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Journal of Polymer Research
Published in: Journal of Polymer Research 5/2021

01-05-2021 | ORIGINAL PAPER

Synthesis and characterization of poly(methyl methacrylate-g-α-methyl-β-alanine) copolymer using "Grafting Through" method

Authors: Bedrettin Savaş, Efkan Çatıker, Temel Öztürk, Ergül Meyvacı

Published in: Journal of Polymer Research | Issue 5/2021

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Abstract

Synthesis of poly(methyl methacrylate-g-α-methyl-β-alanine) [poly(MMA-g-mBA)] copolymer was achieved through base-catalyzed hydrogen transfer polymerization (HTP) and free-radical polymerization (FRP), respectively. For this purpose, poly(α-methyl β-alanine) [PmBA] oligomer with olefinic end-group as a macromonomer was synthesized from methacrylamide by base-catalyzed HTP method. Poly(MMA-g-mBA) in different compositions was obtained through FRP of methyl methacrylate/the PmBA macromonomer mixtures using the "grafting through" method. The characterization of the copolymerization products was accomplished by using multi-instruments such as 1H-NMR, FTIR, TGA, and dynamic light scattering. The spectroscopic and thermal analysis of the graft copolymer reveal that the copolymer was easily built through a combination of HTP and FRP techniques.
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Literature
1.
Savaş B, Çatıker E, Öztürk T, Meyvacı E (2021) Synthesis and characterization of poly(α-methyl β-alanine)-poly(ε-caprolactone) tri arm star polymer by hydrogen transfer polymerization, ring-opening polymerization and “click” chemistry. J Polym Res 28:30CrossRef
2.
Breslow DS, Hulse GE, Matlack AS (1957) Synthesis of poly-β-alanine from acrylamide. a novel synthesis of β-alanine. J Am Chem Soc 79:3760–3763CrossRef
3.
Otsu T, Yamada B, Itahashi M, Mori T (1976) Hydrogen-transfer polymerization of methyl-substituted acrylamides. J Polym Sci: Polymer Chemistry Edition 14:1347–1361
4.
Çatıker E, Sancaktar E (2014) Blends of poly (3-hydroxybutyrate) with poly (β-alanine) and its derivatives. J Appl Polym Sci 131:40484CrossRef
5.
Çatıker E, Öztürk T, Atakay M, Salih B (2019) Synthesis and characterization of novel ABA type poly(ester-ether) triblock copolymers. J Polym Res 26:123CrossRef
6.
Lee MR, Stahl SS, Gellman SH, Masters KS (2009) Nylon-3 copolymers that generate cell-adhesive surfaces identified by library screening. J Am Chem Soc 131:16779–16789CrossRef
7.
Chakraborty S, Liu R, Lemke JJ, Hayouka Z, Welch RA, Weisblum B, Masters KS, Gellman SH (2013) Effects of cyclic vs. acyclic hydrophobic subunits on the chemical structure and biological properties of nylon-3 copolymers. ACS Macro Lett 2:753–756CrossRef
8.
Çatıker E, Meyvacı E, Atakay M, Salih B, Öztürk T (2019) Synthesis and characterization of amphiphilic triblock copolymers including β-alanine/α-methyl-β-alanine and ethylene glycol by “click” chemistry. Polym Bull 76:2113–2128CrossRef
9.
Liu R, Masters KS, Gellman SH (2012) Polymer chain length effects on fibroblast attachment on nylon-3-modified surfaces. Biomacromol 13:1100–1105CrossRef
10.
Iwamura T, Ashizawa K, Adachi K, Takasaki M (2019) Anionic hydrogen-transfer polymerization of N-isopropyl acrylamide under microwave irradiation. J Polym Sci, Part A: Polym Chem 57:2415–2419CrossRef
11.
Altıntas O, Tunca U (2011) Synthesis of terpolymers by click reactions. Chem Asian J 6:2584–2591CrossRef
12.
Savaş B, Öztürk T (2020) Synthesis and characterization of poly(vinyl chloride-g-methyl methacrylate) graft copolymer by redox polymerization and Cu catalyzed azide-alkyne cycloaddition reaction. J Macromol Sci Part A Pure Appl Chem 57:819–825CrossRef
13.
Öztürk T, Savaş B, Meyvacı E, Kılıçlıoğlu A, Hazer B (2020) Synthesis and characterization of the block copolymers using the novel bifunctional initiator by RAFT and FRP technics: evaluation of the primary polymerization parameters. J Polym Res 27:76CrossRef
14.
Öztürk T, Yörümez C (2020) Synthesis of block copolymer including polyepichlorohydrin and polyethylene glycol by “click” chemistry: evaluation of primary parameters of copolymerization. Polym Bull 77:4773–4788CrossRef
15.
Öztürk T, Meyvacı E (2017) Synthesis and characterization poly(ϵ-caprolactone-b-ethylene glycol-b-ϵ-caprolactone) ABA type block copolymers via “click” chemistry and ring-opening polymerization. J Macromol Sci Part A Pure Appl Chem 54:575–581CrossRef
