics. J Eur Ceram Soc 20(14):2551–2559CrossRef Lyckfeldt O, Brandt J, Lesca S (2000) Protein forming—a novel shaping technique for ceramics. J Eur Ceram Soc 20(14):2551–2559CrossRef
11.
go back to reference Garrn I, Reetz C, Brandes N, Kroh LW, Schubert H (2004) Clot-forming: the use of proteins as binders for producing ceramic foams. J Eur Ceram Soc 24(3):579–587CrossRef Garrn I, Reetz C, Brandes N, Kroh LW, Schubert H (2004) Clot-forming: the use of proteins as binders for producing ceramic foams. J Eur Ceram Soc 24(3):579–587CrossRef
12.
go back to reference Murray BS, Ettelaie R (2004) Foam stability: proteins and nanoparticles. Curr Opin Colloid In 9(5):314–320CrossRef Murray BS, Ettelaie R (2004) Foam stability: proteins and nanoparticles. Curr Opin Colloid In 9(5):314–320CrossRef
13.
go back to reference Bos MA, Van Vliet T (2001) Interfacial rheological properties of adsorbed protein layers and surfactants: a review. Adv Colloid Interfac 91(3):437–471CrossRef Bos MA, Van Vliet T (2001) Interfacial rheological properties of adsorbed protein layers and surfactants: a review. Adv Colloid Interfac 91(3):437–471CrossRef
14.
go back to reference Damodaran S (2005) Protein stabilization of emulsions and foams. J Food Sci 70(3):54–66CrossRef Damodaran S (2005) Protein stabilization of emulsions and foams. J Food Sci 70(3):54–66CrossRef
15.
go back to reference Chen J, Dickinson E (1998) Viscoelastic properties of protein-stabilized emulsions: effect of protein-surfactant interactions. J Agr Food Chem 46(1):91–97CrossRef Chen J, Dickinson E (1998) Viscoelastic properties of protein-stabilized emulsions: effect of protein-surfactant interactions. J Agr Food Chem 46(1):91–97CrossRef
16.
go back to reference Verdolotti L, Di Maio E, Forte G, Lavorgna M, Iannace S (2010) Hydration-induced reinforcement of polyurethane–cement foams: solvent resistance and mechanical properties. J Mater Sci 45(12):3388–3391. doi:10.1007/s10853-010-4416-5 CrossRef Verdolotti L, Di Maio E, Forte G, Lavorgna M, Iannace S (2010) Hydration-induced reinforcement of polyurethane–cement foams: solvent resistance and mechanical properties. J Mater Sci 45(12):3388–3391. doi:10.​1007/​s10853-010-4416-5 CrossRef
17.
go back to reference Xu H, Van Deventer JSJ (2000) The geopolymerisation of alumino-silicate minerals. Int J Miner Process 59(3):247–266CrossRef Xu H, Van Deventer JSJ (2000) The geopolymerisation of alumino-silicate minerals. Int J Miner Process 59(3):247–266CrossRef
18.
go back to reference Wang L, Tomura S, Suzuki M, Ohashi F, Inukai K, Maeda M (2001) Synthesis of mesoporous silica material with sodium hexafluorosilicate as silicon source under ultra-low surfactant concentration. J Mater Sci Lett 20:277–280CrossRef Wang L, Tomura S, Suzuki M, Ohashi F, Inukai K, Maeda M (2001) Synthesis of mesoporous silica material with sodium hexafluorosilicate as silicon source under ultra-low surfactant concentration. J Mater Sci Lett 20:277–280CrossRef
19.
go back to reference Zhang XG (2001) Elettrochemistry of silicon and its oxides. Kluver Academic/Plenum Publisher, New York Zhang XG (2001) Elettrochemistry of silicon and its oxides. Kluver Academic/Plenum Publisher, New York
20.
go back to reference Mo BH, Zhu H, Cui XM, He Y, Gong SY (2014) Effect of curing temperature on geopolymerization of metakaolin-based geopolymers. Appl Clay Sci 99:144–148CrossRef Mo BH, Zhu H, Cui XM, He Y, Gong SY (2014) Effect of curing temperature on geopolymerization of metakaolin-based geopolymers. Appl Clay Sci 99:144–148CrossRef
21.
go back to reference Xu H, van Deventer JS (2003) The effect of alkali metals on the formation of geopolymeric gels from alkali-feldspars. Colloid Surface A 216(1):27–44CrossRef Xu H, van Deventer JS (2003) The effect of alkali metals on the formation of geopolymeric gels from alkali-feldspars. Colloid Surface A 216(1):27–44CrossRef
22.
go back to reference Komnitsas K, Zaharaki D (2007) Geopolymerisation: a review and prospects for the minerals industry. Miner Eng 20(14):1261–1277CrossRef Komnitsas K, Zaharaki D (2007) Geopolymerisation: a review and prospects for the minerals industry. Miner Eng 20(14):1261–1277CrossRef
23.
24.
go back to reference Medri V, Papa E, Dedecek J, Jirglova H, Benito P, Vaccari A, Landi E (2013) Effect of metallic Si addition on polymerization degree of in situ foamed alkali-aluminosilicates. Ceram Int 39(7):7657–7668CrossRef Medri V, Papa E, Dedecek J, Jirglova H, Benito P, Vaccari A, Landi E (2013) Effect of metallic Si addition on polymerization degree of in situ foamed alkali-aluminosilicates. Ceram Int 39(7):7657–7668CrossRef
25.
go back to reference Gibson LJ, Ashby MF (1999) Cellular solids: structure and properties. Cambridge University Press, Cambridge, MA Gibson LJ, Ashby MF (1999) Cellular solids: structure and properties. Cambridge University Press, Cambridge, MA
26.
go back to reference Colombo P, Hellmann JR, Shelleman DL (2001) Mechanical properties of silicon oxycarbide ceramic foams. J Am Ceram Soc 84(10):2245–2251CrossRef Colombo P, Hellmann JR, Shelleman DL (2001) Mechanical properties of silicon oxycarbide ceramic foams. J Am Ceram Soc 84(10):2245–2251CrossRef
28.
go back to reference Sing KSW, Everett DH, Haul RAW, Moscou L, Pierotti RA, Rouquerol J (1985) Pure Appl Chem 57:603–619CrossRef Sing KSW, Everett DH, Haul RAW, Moscou L, Pierotti RA, Rouquerol J (1985) Pure Appl Chem 57:603–619CrossRef
Metadata
Title
Synergistic effect of vegetable protein and silicon addition on geopolymeric foams properties
Authors
Letizia Verdolotti
Barbara Liguori
Ilaria Capasso
Agostino Errico
Domenico Caputo
Marino Lavorgna
Salvatore Iannace
Publication date
01-03-2015
Publisher
Springer US
Published in
Journal of Materials Science / Issue 6/2015
Print ISSN: 0022-2461
Electronic ISSN: 1573-4803
DOI
https://doi.org/10.1007/s10853-014-8801-3

Other articles of this Issue 6/2015

Journal of Materials Science 6/2015 Go to the issue

Premium Partners