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Journal of Materials Science: Materials in Electronics
Published in: Journal of Materials Science: Materials in Electronics 12/2015

14-09-2015

Synthesis and enhanced photoreactivity of metallic Bi-decorated BiOBr composites with abundant oxygen vacancies

Authors: Hongchao Ma, Min Zhao, Hongmei Xing, Yinghuan Fu, Xiufang Zhang, Xiaoli Dong

Published in: Journal of Materials Science: Materials in Electronics | Issue 12/2015

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Abstract

Herein, a simple one-pot solvothermal strategy was put forward to obtain metal Bi-decorated BiOBr composites (Bi/BiOBr) with abundant oxygen vacancies. The metal Bi (Bi0) can be deposited into the BiOBr surface via reduction of glycerol solvent in solvothermal process. Precipitation of Bi on surface of BiOBr turned the morphologies of BiOBr from regular flower-like hierarchical architectures to scattered sheets with increase of Bi content, enhanced photoabsorption of BiOBr in whole light region. Interestingly, deposition of metallic Bi (Bi0) on the BiOBr surface could lead to formation of abundant surface oxygen vacancies. As-synthesized Bi/BiOBr composites showed better photocatalytic activity for phenol degradation under sunlight irradiation, as compared with that of BiOBr reference. The enhancement of photocatalytic activities for Bi/BiOBr composites can be attributed to the existence of Bi/BiOBr hetero-structure and abundant oxygen vacancies (as active electron trap), which causing efficient separation of electron–hole pairs in Bi/BiOBr composites.
previous article BaTiO3/Ba4Ti13O30 nanocomposite: synthesis, characterization, and its photovoltaic application via two-step sol–gel method
next article Dielectric, impedance and transport characteristics of (Bi0.6Pb0.4Fe0.6Ti0.4)O3

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Appendix
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Metadata
Title
Synthesis and enhanced photoreactivity of metallic Bi-decorated BiOBr composites with abundant oxygen vacancies
Authors
Hongchao Ma
Min Zhao
Hongmei Xing
Yinghuan Fu
Xiufang Zhang
Xiaoli Dong
Publication date
14-09-2015
Publisher
Springer US
Published in
Journal of Materials Science: Materials in Electronics / Issue 12/2015
Print ISSN: 0957-4522
Electronic ISSN: 1573-482X
DOI
https://doi.org/10.1007/s10854-015-3680-1

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