16.
Nuyken O, Weidner R (1986) Graft and block copolymers via polymeric azo initiators. In: Chromatography/Foams/Copolymers. Advances in Polymer Science, vol 73/74. Springer, Berlin, Heidelberg
17.
Brandrup J, Immergut EH (1975) In: Polymer Handbook, 2nd edn. Wiley, New York
18.
Öztürk T, Cavicchi CA (2018) Synthesis and characterization of poly(epichlorohydrin-g-ε-caprolactone) graft copolymers by “click” chemistry. J Polym Mater 35:209–220CrossRef
19.
Öztürk T, Meyvacı E, Arslan T (2020) Synthesis and characterization of poly(vinyl chloride-g-ε-caprolactone) brush type graft copolymers by ring-opening polymerization and “click” chemistry. J Macromol Sci Part A Pure Appl Chem 57:171–180CrossRef
20.
Janata M, Masar B, Toman L, Vlcek P, Latalova P, Brus J, Holler P (2003) Synthesis of novel types of graft copolymers by a “grafting-from” method using ring-opening polymerization of lactones and lactides. React Funct Polym 57:137–146CrossRef
21.
Xie M, Dang J, Han H, Wang W, Liu J, He X, Zhang Y (2008) Well-Defined Brush Copolymers with High Grafting Density of Amphiphilic Side Chains by Combination of ROP, ROMP, and ATRP. Macromolecules 41:9004–9010CrossRef
22.
Öztürk T, Hazer B (2010) Synthesis and characterization of a novel macromonomer initiator for reversible addition fragmentation chain transfer (RAFT). Evaluation of the polymerization kinetics and gelation behaviors. J Macromol Sci Part A Pure Appl Chem 47:265–272CrossRef
23.
Öztürk T, Kayğın O, Göktaş M, Hazer B (2016) Synthesis and characterization of graft copolymers based on polyepichlorohydrin via reversible addition-fragmentation chain transfer polymerization. J Macromol Sci Part A Pure Appl Chem 53:362–367CrossRef
24.
Gacal B, Durmaz H, Tasdelen MA, Hizal G, Tunca U, Yagci Y, Demirel AL (2006) Anthracene-maleimide-based Diels-Alder “click chemistry” as a novel route to graft copolymers. Macromolecules 39:5330–5336CrossRef
25.
Durmaz H, Dag A, Cerit N, Sirkecioglu O, Hizal G, Tunca U (2010) Graft copolymers via romp and diels-alder click reaction strategy. J Polym Sci, Part A: Polym Chem 48:5982–5991CrossRef
26.
Çatıker E, Güven O, Salih B (2018) Novel hydrophobic macromonomers for potential amphiphilic block copolymers. Polym Bull 75:47–60CrossRef
27.
Roos K, Planes M, Hassani C, Mehats J, Vax A, Carlotti S (2016) Solvent-free anionic polymerization of acrylamide: A mechanistic study for the rapid and controlled synthesis of polyamide-3. Macromolecules 49:2039–2045CrossRef
28.
Savaş B, Öztürk T, Meyvacı E, Hazer B (2020) Synthesis and characterization of comb-type graft copolymers by redox polymerization and “click” chemistry method. SN Appl Sci 2:181CrossRef
29.
Çatıker E, Öztürk T, Atakay M, Salih B (2020) Synthesis and characterization of the ABA-type poly(ester-ether-ester) block copolymers. J Macromol Sci Part A Pure Appl Chem 57:600–609CrossRef
30.
31.
Jamshid MR (2008) Synthesis and thermal properties of novel multiblock biodegradable copolymers derived from polyethylene glycol, ε-caprolactone, and p-dioxanone. ScienceAsia 34:207–213CrossRef
32.
Thanomsilp C, Phetthianchai U (2012) Synthesis and characterization of PLA-co-PEG copolymers. Adv Mat Res 506:178–181
33.
Martinez MR, Cong Y, Sheiko SS, Matyjaszewski K (2020) A thermodynamic roadmap for the grafting-through polymerization of PDMS11MA. ACS Macro Lett 9:1303–1309CrossRef
34.
Cho HY, Krys P, Szcześniak K, Schroeder H, Park S, Jurga S, Buback M, Matyjaszewski K (2015) Synthesis of poly(OEOMA) using macromonomers via “grafting-through” ATRP. Macromolecules 48:6385–6395CrossRef
35.
Kaneyoshi H, Matyjaszewski K (2007) Synthesis of a linear polyethylene macromonomer and preparation of polystyrene-graft-polyethylene copolymers via grafting-through atom transfer radical polymerization. J Appl Polym Sci 105:3–13CrossRef
Metadata
Title
Synthesis and characterization of poly(methyl methacrylate-g-α-methyl-β-alanine) copolymer using "Grafting Through" method
Authors
Bedrettin Savaş
Efkan Çatıker
Temel Öztürk
Ergül Meyvacı
Publication date
01-05-2021
Publisher
Springer Netherlands
Published in
Journal of Polymer Research / Issue 5/2021
Print ISSN: 1022-9760
Electronic ISSN: 1572-8935
DOI
https://doi.org/10.1007/s10965-021-02551-9

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